Article
Multitask Guanidinium Bromide Functionalized Metal–Organic Framework in Chemical Fixation of CO2 at Low Pressure and TemperatureClick to copy article linkArticle link copied!
- Ahmad Shaabani*Ahmad Shaabani*Tel.: +982129902800. Fax: +982122431663. E-mail address: [email protected]Faculty of Chemistry, Shahid Beheshti University, G.C., P.O. Box 19396-4716, Tehran, IranMore by Ahmad Shaabani
- Reza MohammadianReza MohammadianFaculty of Chemistry, Shahid Beheshti University, G.C., P.O. Box 19396-4716, Tehran, IranMore by Reza Mohammadian
- Hassan FarhidHassan FarhidFaculty of Chemistry, Shahid Beheshti University, G.C., P.O. Box 19396-4716, Tehran, IranMore by Hassan Farhid
- Masoumeh Karimi AlavijehMasoumeh Karimi AlavijehFaculty of Chemistry, Shahid Beheshti University, G.C., P.O. Box 19396-4716, Tehran, IranMore by Masoumeh Karimi Alavijeh
- Mostafa M. Amini*Mostafa M. Amini*Tel.: +982129903109. Fax: +982122431663. E-mail address: [email protected]Faculty of Chemistry, Shahid Beheshti University, G.C., P.O. Box 19396-4716, Tehran, IranMore by Mostafa M. Amini
Abstract
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A guanidinium bromide covalently was anchored to a CO2-absorbent metal–organic framework via a two-step postsynthetic modification process and successfully used as a catalyst for the synthesis of cyclic carbonates through cycloaddition of CO2 to epoxides under mild conditions without utilizing any cocatalyst or organic solvent. In this protocol, the synergistic and cooperative effect was anticipated between the catalyst part and the support part to increase the reaction efficiency. Three key factors which are essential for carbon dioxide stabilization reaction were integrated simultaneously in this catalytic system including high CO2 absorption capability of MOF, availability of Lewis acidic centers in MIL-101(Cr) as a cocatalyst, and presence of guanidinium salt as an efficient catalyst. This method demonstrated a high potential for recycling homogeneous catalysts by maintaining their initial performances.
Copyright © 2019 American Chemical Society
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