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Investigation of Azo-COP-2 as a Photoresponsive Low-Energy CO2 Adsorbent and Porous Filler in Mixed Matrix Membranes for CO2/N2 Separation

  • Siyao Li
    Siyao Li
    Barrer Centre, Department of Chemical Engineering, Imperial College London, London SW7 2AZ, United Kingdom
    More by Siyao Li
  • Nicholaus Prasetya
    Nicholaus Prasetya
    Barrer Centre, Department of Chemical Engineering, Imperial College London, London SW7 2AZ, United Kingdom
  • , and 
  • Bradley P. Ladewig*
    Bradley P. Ladewig
    Barrer Centre, Department of Chemical Engineering, Imperial College London, London SW7 2AZ, United Kingdom
    Institute for Micro Process Engineering (IMVT), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
    *E-mail: [email protected]
Cite this: Ind. Eng. Chem. Res. 2019, 58, 23, 9959–9969
Publication Date (Web):May 16, 2019
https://doi.org/10.1021/acs.iecr.9b00762
Copyright © 2019 American Chemical Society

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    Abstract

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    Azo-COP-2 is a nanoporous polymer with exceptional CO2/N2 separation performance. In this study, we further investigate the application of Azo-COP-2 as a low-energy CO2 adsorbent and porous filler in mixed matrix membranes (MMMs) for CO2/N2 separation. As an adsorbent, the UV-irradiated Azo-COP-2 showed lower CO2 uptake than in the nonirradiated state, and Azo-COP-2 also exhibited highly efficient CO2 photoswitching between the two states. Combined with high CO2/N2 selectivity, this makes Azo-COP-2 an excellent candidate for low-energy CO2 capture and release. Azo-COP-2 is also shown to be a beneficial filler in MMMs. For polysulfone-based MMMs, the CO2 permeability and CO2/N2 selectivity could be increased up to 160% and 66.7%, respectively. The strategy shows the great potential of Azo-COP-2 not only for a low-energy CO2 adsorbent but also to improve the performance of conventional polymeric membranes for CO2 postcombustion capture.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.iecr.9b00762. The raw data for all figures in this manuscript, as well as the full resolution SEM micrographs, are available from the open repository https://doi.org/10.5281/zenodo.1469797.

    • FTIR spectra of Matrimid (A), polysulfone (B), and PIM-1 (C) based mixed matrix membranes. Cross-section SEM micrographs of pure polymer matrices. Summary of diffusivity and solubility for Azo-COP-2/Matrimid, Azo-COP-2/Polysulfone, and Azo-COP-2/PIM-1 MMMs. (PDF)

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