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Mechanism and Kinetics Study on Low-Temperature NH3-SCR Over Manganese–Cerium Composite Oxide Catalysts

  • Feng Lin
    Feng Lin
    School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
    Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering, Shanghai 200093, China
    More by Feng Lin
  • Qiulin Wang*
    Qiulin Wang
    School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
    Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering, Shanghai 200093, China
    *E-mail: [email protected]. Tel: +86 21 55270805.
    More by Qiulin Wang
  • Jianchao Zhang
    Jianchao Zhang
    School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
    Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering, Shanghai 200093, China
  • Jing Jin
    Jing Jin
    School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
    Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering, Shanghai 200093, China
    More by Jing Jin
  • Shengyong Lu
    Shengyong Lu
    State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou 310027, China
    More by Shengyong Lu
  • , and 
  • Jianhua Yan
    Jianhua Yan
    State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou 310027, China
    More by Jianhua Yan
Cite this: Ind. Eng. Chem. Res. 2019, 58, 51, 22763–22770
Publication Date (Web):November 20, 2019
https://doi.org/10.1021/acs.iecr.9b04780
Copyright © 2019 American Chemical Society

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    Abstract

    Abstract Image

    Titanium dioxide-supported manganese oxide and cerium oxide noted as MnOx/TiO2, CeO2/TiO2, and MnOx–CeO2/TiO2 were prepared by sol–gel method and their low-temperature (<200 °C) catalytic activity toward selective catalytic reduction (SCR) of NO with NH3 were evaluated. The MnOx–CeO2/TiO2 catalyst exhibited optimal low-temperature performance that is nearly 98% of NO was abated below 200 °C. That is because MnOx/TiO2 combined with CeO2 improves redox ability and surface acidity of the catalyst, mainly due to the incorporation of Mn atoms into bulk CeO2 that creates active Mn–O–Ce structures. In situ Fourier transform infrared (FTIR) spectroscopy suggested that the coordinated NH3 on Lewis acid sites were favored to react with NO and the NH3-SCR over MnOx–CeO2/TiO2 catalyst mainly followed the E–R mechanism at 200 °C. Furthermore, the reaction rate constant and apparent activation energy of the NH3-SCR reaction on the MnOx–CeO2/TiO2 catalyst confirmed the promotional effects of Ce addition on the activity of Mn-based catalyst.

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