ACS Publications. Most Trusted. Most Cited. Most Read

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Inorg. Chem. 2020, 59, 17, 12858-12866
RETURN TO ISSUEPREVArticleNEXT

Structural Diversity in Layered Hybrid Perovskites, A2PbBr4 or AA′PbBr4, Templated by Small Disc-Shaped Amines

  • Yuan-Yuan Guo
    Yuan-Yuan Guo
    School of Chemistry and EaStChem, University of St. Andrews, St. Andrews KY16 9ST, United Kingdom
    More by Yuan-Yuan Guo
    Orcidhttp://orcid.org/0000-0002-0618-1709
  • , 
  • Lin-Jie Yang
    Lin-Jie Yang
    School of Chemistry and EaStChem, University of St. Andrews, St. Andrews KY16 9ST, United Kingdom
    More by Lin-Jie Yang
  • , 
  • Simon Biberger
    Simon Biberger
    Soft Matter Optoelectronics, Department of Physics, University of Bayreuth, Bayreuth 95440, Germany
    More by Simon Biberger
  • , 
  • Jason A. McNulty
    Jason A. McNulty
    School of Chemistry and EaStChem, University of St. Andrews, St. Andrews KY16 9ST, United Kingdom
    More by Jason A. McNulty
    Orcidhttp://orcid.org/0000-0003-4630-7086
  • , 
  • Teng Li
    Teng Li
    School of Chemistry and EaStChem, University of St. Andrews, St. Andrews KY16 9ST, United Kingdom
    More by Teng Li
  • , 
  • Konstantin Schötz
    Konstantin Schötz
    Soft Matter Optoelectronics, Department of Physics, University of Bayreuth, Bayreuth 95440, Germany
    More by Konstantin Schötz
  • , 
  • Fabian Panzer
    Fabian Panzer
    Soft Matter Optoelectronics, Department of Physics, University of Bayreuth, Bayreuth 95440, Germany
    More by Fabian Panzer
    Orcidhttp://orcid.org/0000-0002-2191-9011
  • , and 
  • Philip Lightfoot*
    Philip Lightfoot
    School of Chemistry and EaStChem, University of St. Andrews, St. Andrews KY16 9ST, United Kingdom
    *Email: [email protected]
    More by Philip Lightfoot
    Orcidhttp://orcid.org/0000-0001-7048-3982
Cite this: Inorg. Chem. 2020, 59, 17, 12858–12866
Publication Date (Web):August 11, 2020
https://doi.org/10.1021/acs.inorgchem.0c01807
Copyright © 2020 American Chemical Society
Request reuse permissions

    Article Views

    1304

    Altmetric

    -

    Citations

    24
    LEARN ABOUT THESE METRICS
    Read OnlinePDF (3 MB)
    Get e-Alerts
    Supporting Info (2)»
    SUBJECTS:

    Abstract

    Abstract Image

    We present three new hybrid layered lead(II) bromide perovskites of generic composition A2PbBr4 or AA′PbBr4 that exhibit three distinct structure types. [TzH]2PbBr4 ([TzH+] = 1,2,4-triazolium) adopts a (001)-oriented layer structure and [AaH]2PbBr4, ([AaH+] = acetamidinium) adopts a (110)-oriented type, whereas [ImH][TzH]PbBr4, ([ImH+] = imidazolium) adopts a rare (110)-oriented structure with enhanced corrugation (i.e., 3 × 3 type). The crystal structures of each are discussed in terms of the differing nature of the templating molecular species. Photoluminescent spectra for each are reported and the behaviors discussed in relation to the different structure of each composition.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c01807.

    • Crystallographic data at 173 K, hydrogen-bonding details, octahedral distortion parameters, brief review of (110)-oriented layered perovskite unit-cell details (PDF)

    • ISODISTORT mode amplitudes for T2PbBr4 (PDF)

    Accession Codes

    CCDC 1985833–1985838 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 24 publications.

    1. Hao A. Nguyen, Grant Dixon, Florence Y. Dou, Shaun Gallagher, Stephen Gibbs, Dylan M. Ladd, Emanuele Marino, Justin C. Ondry, James P. Shanahan, Eugenia S. Vasileiadou, Stephen Barlow, Daniel R. Gamelin, David S. Ginger, David M. Jonas, Mercouri G. Kanatzidis, Seth R. Marder, Daniel Morton, Christopher B. Murray, Jonathan S. Owen, Dmitri V. Talapin, Michael F. Toney, Brandi M. Cossairt. Design Rules for Obtaining Narrow Luminescence from Semiconductors Made in Solution. Chemical Reviews 2023, 123 (12) , 7890-7952. https://doi.org/10.1021/acs.chemrev.3c00097
    2. Qiang-Qiang Jia, Meng-Meng Lun, Gele Teri, Li-Yan Xie, Da-Wei Fu, Qiang Guo. Fluorescence Emission Is Highly Structure-Dependent in Hybrid Lead Halides. Inorganic Chemistry 2023, 62 (19) , 7186-7194. https://doi.org/10.1021/acs.inorgchem.2c04267
    3. Ping Fu, Michael A. Quintero, Claire Welton, Xiaotong Li, Bruno Cucco, Michael C. De Siena, Jacky Even, George Volonakis, Mikaël Kepenekian, Runze Liu, Craig C. Laing, Vladislav Klepov, Yukun Liu, Vinayak P. Dravid, G. N. Manjunatha Reddy, Can Li, Mercouri G. Kanatzidis. Short Aromatic Diammonium Ions Modulate Distortions in 2D Lead Bromide Perovskites for Tunable White-Light Emission. Chemistry of Materials 2022, 34 (21) , 9685-9698. https://doi.org/10.1021/acs.chemmater.2c02471
    4. Xiang-Bin Han, Chang-Qing Jing, Hui-Yuan Zu, Wen Zhang. Structural Descriptors to Correlate Pb Ion Displacement and Broadband Emission in 2D Halide Perovskites. Journal of the American Chemical Society 2022, 144 (40) , 18595-18606. https://doi.org/10.1021/jacs.2c08364
    5. Xiaotong Li, Hao Dong, George Volonakis, Constantinos C. Stoumpos, Jacky Even, Claudine Katan, Peijun Guo, Mercouri G. Kanatzidis. Ordered Mixed-Spacer 2D Bromide Perovskites and the Dual Role of 1,2,4-Triazolium Cation. Chemistry of Materials 2022, 34 (14) , 6541-6552. https://doi.org/10.1021/acs.chemmater.2c01432
    6. Maroua Ben Haj Salah, Nicolas Mercier, Magali Allain, Antonin Leblanc, Jens Dittmer, Chiara Botta, Claudio Quarti, Claudine Katan. Synthesis and Characterization of (FA)3(HEA)2Pb3I11: A Rare Example of <1 1 0>-Oriented Multilayered Halide Perovskites. Chemistry of Materials 2022, 34 (13) , 5780-5790. https://doi.org/10.1021/acs.chemmater.2c00130
    7. Ceng Han, Alasdair J. Bradford, Jason A. McNulty, Weiguo Zhang, P. Shiv Halasyamani, Alexandra M. Z. Slawin, Finlay D. Morrison, Stephen L. Lee, Philip Lightfoot. Polarity and Ferromagnetism in Two-Dimensional Hybrid Copper Perovskites with Chlorinated Aromatic Spacers. Chemistry of Materials 2022, 34 (5) , 2458-2467. https://doi.org/10.1021/acs.chemmater.2c00107
    8. Ceng Han, Jason A. McNulty, Alasdair J. Bradford, Alexandra M. Z. Slawin, Finlay D. Morrison, Stephen L. Lee, Philip Lightfoot. Polar Ferromagnet Induced by Fluorine Positioning in Isomeric Layered Copper Halide Perovskites. Inorganic Chemistry 2022, 61 (7) , 3230-3239. https://doi.org/10.1021/acs.inorgchem.1c03726
    9. Eugenia S. Vasileiadou, Ido Hadar, Mikaël Kepenekian, Jacky Even, Qing Tu, Christos D. Malliakas, Daniel Friedrich, Ioannis Spanopoulos, Justin M. Hoffman, Vinayak P. Dravid, Mercouri G. Kanatzidis. Shedding Light on the Stability and Structure–Property Relationships of Two-Dimensional Hybrid Lead Bromide Perovskites. Chemistry of Materials 2021, 33 (13) , 5085-5107. https://doi.org/10.1021/acs.chemmater.1c01129
    10. Meng Sun, Shu Zhang, Kai-Yao Wang, Juan Wang, Lin Cheng, Jia-Ying Zhu, Yi-Ming Zhao, Cheng Wang. Mixed Solvothermal Synthesis of Tn Cluster-Based Indium and Gallium Sulfides Using Versatile Ammonia or Amine Structure-Directing Agents. Inorganic Chemistry 2021, 60 (10) , 7115-7127. https://doi.org/10.1021/acs.inorgchem.1c00171
    11. Xiaotong Li, Justin M. Hoffman, Mercouri G. Kanatzidis. The 2D Halide Perovskite Rulebook: How the Spacer Influences Everything from the Structure to Optoelectronic Device Efficiency. Chemical Reviews 2021, 121 (4) , 2230-2291. https://doi.org/10.1021/acs.chemrev.0c01006
    12. Hai Zhang, Peijie Zhang, Chenlong Xie, Jiang Han, Bin Xu, Zewei Quan. Distinct Excitonic Emissions in 2D (C 7 H 7 N 2 ) 2 PbX 4 (X = Cl, Br) under Compression. Advanced Science 2023, 3 https://doi.org/10.1002/advs.202305597
    13. Dawid Drozdowski, Katarzyna Fedoruk, Adam Kabanski, Mirosław Maczka, Adam Sieradzki, Anna Gagor. Broadband yellow and white emission from large octahedral tilting in (110)-oriented layered perovskites: imidazolium-methylhydrazinium lead halides. Journal of Materials Chemistry C 2023, 11 (14) , 4907-4915. https://doi.org/10.1039/D3TC00401E
    14. Hyun‐Jong Lee, Eunji Lee, Ji‐Hyun Cha, Duk‐Young Jung. Acetamidinium bromoplumbate CH 3 C ( NH 2 ) 2 PbBr 3 with 4H BaRuO 3 structure. Bulletin of the Korean Chemical Society 2023, 44 (3) , 230-235. https://doi.org/10.1002/bkcs.12660
    15. Kaiyue Song, Binjun Chen, Xiaoli Lin, Hailong Yang, Yue Liu, Yuanzheng Liu, Haohong Li, Zhirong Chen. Thermal Enhanced Resistive Switching Performance of ‐oriented Perovskite [(TZ‐H) 2 (PbBr 4 )] n with High Working Temperature: a Triazolium/(PbBr 4 ) n 2 n – Interfacial Interaction Insight. Advanced Electronic Materials 2022, 8 (11) https://doi.org/10.1002/aelm.202200537
    16. Congcong Chen, Emily E. Morgan, Yang Liu, Jian Chen, Ram Seshadri, Lingling Mao. “Breathing” organic cation to stabilize multiple structures in low-dimensional Ge-, Sn-, and Pb-based hybrid iodide perovskites. Inorganic Chemistry Frontiers 2022, 9 (19) , 4892-4898. https://doi.org/10.1039/D2QI01247B
    17. Ethan J. Crace, Alexander C. Su, Hemamala I. Karunadasa. Reliably obtaining white light from layered halide perovskites at room temperature. Chemical Science 2022, 13 (34) , 9973-9979. https://doi.org/10.1039/D2SC02381D
    18. Yuanqi Lan, Qi Yan, Xinyuan Zhang, Wenjiao Yao, Chenchen Wang, Chun-Sing Lee, Philip Lightfoot, Yongbing Tang. Perovskite-derived structure modulation in the iron sulfate family. Chemical Communications 2022, 58 (50) , 7074-7077. https://doi.org/10.1039/D2CC02242G
    19. Clement Elliott, Jason A. McNulty, David B. Cordes, Alexandra M.Z. Slawin, Philip Lightfoot. Structural diversity in hybrid lead halides templated by 4-methylimidazolium. Journal of Solid State Chemistry 2021, 303 , 122466. https://doi.org/10.1016/j.jssc.2021.122466
    20. Yuan‐Yuan Guo, Clement Elliott, Jason A. McNulty, David B. Cordes, Alexandra M. Z. Slawin, Philip Lightfoot. New Variants of (110)‐Oriented Layered Lead Bromide Perovskites, Templated by Formamidinium or Pyrazolium. European Journal of Inorganic Chemistry 2021, 2021 (33) , 3404-3411. https://doi.org/10.1002/ejic.202100433
    21. Hayden A. Evans, Lingling Mao, Ram Seshadri, Anthony K. Cheetham. Layered Double Perovskites. Annual Review of Materials Research 2021, 51 (1) , 351-380. https://doi.org/10.1146/annurev-matsci-092320-102133
    22. Jason A. McNulty, Philip Lightfoot. Structural chemistry of layered lead halide perovskites containing single octahedral layers. IUCrJ 2021, 8 (4) , 485-513. https://doi.org/10.1107/S2052252521005418
    23. Yuan-Yuan Guo, Lin-Jie Yang, Jason A. McNulty, Alexandra M. Z. Slawin, Philip Lightfoot. Structural variations in (001)-oriented layered lead halide perovskites, templated by 1,2,4-triazolium. Dalton Transactions 2020, 49 (47) , 17274-17280. https://doi.org/10.1039/D0DT02936J
    24. Jason A. McNulty, Alexandra M. Z. Slawin, Philip Lightfoot. Variable dimensionality in ‘hollow’ hybrid tin iodide perovskites. Dalton Transactions 2020, 49 (43) , 15171-15174. https://doi.org/10.1039/D0DT03449E
    Download PDF

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect