Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
Self-assembly of a Mixed Valence Copper Triangular Prism and Transformation to Cage Triggered by an External Stimulus

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Inorg. Chem. 2020, 59, 23, 17374-17378
    Article

    Self-assembly of a Mixed Valence Copper Triangular Prism and Transformation to Cage Triggered by an External Stimulus
    Click to copy article linkArticle link copied!

    • Ya-Liang Lai
      Ya-Liang Lai
      College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, Guangdong 510632, P. R. China
      More by Ya-Liang Lai
    • Xue-Zhi Wang
      Xue-Zhi Wang
      College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, Guangdong 510632, P. R. China
      More by Xue-Zhi Wang
    • Xian-Chao Zhou
      Xian-Chao Zhou
      College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, Guangdong 510632, P. R. China
      More by Xian-Chao Zhou
    • Rui-Rong Dai
      Rui-Rong Dai
      College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, Guangdong 510632, P. R. China
      More by Rui-Rong Dai
    • Xiao-Ping Zhou*
      Xiao-Ping Zhou
      College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, Guangdong 510632, P. R. China
      *Email: [email protected]
      More by Xiao-Ping Zhou
      Orcidhttp://orcid.org/0000-0002-0351-7326
    • Dan Li
      Dan Li
      College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, Guangdong 510632, P. R. China
      More by Dan Li
      Orcidhttp://orcid.org/0000-0002-4936-4599
    Other Access OptionsSupporting Information (1)

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2020, 59, 23, 17374–17378
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.0c02682
    Published November 10, 2020
    Copyright © 2020 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    A triangular prismatic metal–organic cage based on mixed valence copper ions has been designed and synthesized by using metallocycle panels and pillar ligands. The triangular prism will be quickly transformed to a 10-nuclear cage upon an external chemical stimulus, which features a bicapped square antiprism structure. This prismatic cage can act as a catalyst for oxidation of aromatic alcohols to their corresponding aromatic aldehydes with high yields at room temperature under O2 atmosphere.

    Copyright © 2020 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02682.

    • Experimental characterizations, additional structural presentations, and FT-IR, PXRD, and ESI-MS analyses (PDF)

    Accession Codes

    CCDC 2011494 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 14 publications.

    1. Zhixuan An, Xiaohui Li, Zhong Zhang, Xiuli Wang. Capped Polyoxometalate-Based Metal–Organic Complex with Mixed-Valence CuI/CuII for Synergistic Catalytic Synthesis of p-Benzoquinone. Inorganic Chemistry 2024, Article ASAP.
    2. Jack A. Davies, Tanya K. Ronson, Jonathan R. Nitschke. Triamine and Tetramine Edge-Length Matching Drives Heteroleptic Triangular and Tetragonal Prism Assembly. Journal of the American Chemical Society 2024, 146 (8) , 5215-5223. https://doi.org/10.1021/jacs.3c11320
    3. Dong-Nan Yu, Zi-Xuan Yao, Fahime Bigdeli, Xue-Mei Gao, Xun Cheng, Jing-Zhe Li, Jing-Wen Zhang, Wei Wang, Zong-Jie Guan, Yongfeng Bu, Kuan-Guan Liu, Ali Morsali. Synthesis and Study of Photothermal Properties of a Mixed-Valence Nanocluster CuI/CuII with Strong near-Infrared Optical Absorption Supported by 4-tert-Butylcalix[4]arene Ligand. Inorganic Chemistry 2023, 62 (1) , 401-407. https://doi.org/10.1021/acs.inorgchem.2c03501
    4. Charlie T. McTernan, Jack A. Davies, Jonathan R. Nitschke. Beyond Platonic: How to Build Metal–Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes. Chemical Reviews 2022, 122 (11) , 10393-10437. https://doi.org/10.1021/acs.chemrev.1c00763
    5. Joseph Ricardo-Noordberg, Saeid Kamal, Marek Majewski. Molecular copper(I)‐sensitized photoanodes for alcohol oxidation under ambient conditions. ChemSusChem 2024, https://doi.org/10.1002/cssc.202400611
    6. Ya‐Liang Lai, Mo Xie, Xian‐Chao Zhou, Xue‐Zhi Wang, Xiao‐Wei Zhu, Dong Luo, Xiao‐Ping Zhou, Dan Li. Precise Post‐Synthetic Modification of Heterometal‐Organic Capsules for Selectively Encapsulating Tetrahedral Anions. Angewandte Chemie 2024, 136 (20) https://doi.org/10.1002/ange.202402829
    7. Ya‐Liang Lai, Mo Xie, Xian‐Chao Zhou, Xue‐Zhi Wang, Xiao‐Wei Zhu, Dong Luo, Xiao‐Ping Zhou, Dan Li. Precise Post‐Synthetic Modification of Heterometal‐Organic Capsules for Selectively Encapsulating Tetrahedral Anions. Angewandte Chemie International Edition 2024, 63 (20) https://doi.org/10.1002/anie.202402829
    8. Huirong Ma, Liangchen Liu, Yuluan Liao, Huatian Shi, Po Sun, Weibin Yu. An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues. Inorganic Chemistry Frontiers 2024, 11 (9) , 2590-2597. https://doi.org/10.1039/D4QI00343H
    9. Albert A. Shteinman. Metallocavitins as Advanced Enzyme Mimics and Promising Chemical Catalysts. Catalysts 2023, 13 (2) , 415. https://doi.org/10.3390/catal13020415
    10. Ran Chen, Qian-Qian Yan, Shao-Jun Hu, Xiao-Qing Guo, Li-Peng Zhou, Qing-Fu Sun. Dinuclear mono-bridged or polymeric lanthanide complexes from one ligand: structural transformation and chiral induction. Dalton Transactions 2022, 52 (1) , 37-43. https://doi.org/10.1039/D2DT03351H
    11. Jinjin Liu, Zhifang Wang, Peng Cheng, Michael J. Zaworotko, Yao Chen, Zhenjie Zhang. Post-synthetic modifications of metal–organic cages. Nature Reviews Chemistry 2022, 6 (5) , 339-356. https://doi.org/10.1038/s41570-022-00380-y
    12. Zi-Xuan Yao, Jing-Zhe Li, Hao-Hai Wang, Xun Cheng, Lin-Lin Hou, Dong-Nan Yu, Delun Chen, Wen-Yan Dan, Kuan-Guan Liu. Construction of eight mixed-valence pentanuclear CuI4Cu II clusters using ligands with inhomogeneous electron density distribution: synthesis, characterization and photothermal properties. Dalton Transactions 2022, 51 (15) , 6053-6060. https://doi.org/10.1039/D2DT00658H
    13. Wenjian Zhou, Xinrui Xiao, Yonghong Liu, Xu Zhang. Magnetic Se/Fe/PCN-Catalyzed Oxidative Cracking Alkenes in O 2. Chinese Journal of Organic Chemistry 2022, 42 (6) , 1849. https://doi.org/10.6023/cjoc202201023
    14. Ran Chen, Qian-Qian Yan, Shao-Jun Hu, Xiao-Qing Guo, Li-Xuan Cai, Dan-Ni Yan, Li-Peng Zhou, Qing-Fu Sun. Dinuclear helicate or mononuclear pincer lanthanide complexes from one ligand: stereo-controlled assembly and catalysis. Organic Chemistry Frontiers 2021, 8 (11) , 2576-2582. https://doi.org/10.1039/D1QO00369K
    Download PDF
    Go to Inorganic Chemistry
    Get e-Alerts
    Get e-Alerts

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2020, 59, 23, 17374–17378
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.0c02682
    Published November 10, 2020
    Copyright © 2020 American Chemical Society
    Request reuse permissions

    Article Views

    1828

    Altmetric

    -

    Citations

    14
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.