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Download Hi-Res ImageDownload to MS-PowerPointCite This:Inorg. Chem. 2021, 60, 4, 2105-2111
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Conjugated-Polypyridine-Derivative-Derived Semiconductive Iodoplumbates with Tunable Architectures and Efficient Visible-Light-Induced Photocatalytic Property

  • Chen Li
    Chen Li
    College of Chemistry and Chemical Engineering, Qingdao University, Qingdao, Shandong 266071, P. R. China
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  • , 
  • Kui Wang
    Kui Wang
    College of Chemistry and Chemical Engineering, Qingdao University, Qingdao, Shandong 266071, P. R. China
    More by Kui Wang
  • , 
  • Xin-Yu Li
    Xin-Yu Li
    College of Chemistry and Chemical Engineering, Qingdao University, Qingdao, Shandong 266071, P. R. China
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  • , 
  • Xiao-Fan Jiang
    Xiao-Fan Jiang
    College of Chemistry and Chemical Engineering, Qingdao University, Qingdao, Shandong 266071, P. R. China
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  • , 
  • Qi Wei
    Qi Wei
    College of Chemistry and Chemical Engineering, Qingdao University, Qingdao, Shandong 266071, P. R. China
    More by Qi Wei
    Orcidhttp://orcid.org/0000-0003-0049-308X
  • , 
  • Jin-Hua Li*
    Jin-Hua Li
    College of Chemistry and Chemical Engineering, Qingdao University, Qingdao, Shandong 266071, P. R. China
    *Email: [email protected]
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    Orcidhttp://orcid.org/0000-0001-7352-9333
  • , and 
  • Guo-Ming Wang
    Guo-Ming Wang
    College of Chemistry and Chemical Engineering, Qingdao University, Qingdao, Shandong 266071, P. R. China
    More by Guo-Ming Wang
    Orcidhttp://orcid.org/0000-0003-0156-904X
Cite this: Inorg. Chem. 2021, 60, 4, 2105–2111
Publication Date (Web):January 28, 2021
https://doi.org/10.1021/acs.inorgchem.0c03665
Copyright © 2021 American Chemical Society
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    Abstract

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    By mediation of the pH values, three novel inorganic–organic iodoplumbate hybrids, [Me3TPT][Pb3I9] [1; Me3TPT = trimethyl-2,4,6-tris(4-pyridyl)-1,3,5-triazine], [Me3TPT]2[Pb9I24] (2), and [Me3TPT]2[Pb19I44] (3), have been achieved under solvothermal conditions. The large conjugated in situ N-alkylation polypyridine derivatives act as structure-directing agents and electron acceptors, making the materials feature adjustable structural variations with 0D, 1D, and 2D structures and a potential semiconductive performance with narrow energy gaps (1.72, 1.80, and 1.78 eV for 1–3, respectively), which result in their efficient photocatalytic activity under visible-light irradiation. Theoretical calculation reveals that the conjugated organic moieties greatly contribute to the conduction band, leading to narrow band gaps. It is expected that the work will contribute to the exploitation of novel semiconducting halometallates by employing conjugated organic species as structure-directing agents.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c03665.

    • Atomic coordinates and equivalent isotropic displacement parameters of 1–3, detailed in situ N-methylation of TPT, simulated and measured PXRD patterns, and IR and absorption spectra, linear relationship of ln(C0/C), and TGA curve (PDF)

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    CCDC 2047292–2047294 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

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    Cited By

    This article is cited by 9 publications.

    1. Eugenia S. Vasileiadou, Imra S. Tajuddin, Michael C. De Siena, Vladislav V. Klepov, Mikaël Kepenekian, George Volonakis, Jacky Even, Lukasz Wojtas, Ioannis Spanopoulos, Xiuquan Zhou, Abishek K. Iyer, Julie L. Fenton, William R. Dichtel, Mercouri G. Kanatzidis. Novel 3D Cubic Topology in Hybrid Lead Halides with a Symmetric Aromatic Triammonium Exhibiting Water Stability. Chemistry of Materials 2023, 35 (14) , 5267-5280. https://doi.org/10.1021/acs.chemmater.3c00164
    2. Zi-You Ran, Xing Liu, Chun-Mei Huang, Jian Zhou. Electro-catalytic Iodoplumbate Incorporating Two Types of Polymeric Anions. Inorganic Chemistry 2023, 62 (22) , 8647-8654. https://doi.org/10.1021/acs.inorgchem.3c00778
    3. Jingyan Liu, Xianghong Zhang, Jiangyan Zhang, Shuquan Zhang, Yong Chen, Hongming Chen, Huipeng Chen, Meijin Lin. Interpenetration of Donor–Acceptor Hybrid Frameworks for Highly Sensitive Thermal Sensors. ACS Applied Materials & Interfaces 2022, 14 (21) , 24575-24582. https://doi.org/10.1021/acsami.2c03578
    4. Hong-Mei Pan, Kai Xu, Fan-Lei Meng, Hui Ge, Xu Yin, Xiao-Min Wu, Xiao-Wu Lei, Zhi-Hong Jing, Cheng-Yang Yue. Three-Dimensional Cuprous Iodide Framework with Intrinsic Broadband Red-to-Near-Infrared Light Emission. Inorganic Chemistry 2021, 60 (22) , 16906-16910. https://doi.org/10.1021/acs.inorgchem.1c02330
    5. P.S. Nandisha, Sowbhagya, S. Yallappa. Synthesis and characterization of ternary NiO@Bi2MoO6–MoS heterojunction with enhanced photodegradation efficiency towards indigo carmine dye. Solid State Sciences 2023, 139 , 107157. https://doi.org/10.1016/j.solidstatesciences.2023.107157
    6. Li‐Juan Feng, Yan‐Yu Zhao, Ru‐Yang Song, Cheng‐Yang Yue. Organic‐Inorganic Hybrid Low‐dimensional Lead Iodides with Broadband Yellow to Red Light Emissions. Zeitschrift für anorganische und allgemeine Chemie 2022, 648 (7) https://doi.org/10.1002/zaac.202100284
    7. Meng-Ru Li, Yue Jin, Hao Chen, Rui-Rui Jing, Ning Zhao, Zhao-Xun Lian. The hybridizaiton of iodoplumbate with xanthene dye: white emission and high photocurrent response driven by strong organic/inorganic interactions. Inorganic and Nano-Metal Chemistry 2022, 36 , 1-8. https://doi.org/10.1080/24701556.2021.2025104
    8. Jian-Jun Liu, Chixian He, Teng Liu, Jiaming Liu, Shu-Biao Xia. Two photochromic hybrid materials assembled from naphthalene diimide as photocatalysts for the degradation of carcinogenic dye basic red 9 under visible light. Journal of Molecular Structure 2021, 1243 , 130804. https://doi.org/10.1016/j.molstruc.2021.130804
    9. Yu‐Tong Zhang, Jia‐Xin Ruan, Dong‐Sheng Ma, Jin‐Sheng Gao, Guang Wu, Yi‐Fu Liu, Ying‐Hui Yu. Two fluorescent copper phosphonate complexes for sensing antibiotics, ketones and Fe 3+ in water. Zeitschrift für anorganische und allgemeine Chemie 2021, 647 (20-21) , 1954-1966. https://doi.org/10.1002/zaac.202100213
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