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Solvation-Anionic Exchange Mechanism of Solvent Extraction: Enhanced U(VI) Uptake by Tetradentate Phenanthroline Ligands
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    Solvation-Anionic Exchange Mechanism of Solvent Extraction: Enhanced U(VI) Uptake by Tetradentate Phenanthroline Ligands
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    • Svetlana V. Gutorova
      Svetlana V. Gutorova
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
    • Petr I. Matveev
      Petr I. Matveev
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
    • Pavel S. Lemport
      Pavel S. Lemport
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
    • Daniil A. Novichkov
      Daniil A. Novichkov
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
    • Igor P. Gloriozov
      Igor P. Gloriozov
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
    • Nane A. Avagyan
      Nane A. Avagyan
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
    • Alexey O. Gudovannyy
      Alexey O. Gudovannyy
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
    • Yulia V. Nelyubina
      Yulia V. Nelyubina
      A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova Street, 28, Moscow 119991, Russia
    • Vitaly A. Roznyatovsky
      Vitaly A. Roznyatovsky
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
    • Vladimir G. Petrov
      Vladimir G. Petrov
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
    • Konstantin A. Lyssenko
      Konstantin A. Lyssenko
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
      National Research University Higher School of Economics, Myasnitskaya Street, 20, Moscow 101000, Russia
    • Yuri A. Ustynyuk
      Yuri A. Ustynyuk
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
    • Stepan N. Kalmykov
      Stepan N. Kalmykov
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
    • Valentine G. Nenajdenko*
      Valentine G. Nenajdenko
      Department of Chemistry, Lomonosov Moscow State University, Leninskie gory 1 Bld. 3, Moscow 119991, Russia
      *Email: [email protected]
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2023, 62, 1, 487–496
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    https://doi.org/10.1021/acs.inorgchem.2c03571
    Published December 21, 2022
    Copyright © 2022 American Chemical Society

    Abstract

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    Phenanthroline diamides (L) demonstrated a unique ability to extract uranium from nitric acid solutions into a polar organic solvent forming complexes of 1:2 stoichiometry as tight ion pairs {[UO2LNO3]+[UO2(NO3)3]} by a novel extraction mechanism, which is a combination of two already well-known mechanisms: solvation and ion-pair anion exchange. A UV–vis study was used to confirm the formation of such complexes directly in the organic phase. Moreover, chemical synthesis and single crystal growth were performed to confirm unambiguously the structure of the complexes in the solid state.

    Copyright © 2022 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c03571.

    • Additional solvent extraction experiments; NMR and IR spectra of synthesized compounds; and quantum chemical calculation details (PDF)

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    CCDC 2192847, 2193651, and 2194050 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

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    This article is cited by 10 publications.

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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2023, 62, 1, 487–496
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.2c03571
    Published December 21, 2022
    Copyright © 2022 American Chemical Society

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