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Neutral Phosphorus-Based Beryllium Scorpionate Complexes as Spectroscopic Probes for Base Strength and Electron Donation

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    Neutral Phosphorus-Based Beryllium Scorpionate Complexes as Spectroscopic Probes for Base Strength and Electron Donation
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2024, 63, 51, 24392–24399
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    https://doi.org/10.1021/acs.inorgchem.4c04565
    Published December 8, 2024
    Copyright © 2024 The Authors. Published by American Chemical Society
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    Abstract

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    The synthesis and properties of tris(diisopropylphosphanylmethyl)phenylborate ([TP(iPr)]−) beryllium complexes [TP(iPr)]BeL with L = Cl, Br, I, CN, SCN, OCN, N3, and CF3SO3 are described. In these compounds, the 1JPBe NMR coupling constant can be used as a sensitive probe for the basicity and electron-donating properties of the L– anions in solution.

    Copyright © 2024 The Authors. Published by American Chemical Society

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    Deposition Numbers 2389610–2389616 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via the joint Cambridge Crystallographic Data Centre (CCDC) and Fachinformationszentrum Karlsruhe Access Structures service.

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    This article is cited by 1 publications.

    1. Chantsalmaa Berthold, Mark H. Lochte, Magnus Richard Buchner. Transmetalation from Boron to Beryllium in Phosphorus‐Based Scorpionate Complexes. Chemistry – A European Journal 2025, https://doi.org/10.1002/chem.202500673
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2024, 63, 51, 24392–24399
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.4c04565
    Published December 8, 2024
    Copyright © 2024 The Authors. Published by American Chemical Society
    Request reuse permissions

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