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Synthesis of Heavy Cyclodipnictadiphosphanes [ClE(μ-P-Ter)]2 [E = P, As, Sb, or Bi; Ter = 2,6-bis(2,4,6-trimethylphenyl)phenyl]

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    Synthesis of Heavy Cyclodipnictadiphosphanes [ClE(μ-P-Ter)]2 [E = P, As, Sb, or Bi; Ter = 2,6-bis(2,4,6-trimethylphenyl)phenyl]
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    † Department of Chemistry, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, U.K.
    ‡ Institut für Chemie, Abteilung Anorganische Chemie, Universität Rostock, Albert-Einstein-Straße 3a, 18059 Rostock, Germany
    § Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Abteilung Materialdesign, Albert-Einstein-Straße 29a, 18059 Rostock, Germany
    *E-mail: [email protected]
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2016, 55, 7, 3692–3699
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    https://doi.org/10.1021/acs.inorgchem.6b00218
    Published March 15, 2016
    Copyright © 2016 American Chemical Society
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    Abstract

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    A complete series of terphenyl-substituted 1,3-dichloro-1,3-dipnicta-2,4-diphosphanes {[ClE(μ-P-Ter)]2, where E = P, As, Sb, or Bi and Ter = 2,6-bis(2,4,6-trimethylphenyl)phenyl} was prepared and fully characterized. While the heavy derivatives with E = Sb or Bi can be accessed via conversion of silylated phosphanes with amino-dichloropnictanes and subsequent elimination of TerNH2, the lighter congeners could be prepared only by a metathesis reaction of [ClBi(μ-P-Ter)]2 with PCl3 and AsCl3. Spectroscopic and structural data indicate the existence of cis and trans isomers of [ClP(μ-P-Ter)]2 in contrast to all heavier derivatives, for which only the trans isomer was obtained.

    Copyright © 2016 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorgchem.6b00218.

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    Cited By

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    This article is cited by 24 publications.

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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2016, 55, 7, 3692–3699
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.6b00218
    Published March 15, 2016
    Copyright © 2016 American Chemical Society
    Request reuse permissions

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