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    Cluster Organic Frameworks Constructed from Heterometallic Supertetrahedral Cluster Secondary Building Units
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    † State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, People’s Republic of China
    ‡ State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350108, People’s Republic of China
    *E-mail for X.-X.L.: [email protected]
    *E-mail for S.-T.Z.: [email protected]
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2017, 56, 8, 4635–4642
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    https://doi.org/10.1021/acs.inorgchem.7b00267
    Published March 27, 2017
    Copyright © 2017 American Chemical Society
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    Abstract

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    The two novel cluster organic frameworks based on heterometallic supertetrahedral cluster secondary building units (SBUs) [Cd4Cu6(L)4(Ac)7(H2O)4](Ac)·7H2O (1) and [Mn4Cu6(L)4(Ac)4.5(H2O)9]CuCN(Ac)3.5·H2O (2), where H3L = 2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol and Ac = CH3COO–, have been prepared under solvothermal conditions. 1 and 2 are the first cases of cluster organic frameworks containing Cd-Cu/Mn-Cu heterometallic supertetrahedral cluster SBUs. Furthermore, 1 and 2 show an integration of magnetic properties and adsorption properties from both the heterometallic cluster secondary building units and the framework in a porous material.

    Copyright © 2017 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorgchem.7b00267.

    • Bond valence sum calculations for 1 and 2, additional structural figures, PXRD patterns, XPS spectrum, and TGA curves for complexes 1 and 2 (PDF)

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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2017, 56, 8, 4635–4642
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.7b00267
    Published March 27, 2017
    Copyright © 2017 American Chemical Society
    Request reuse permissions

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