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Synthesis of Manganese ZIF-8 from [Mn(BH4)2·3THF]·NaBH4

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    Synthesis of Manganese ZIF-8 from [Mn(BH4)2·3THF]·NaBH4
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    ∥ †Department of Molecular Engineering, Graduate School of Engineering, and ∥Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
    ‡ Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Institute for Advanced Study, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan
    § Department of Chemical and Biomolecular Engineering, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong 21210, Thailand
    *E-mail: [email protected]
    *E-mail: [email protected]
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2017, 56, 15, 8744–8747
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    https://doi.org/10.1021/acs.inorgchem.7b01322
    Published July 17, 2017
    Copyright © 2017 American Chemical Society
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    Abstract

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    Cubic and highly porous [Mn(2-methylimidazolate)2] (Mn-ZIF-8) was synthesized from [Mn(BH4)2·3THF]·NaBH4 under an Ar atmosphere. The structure contains rare Mn2+-4N tetrahedral geometry and has larger cell parameters, resulting in 20% larger amounts of gas uptake compared with [Zn(2-methylimidazolate)2]. A kinetically favored reaction using a reactive metal borohydride precursor is key for the construction of new metal–organic framework systems.

    Copyright © 2017 American Chemical Society

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorgchem.7b01322.

    • Experimental details and additional characterizations (PXRD, TGA, CO2 and O2 sorption, Rietveld refinement, and theoretical calculation) (PDF)

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    CCDC 1551898 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

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    Cited By

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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2017, 56, 15, 8744–8747
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.7b01322
    Published July 17, 2017
    Copyright © 2017 American Chemical Society
    Request reuse permissions

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