ACS Publications. Most Trusted. Most Cited. Most Read

OR SEARCH CITATIONS

My Activity
Recently Viewed
You have not visited any articles yet, Please visit some articles to see contents here.
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Inorg. Chem. 2017, 56, 18, 11104-11112
RETURN TO ISSUEPREVArticleNEXT

Open-Framework Manganese(II) and Cobalt(II) Borophosphates with Helical Chains: Structures, Magnetic, and Luminescent Properties

View Author Information
† Department of Chemistry, Iowa State University, Ames, Iowa 50011-3111, United States
‡ Ames Laboratory, U.S. Department of Energy, Iowa State University, Ames, Iowa 50011-3020, United States
§ Department of Materials and Environmental Chemistry, Stockholm University, Svante Arrhenius väg 16 C, 10691 Stockholm, Sweden
∥ Department of Materials Science and Engineering, Iowa State University, Ames, Iowa 50011-2300, United States
⊥ Department of Nanotechnology, Wrocław Research Centre EIT+, 147 Stabłowicka Street, 54-066 Wrocław, Poland
*E-mail: [email protected]
Cite this: Inorg. Chem. 2017, 56, 18, 11104–11112
Publication Date (Web):September 1, 2017
https://doi.org/10.1021/acs.inorgchem.7b01423
Copyright © 2017 American Chemical Society
RIGHTS & PERMISSIONS
Article Views
1030
Altmetric
-
Citations
15
LEARN ABOUT THESE METRICS
Read OnlinePDF (2 MB)
Get e-Alerts
Supporting Info (1)»
SUBJECTS:

Abstract

Abstract Image

Two borophosphates, (NH4)1–2xM1+x(H2O)2(BP2O8)·yH2O with M = Mn (I) and Co (II), synthesized hydrothermally crystallize in enantiomorphous space groups P6522 and P6122 with a = 9.6559(3) and 9.501(3) Å, c = 15.7939(6) and 15.582(4) Å, and V = 1275.3(1) and 1218.2(8) Å3 for I and II, respectively. Both compounds feature helical chains composed of vertex-sharing tetrahedral PO4 and BO4 groups that are connected through O atoms to transition-metal cations, Mn2+ and Co2+, respectively. For the two crystallographically distinct transition-metal cation sites present in the structure, this results in octahedral coordination with different degrees of distortion from the ideal symmetry. The crystal-field parameters, calculated from the corresponding absorption spectra, indicate that Mn2+ and Co2+ ions are located in a weak octahedral-like crystal field and suggest that the Co–ligand interactions are more covalent than the Mn–ligand ones. Luminescence measurements at room temperature reveal an orange emission that red-shifts upon lowering of the temperature to 77 K for I, while II is not luminescent. The luminescence lifetimes of I are 33.4 μs at room temperature and 1.87 ms at 77 K. Both compounds are Curie–Weiss paramagnets with negative Weiss constants and effective magnetic moments expected for noninteracting Mn2+ and Co2+ cations but no clear long-range magnetic order above 2 K.

Supporting Information

ARTICLE SECTIONS
Jump To

The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorgchem.7b01423.

  • Crystal photograph of II, powder XRD patterns, XPS, luminescence, IR, and Raman spectra for both compounds (PDF)

Accession Codes

CCDC 1551772–1551773 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

Terms & Conditions

Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

Cited By

This article is cited by 15 publications.

  1. Jan A. Zienkiewicz, Maciej Ptak, Dawid Drozdowski, Katarzyna Fedoruk, Mariusz Stefanski, Adam Pikul. Hybrid Organic–Inorganic Crystals of [Methylhydrazinium]MIICl3 (MII = Co, Ni, Mn). The Journal of Physical Chemistry C 2022, 126 (37) , 15809-15818. https://doi.org/10.1021/acs.jpcc.2c04893
  2. Stefanie Siebeneichler, Katharina V. Dorn, Volodymyr Smetana, Alexander Ovchinnikov, Anja-Verena Mudring. From a Dense Structure to Open Frameworks: The Structural Plethora of Alkali Metal Iron Fluorophosphates. Inorganic Chemistry 2022, 61 (25) , 9767-9775. https://doi.org/10.1021/acs.inorgchem.2c01205
  3. Guangmei Wang, Martin Valldor, Katharina V. Dorn, Magdalena Wilk-Kozubek, Volodymyr Smetana, Anja-Verena Mudring. Ionothermal Synthesis Enables Access to 3D Open Framework Manganese Phosphates Containing Extra-Large 18-Ring Channels. Chemistry of Materials 2019, 31 (18) , 7329-7339. https://doi.org/10.1021/acs.chemmater.9b01935
  4. Dagmara Stefańska. Effect of Organic Cation on Optical Properties of [A]Mn(H2POO)3 Hybrid Perovskites. Molecules 2022, 27 (24) , 8953. https://doi.org/10.3390/molecules27248953
  5. Mirosław Mączka, Dagmara Stefańska, Anna Gągor, Adam Pikul. The cation-dependent structural, magnetic and optical properties of a family of hypophosphite hybrid perovskites. Dalton Transactions 2021, 51 (1) , 352-360. https://doi.org/10.1039/D1DT03382D
  6. Jan Albert Zienkiewicz, Dorota Anna Kowalska, Katarzyna Fedoruk, Mariusz Stefanski, Adam Pikul, Maciej Ptak. Unusual isosymmetric order–disorder phase transition in a new perovskite-type dimethylhydrazinium manganese formate exhibiting weak ferromagnetism and photoluminescence properties. Journal of Materials Chemistry C 2021, 9 (21) , 6841-6851. https://doi.org/10.1039/D1TC01014J
  7. Mirosław Mączka, Dagmara Stefańska, Maciej Ptak, Anna Gągor, Adam Pikul, Adam Sieradzki. Cadmium and manganese hypophosphite perovskites templated by formamidinium cations: dielectric, optical and magnetic properties. Dalton Transactions 2021, 50 (7) , 2639-2647. https://doi.org/10.1039/D0DT03995K
  8. Tianyou Wang, Chao Wu, Lin Lin, Zhipeng Huang, Mark G. Humphrey, Chi Zhang. Synthesis, crystal structures and optical properties of open-framework gallium phosphates: NaGa3F4(PO4)2(H2O)2 and AGa2P2O7(OH)3(H2O) (A = K, Rb). Journal of Solid State Chemistry 2020, 288 , 121412. https://doi.org/10.1016/j.jssc.2020.121412
  9. Sebastian Bette, Jörg Stelzner, Gerhard Eggert, Thomas Schleid, Galina Matveeva, Ute Kolb, Robert E. Dinnebier. Korrosion von Kulturgut: Entdeckung einer kollagenartigen Tripelhelix in der Kristallstruktur von Calciumacetat‐Hemihydrat. Angewandte Chemie 2020, 132 (24) , 9525-9529. https://doi.org/10.1002/ange.202001609
  10. Sebastian Bette, Jörg Stelzner, Gerhard Eggert, Thomas Schleid, Galina Matveeva, Ute Kolb, Robert E. Dinnebier. Corrosion of Heritage Objects: Collagen‐Like Triple Helix Found in the Calcium Acetate Hemihydrate Crystal Structure. Angewandte Chemie International Edition 2020, 59 (24) , 9438-9442. https://doi.org/10.1002/anie.202001609
  11. Mirosław Mączka, Anna Gągor, Adam Pikul, Dagmara Stefańska. Novel hypophosphite hybrid perovskites of [CH 3 NH 2 NH 2 ][Mn(H 2 POO) 3 ] and [CH 3 NH 2 NH 2 ][Mn(H 2 POO) 2.83 (HCOO) 0.17 ] exhibiting antiferromagnetic order and red photoluminescence. RSC Advances 2020, 10 (32) , 19020-19026. https://doi.org/10.1039/D0RA03397A
  12. Mirosław Mączka, Dagmara Stefańska, Jan K. Zaręba, Marcin Nyk, Adam Sieradzki. Temperature-dependent luminescence and second-harmonic generation of perovskite-type manganese and cadmium dicyanamide frameworks templated by tetrapropylammonium cations. Journal of Alloys and Compounds 2020, 821 , 153464. https://doi.org/10.1016/j.jallcom.2019.153464
  13. Fatemeh Yaghoobi, Reza Karimi shervedani, Mostafa Torabi, Amirhosein Kefayat, Fatemeh Ghahremani, Amin Farzadniya. Therapeutic effect of deferrioxamine conjugated to PEGylated gold nanoparticles and complexed with Mn(II) beside the CT scan and MRI diagnostic studies. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2019, 583 , 123917. https://doi.org/10.1016/j.colsurfa.2019.123917
  14. Larisa Shvanskaya, Olga Yakubovich, Polina Krikunova, Evgeny Ovchenkov, Alexander Vasiliev. Chain caesium borophosphates with B:P ratio 1:2: synthesis, structure relationships and low-temperature thermodynamic properties. Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 2019, 75 (6) , 1174-1185. https://doi.org/10.1107/S2052520619013763
  15. Xiaoqiang Tong, Chaojie Jing, Zhaojun Dong, Na Zhang, Lijun Bi, Yanyan Wang, Hua Cai, Dongmin An, Xiaoxue Lian, Qiong Wang, Qingjun Zhou, Ying Guo, Yan Yan, Wenfu Yan. A chiral open-framework fluorinated cobalt phosphate consists of distorted F-encapsulated double 4-ring units with bulk homochirality. Chemical Communications 2019, 55 (2) , 226-228. https://doi.org/10.1039/C8CC07161F

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect

This website uses cookies to improve your user experience. By continuing to use the site, you are accepting our use of cookies. Read the ACS privacy policy.

CONTINUE