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Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations

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Departamento de Química Inorgánica, Universidad del País Vasco, UPV/EHU, Apartado 644, E-48080 Bilbao, Spain
Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, Spain
§ Instituto de Ciencia Molecular, Departamento de Quı́mica Inorgánica, Universidad de Valencia, C/Catedrático José Beltrán, 2. 46980 Paterna, Valencia, Spain
Departamento de Química Inorgánica, Universidad de Alcalá, Campus Universitario, E-28871 Alcalá de Henares, Spain
Departamento de Nanoestructuras, Superficies, Recubrimientos y Astrofísica Molecular, Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), 28049 Madrid, Spain
# Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, 28049 Madrid, Spain
*E-mail for E.D.: [email protected]
*E-mail for F.Z.: [email protected]
Cite this: Inorg. Chem. 2017, 56, 19, 11810–11818
Publication Date (Web):September 18, 2017
https://doi.org/10.1021/acs.inorgchem.7b01775
Copyright © 2017 American Chemical Society

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    Abstract

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    The use of theoretical calculations has allowed us to predict the coordination behavior of dithiolene [M(SC6H4S)2]2– (M = Ni, Pd, Pt) entities, giving rise to the first organometallic polymers {[K2(μ-H2O)2][Ni(SC6H4S)2]}n and {[K2(μ-H2O)2(thf)]2[K2(μ-H2O)2(thf)2][Pd3(SC6H4S)6]}n by one-pot reactions of the corresponding d10 metal salts, 1,2-benzenedithiolene, and KOH. The polymers are based on σ,π interactions between potassium atoms and [M(SC6H4S)2]2– (M = Ni, Pd) entities. In contrast, only σ interactions are observed when the analogous platinum derivative is used instead, yielding the coordination polymer {[K2(μ-thf)2][Pt(SC6H4S)2]}n.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorgchem.7b01775.

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    CCDC 15519421551944 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

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    This article is cited by 12 publications.

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