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Synthesis and Characterization of MgCr2S4 Thiospinel as a Potential Magnesium Cathode

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Inorg. Chem. 2018, 57, 14, 8634-8638
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    Synthesis and Characterization of MgCr2S4 Thiospinel as a Potential Magnesium Cathode
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    • Allison Wustrow
      Allison Wustrow
      Joint Center for Energy Storage Research (JCESR)  and  Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States
      More by Allison Wustrow
    • Baris Key
      Baris Key
      Joint Center for Energy Storage Research (JCESR), Northwestern University, Evanston, Illinois 60208, United States
      Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
      More by Baris Key
    • Patrick J. Phillips
      Patrick J. Phillips
      Joint Center for Energy Storage Research (JCESR), Northwestern University, Evanston, Illinois 60208, United States
      Department of Physics, University of Illinois at Chicago, Chicago, Illinois 60607, United States
      More by Patrick J. Phillips
    • Niya Sa
      Niya Sa
      Joint Center for Energy Storage Research (JCESR), Northwestern University, Evanston, Illinois 60208, United States
      Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
      More by Niya Sa
    • Andrew S. Lipton
      Andrew S. Lipton
      Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, Washington 99354, United States
      More by Andrew S. Lipton
    • Robert F. Klie
      Robert F. Klie
      Joint Center for Energy Storage Research (JCESR), Northwestern University, Evanston, Illinois 60208, United States
      Department of Physics, University of Illinois at Chicago, Chicago, Illinois 60607, United States
      More by Robert F. Klie
    • John T. Vaughey
      John T. Vaughey
      Joint Center for Energy Storage Research (JCESR), Northwestern University, Evanston, Illinois 60208, United States
      Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States
      More by John T. Vaughey
      Orcidhttp://orcid.org/0000-0002-2556-6129
    • Kenneth R. Poeppelmeier*
      Kenneth R. Poeppelmeier
      Joint Center for Energy Storage Research (JCESR)  and  Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States
      *E-mail: [email protected]
      More by Kenneth R. Poeppelmeier
      Orcidhttp://orcid.org/0000-0003-1655-9127
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2018, 57, 14, 8634–8638
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    https://doi.org/10.1021/acs.inorgchem.8b01417
    Published July 3, 2018
    Copyright © 2018 American Chemical Society
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    Abstract

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    Magnesium-ion batteries are a promising energy storage technology because of their higher theoretical energy density and lower cost of raw materials. Among the major challenges has been the identification of cathode materials that demonstrate capacities and voltages similar to lithium-ion systems. Thiospinels represent an attractive choice for new Mg-ion cathode materials owing to their interconnected diffusion pathways and demonstrated high cation mobility in numerous systems. Reported magnesium thiospinels, however, contain redox inactive metals such as scandium or indium, or have low voltages, such as MgTi2S4. This article describes the direct synthesis and structural and electrochemical characterization of MgCr2S4, a new thiospinel containing the redox active metal chromium and discusses its physical properties and potential as a magnesium battery cathode. However, as chromium(III) is quite stable against oxidation in sulfides, removing magnesium from the material remains a significant challenge. Early attempts at both chemical and electrochemical demagnesiation are discussed.

    Copyright © 2018 American Chemical Society

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorgchem.8b01417.

    • Complete diffraction patterns showing the effects of temperature and excess MgS on synthesis. Galvanostatic cycling of MgCr2S4 under various conditions. Diffraction patterns of cycled cathodes (PDF)

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    Cite this: Inorg. Chem. 2018, 57, 14, 8634–8638
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    https://doi.org/10.1021/acs.inorgchem.8b01417
    Published July 3, 2018
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