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Universal Single-Ion Physics in Spin–Orbit-Coupled d5 and d4 Ions

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Inorg. Chem. 2018, 57, 22, 14443-14449
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    Universal Single-Ion Physics in Spin–Orbit-Coupled d5 and d4 Ions
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    • Hongcheng Lu
      Hongcheng Lu
      Institute for Quantum Matter and Department of Physics and Astronomy, The Johns Hopkins University, Baltimore, Maryland 21218, United States
      More by Hongcheng Lu
      Orcidhttp://orcid.org/0000-0003-0414-4768
    • Juan R. Chamorro
      Juan R. Chamorro
      Institute for Quantum Matter and Department of Physics and Astronomy  and  Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21218, United States
      More by Juan R. Chamorro
    • Cheng Wan
      Cheng Wan
      Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21218, United States
      More by Cheng Wan
    • Tyrel M. McQueen*
      Tyrel M. McQueen
      Institute for Quantum Matter and Department of Physics and Astronomy,  Department of Chemistry  and  Department of Materials Science and Engineering, The Johns Hopkins University, Baltimore, Maryland 21218, United States
      *E-mail: [email protected] (T.M.M.).
      More by Tyrel M. McQueen
      Orcidhttp://orcid.org/0000-0002-8493-4630
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2018, 57, 22, 14443–14449
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    https://doi.org/10.1021/acs.inorgchem.8b02718
    Published November 5, 2018
    Copyright © 2018 American Chemical Society
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    Abstract

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    We have identified six new 4d4 and 4d5 compounds with isolated RuCl6 octahedra, with formulas (HMA)4RuCl6·Cl (1; MA = methylamine), (HGly)4RuCl6·Cl (2; gly = glycine), (HGly)3RuCl6·2H2O (3), (NH4)2RuCl6 (4), (HPy)2RuCl6 (5; py = pyridine), and H2(4,4′-bpy)RuCl6 (6; 4,4′-bpy = 4,4′-bipyridine). We find that the temperature-dependent magnetization is well described by single-ion physics in the presence of spin–orbit coupling and negligible superexchange interactions. Further, we find that many compounds in the literature are also well described by single-ion physics, and our results demonstrate the importance of considering single-ion physics when evaluating candidate geometric frustrated magnets in the presence of spin–orbit coupling.

    Copyright © 2018 American Chemical Society

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorgchem.8b02718.

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    CCDC 1546914–1546919 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

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    This article is cited by 25 publications.

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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2018, 57, 22, 14443–14449
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.8b02718
    Published November 5, 2018
    Copyright © 2018 American Chemical Society
    Request reuse permissions

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