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Facile Synthesis of Carbon Dots@2D MoS2 Heterostructure with Enhanced Photocatalytic Properties

  • Ning Li*
    Ning Li
    School of Energy and Power Engineering & School of Material Science and Engineering, North University of China, Taiyuan 030051, P. R. China
    State Key Lab of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, P. R. China
    *E-mail: [email protected]
    More by Ning Li
  • Zhengtang Liu
    Zhengtang Liu
    State Key Lab of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, P. R. China
  • Ming Liu
    Ming Liu
    School of Energy and Power Engineering & School of Material Science and Engineering, North University of China, Taiyuan 030051, P. R. China
    More by Ming Liu
  • Chaorui Xue
    Chaorui Xue
    School of Energy and Power Engineering & School of Material Science and Engineering, North University of China, Taiyuan 030051, P. R. China
    More by Chaorui Xue
  • Qing Chang*
    Qing Chang
    School of Energy and Power Engineering & School of Material Science and Engineering, North University of China, Taiyuan 030051, P. R. China
    *E-mail: [email protected]
    More by Qing Chang
  • Huiqi Wang
    Huiqi Wang
    School of Energy and Power Engineering & School of Material Science and Engineering, North University of China, Taiyuan 030051, P. R. China
    More by Huiqi Wang
  • Ying Li
    Ying Li
    School of Energy and Power Engineering & School of Material Science and Engineering, North University of China, Taiyuan 030051, P. R. China
    CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, P. R. China
    More by Ying Li
  • Zhenchao Song
    Zhenchao Song
    School of Energy and Power Engineering & School of Material Science and Engineering, North University of China, Taiyuan 030051, P. R. China
  • , and 
  • Shengliang Hu*
    Shengliang Hu
    School of Energy and Power Engineering & School of Material Science and Engineering, North University of China, Taiyuan 030051, P. R. China
    *E-mail: [email protected]
Cite this: Inorg. Chem. 2019, 58, 9, 5746–5752
Publication Date (Web):April 5, 2019
https://doi.org/10.1021/acs.inorgchem.9b00111
Copyright © 2019 American Chemical Society

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    Abstract

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    To better utilize carbon dots (CDs) as efficient photocatalysts, an excellent strategy of constructing CDs@MoS2 heterostructure is presented. Here a facile sonication–hydrothermal method is utilized to synthesize CDs@MoS2. Such heterostructure regulates the energy level configuration, and visible light absorption and the separation and transfer of photogenerated charges are enhanced remarkably, which is propitious for the production of more photoinduced charges and improvement of the heterogeneous photocatalytic activity. Meanwhile, the photocatalytic performance of CDs@MoS2 was obviously improved in methylene blue degradation. On the basis of a series of contrast experiments, the possible mechanism of the photocatalytic reaction is proposed. Therefore, this work offers a facile route for the design of a zero-dimensional/two-dimensional heterojunction for the adjustment of the energy level structure and the improvement in photocatalytic performance.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorgchem.9b00111.

    • XRD patterns of MoS2 powder, TEM image of CDs@MoS2, size distribution of CDs, dark adsorption curve, degradation rates, recycling experiments, XRD, XPS, and TEM images of the CDs@MoS2 sample after photodegradation, PL spectra, and quantification of active species (PDF)

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