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A Superior Sodium/Lithium-Ion Storage Material: Sea Sponge C/Sn2Fe@GO
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    A Superior Sodium/Lithium-Ion Storage Material: Sea Sponge C/Sn2Fe@GO
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    • Weixi Yan
      Weixi Yan
      Shanghai Key Laboratory of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China
      More by Weixi Yan
    • Qingnan Wu
      Qingnan Wu
      College of Plant Protection, Henan Agricultural University, Zhengzhou 450002, China
      More by Qingnan Wu
    • Ming Wen*
      Ming Wen
      Shanghai Key Laboratory of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China
      *E-mail: [email protected] (M.W.).
      More by Ming Wen
    • Shipei Chen
      Shipei Chen
      Shanghai Key Laboratory of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China
      More by Shipei Chen
    • Qingsheng Wu
      Qingsheng Wu
      Shanghai Key Laboratory of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China
      More by Qingsheng Wu
    • Nicola Pinna
      Nicola Pinna
      Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Strasse 2, Berlin 12489, Germany
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2019, 58, 12, 7915–7924
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    https://doi.org/10.1021/acs.inorgchem.9b00621
    Published May 31, 2019
    Copyright © 2019 American Chemical Society

    Abstract

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    A well-structured anode nanomaterial, which can ensure electron and ion transport and avoid excessive pulverization, is of crucial importance to achieve high capacity with superior cycling stability for both sodium- and lithium-ion batteries (SIBs and LIBs). For the purpose of a superior rate performance, this work here has designed and successfully synthesized a new Na+/Li+ storage nanomaterial of SCS/Sn2Fe@GO through loading of a Sn2Fe nanoalloy on sea-sponge-like carbon spheres (SCSs), followed by a graphene oxide (GO) wrapping process. In such a designed composite, the SCS skeleton ensures electronic conductivity and shorts Na+ and Li+ diffusion pathways, while the Sn2Fe nanoalloy delivers a high capacity and prevents excessive pulverization. The GO shell around SCS/Sn2Fe greatly enhances the cyclability. Used as an anode, the SCS/Sn2Fe@GO nanocomposite enables a high capacity up to 660 mAh g–1 at 50 mA g–1, which is maintained without decay up to 800 cycles in SIBs, and up to 850 mAh g–1 at 500 mA g–1 after 3500 cycles in LIBs, proving its applicability in new-generation SIBs and LIBs.

    Copyright © 2019 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.inorgchem.9b00621.

    • SEM, XRD, particle size distribution, and BET of the SSC skeleton, SEM and TGA of SCS/Sn2Fe composites, Raman patterns of GO, SCS/Sn2Fe, and SCS/Sn2Fe@GO, and electrochemical data of SCS, SCS/Sn2Fe, and SCS/Sn2Fe@GO composites (PDF)

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    This article is cited by 10 publications.

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    2. Hanyu Xu, Chunhui Wang, Jia-feng Zhang, Jianyong Zhang, Liang Cao, Bao Zhang, Xing Ou. Rational Design of Bimetal–Organic Framework-Derived ZnSnS3 Nanodots Incorporated into the Nitrogen-Doped Graphene Framework for Advanced Lithium Storage. ACS Sustainable Chemistry & Engineering 2020, 8 (11) , 4464-4473. https://doi.org/10.1021/acssuschemeng.9b07487
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    6. Zhiqiang Li, Le Cai, Kainian Chu, Shikai Xu, Ge Yao, Lingzhi Wei, Fangcai Zheng. Heteroatom-doped carbon materials with interconnected channels as ultrastable anodes for lithium/sodium ion batteries. Dalton Transactions 2021, 50 (12) , 4335-4344. https://doi.org/10.1039/D1DT00243K
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    9. L. Jiang, S. Song, D. Luo, F. Cai, L. Xie, Q. Zhang, Z. Ren. Plant growth–inspired design of high-performance composite electrode nanostructures for supercapacitors. Materials Today Physics 2020, 12 , 100138. https://doi.org/10.1016/j.mtphys.2019.100138
    10. Weina Li, Jiaqi Li, Jiahao Wen, Ming Wen, Shipei Chen, Qingsheng Wu, Yongqing Fu. Hollow nanostructure of sea-sponge-C/SiC@SiC/C for stable Li+-storage capability. Science Bulletin 2019, 64 (16) , 1152-1157. https://doi.org/10.1016/j.scib.2019.06.014

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2019, 58, 12, 7915–7924
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.inorgchem.9b00621
    Published May 31, 2019
    Copyright © 2019 American Chemical Society

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