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Manipulating Spin Alignments of (Y,Lu)1.7Fe17 Intermetallic Compounds via Unusual Thermal Pressure

  • Yili Cao
    Yili Cao
    Beijing Advanced Innovation Center for Materials Genome Engineering and Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China
    More by Yili Cao
  • Kun Lin
    Kun Lin
    Beijing Advanced Innovation Center for Materials Genome Engineering and Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China
    More by Kun Lin
  • Zhanning Liu
    Zhanning Liu
    Beijing Advanced Innovation Center for Materials Genome Engineering and Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China
    More by Zhanning Liu
  • Jinyu Hu
    Jinyu Hu
    Beijing Advanced Innovation Center for Materials Genome Engineering and Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China
    More by Jinyu Hu
  • Chin-Wei Wang
    Chin-Wei Wang
    Neutron Group, National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan
  • Xinzhi Liu
    Xinzhi Liu
    Helmholtz-Zentrum-Berlin für Materialien und Energie, Hahn-Meitner-Platz 1, D-14109 Berlin, Germany
    More by Xinzhi Liu
  • Evgenia Tereshina-Chitrova
    Evgenia Tereshina-Chitrova
    Faculty of Mathematics and Physics, Charles University, 12116 Prague, Czech Republic
    Institute of Physics, Czech Academy of Sciences, 18121 Prague, Czech Republic
  • Kenichi Kato
    Kenichi Kato
    RIKEN SPring-8 Center, Hyogo 679-5148, Japan
    More by Kenichi Kato
  • Qiang Li
    Qiang Li
    Beijing Advanced Innovation Center for Materials Genome Engineering and Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China
    More by Qiang Li
  • Jinxia Deng
    Jinxia Deng
    Beijing Advanced Innovation Center for Materials Genome Engineering and Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China
    More by Jinxia Deng
  • Jun Chen
    Jun Chen
    Beijing Advanced Innovation Center for Materials Genome Engineering and Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China
    More by Jun Chen
  • Hongjie Zhang
    Hongjie Zhang
    State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  • , and 
  • Xianran Xing*
    Xianran Xing
    Beijing Advanced Innovation Center for Materials Genome Engineering and Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing 100083, China
    *Email: [email protected]
    More by Xianran Xing
Cite this: Inorg. Chem. 2020, 59, 8, 5247–5251
Publication Date (Web):March 27, 2020
https://doi.org/10.1021/acs.inorgchem.9b03570
Copyright © 2020 American Chemical Society

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    Abstract

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    External pressure has been successfully employed to achieve desirable spin alignments in the field of materials science but is seriously restricted by the difficulty of reaching high pressure with conventional methods. The search for simple and effective ways to apply pressure on the lattice is challenging but intriguing. Here we report a new strategy to manipulate the spin alignments of (Y,Lu)1.7Fe17 intermetallic compounds through unusual thermal pressure. The spin alignments of Fe initially lie parallel inside the basal plane and then turn spirally between adjacent layers with a zone axis along the c direction under higher Lu concentration. The synchrotron and neutron powder diffraction investigations clearly reveal that the direction of spin alignments is highly correlated to large lattice contraction induced by negative thermal expansion (NTE), an unusual thermal pressure, along the c direction. The critical lattice parameter c to form spiral spin alignments is determined unambiguously. This work presents a feasible way to adjust spin alignments through NTE, which might be conducive to the future design of particular spin alignments instead of physical pressure for functional magnetic materials.

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    Cited By

    This article is cited by 5 publications.

    1. Yili Cao, Takeshi Matsukawa, Alexandra Gibbs, Maxim Avdeev, Chin-Wei Wang, Hui Wu, Qing-zhen Huang, Kenji Ohoyama, Toru Ishigaki, Haowei Zhou, Qiang Li, Jun Miao, Kun Lin, Xianran Xing. Quantified Zero Thermal Expansion in Magnetic R2Fe17-Based Intermetallic Compounds (R = Rare Earth). Chemistry of Materials 2023, 35 (11) , 4549-4555. https://doi.org/10.1021/acs.chemmater.3c00915
    2. Qiang Li, Kun Lin, Zhanning Liu, Lei Hu, Yili Cao, Jun Chen, Xianran Xing. Chemical Diversity for Tailoring Negative Thermal Expansion. Chemical Reviews 2022, 122 (9) , 8438-8486. https://doi.org/10.1021/acs.chemrev.1c00756
    3. Yili Cao, Kun Lin, Zhanning Liu, Jinyu Hu, Chin-Wei Wang, Evgenia Tereshina-Chitrova, Kenichi Kato, Qiang Li, Jinxia Deng, Jun Chen, Hongjie Zhang, Xianran Xing. Role of “Dumbbell” Pairs of Fe in Spin Alignments and Negative Thermal Expansion of Lu2Fe17-Based Intermetallic Compounds. Inorganic Chemistry 2020, 59 (16) , 11228-11232. https://doi.org/10.1021/acs.inorgchem.0c01590
    4. Chengyi Yu, Kun Lin, Suihe Jiang, Yili Cao, Wenjie Li, Yilin Wang, Yan Chen, Ke An, Li You, Kenichi Kato, Qiang Li, Jun Chen, Jinxia Deng, Xianran Xing. Plastic and low-cost axial zero thermal expansion alloy by a natural dual-phase composite. Nature Communications 2021, 12 (1) https://doi.org/10.1038/s41467-021-25036-1
    5. Yuzhu Song, Naike Shi, Shiqing Deng, Xianran Xing, Jun Chen. Negative thermal expansion in magnetic materials. Progress in Materials Science 2021, 121 , 100835. https://doi.org/10.1016/j.pmatsci.2021.100835

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