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Determination of Six Pyrazole Fungicides in Grape Wine by Solid-Phase Extraction and Gas Chromatography–Tandem Mass Spectrometry

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    Determination of Six Pyrazole Fungicides in Grape Wine by Solid-Phase Extraction and Gas Chromatography–Tandem Mass Spectrometry
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    † College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, People’s Republic of China
    ‡ Wenzhou Entry−Exit Inspection and Quarantine Bureau of People’s Republic of China, Wenzhou, Zhejiang 325027, People’s Republic of China
    § Chinese Academy of Inspection and Quarantine, Beijing 100176, People’s Republic of China
    ∥ Shanghai Entry−Exit Inspection and Quarantine Bureau of People’s Republic of China, Shanghai 200135, People’s Republic of China
    *Telephone: 86-577-88373937. Fax: 86-577-88373190. E-mail: [email protected]
    *E-mail: [email protected]
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    Journal of Agricultural and Food Chemistry

    Cite this: J. Agric. Food Chem. 2016, 64, 19, 3901–3907
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    https://doi.org/10.1021/acs.jafc.6b00530
    Published April 25, 2016
    Copyright © 2016 American Chemical Society
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    Abstract

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    A gas chromatography–tandem mass spectrometry (GC–MS/MS) method was developed for the first simultaneous identification and quantification of six pyrazole fungicides (furametpyr, rabenzazole, fluxapyroxad, penflufen, bixafen, and isopyrazam) in grape wine samples. The grape wine samples were first diluted with water, then purified by solid-phase extraction, and finally examined by GC–MS/MS in multiple reaction monitoring (MRM) mode. Matrix-matched calibration curves were used to correct the matrix effects. The limits of quantification (LOQs), calculated as 10 times the standard deviation, were 0.2–0.8 μg kg–1 for the six pyrazole fungicides. The average recoveries were in the range of 74.3–94.5%, with relative standard deviations (RSDs) below 5.8%, measured at three concentration levels. The proposed method is suitable for the simultaneous determination of six pyrazole fungicides in grape wine samples.

    Copyright © 2016 American Chemical Society

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    Cited By

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    This article is cited by 17 publications.

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    Journal of Agricultural and Food Chemistry

    Cite this: J. Agric. Food Chem. 2016, 64, 19, 3901–3907
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jafc.6b00530
    Published April 25, 2016
    Copyright © 2016 American Chemical Society
    Request reuse permissions

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