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Deformation of Microporous Carbon Adsorbent Sorbonorit-4 during Methane Adsorption

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Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Chem. Eng. Data 2022, 67, 7, 1699-1714
    Adsorption and Diffusion in Porous Materials

    Deformation of Microporous Carbon Adsorbent Sorbonorit-4 during Methane Adsorption
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    • Andrey V. Shkolin*
      Andrey V. Shkolin
      Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Science (IPCE RAS), Leninsky prospect, 31, build. 4, Moscow, 119071, Russian Federation
      *Email: [email protected]. Phone (office): +7 (495) 955-46-01. Fax +7(495)952-53-08.
      More by Andrey V. Shkolin
      Orcidhttps://orcid.org/0000-0001-6446-4419
    • Ilya E. Men’shchikov
      Ilya E. Men’shchikov
      Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Science (IPCE RAS), Leninsky prospect, 31, build. 4, Moscow, 119071, Russian Federation
      More by Ilya E. Men’shchikov
    • Elena V. Khozina
      Elena V. Khozina
      Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Science (IPCE RAS), Leninsky prospect, 31, build. 4, Moscow, 119071, Russian Federation
      More by Elena V. Khozina
    • Vladislav Yu. Yakovlev
      Vladislav Yu. Yakovlev
      Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Science (IPCE RAS), Leninsky prospect, 31, build. 4, Moscow, 119071, Russian Federation
      Nuclear Safety Institute of Russian Academy of Science, Bolshaya Tul’skaya straße, 52, Moscow, 115191, Russian Federation
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    • Valery N. Simonov
      Valery N. Simonov
      Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Science (IPCE RAS), Leninsky prospect, 31, build. 4, Moscow, 119071, Russian Federation
      National Research Nuclear University, Moscow Engineering Physics Institute (MEPHI), Kashirskoe shosse, 31, Moscow, 115409, Russian Federation
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    • Anatolii A. Fomkin
      Anatolii A. Fomkin
      Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Science (IPCE RAS), Leninsky prospect, 31, build. 4, Moscow, 119071, Russian Federation
      More by Anatolii A. Fomkin
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2022, 67, 7, 1699–1714
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    https://doi.org/10.1021/acs.jced.1c00904
    Published April 6, 2022
    Copyright © 2022 American Chemical Society
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    Abstract

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    The temperature- and methane adsorption-induced deformations of microporous activated carbon Sorbonorit-4 were measured by in situ dilatometry over a wide range of temperatures and pressures. The thermal expansion coefficient of Sorbonorit-4 in vacuum increased linearly with temperature within a range of 293–573 K. Methane adsorption in Sorbonorit-4 induced its contraction at low pressures and temperatures or expansion at high temperatures throughout the entire pressure range. An inversion of the temperature dependence of adsorption-induced strain (AIS) of Sorbonorit-4 was found. At low pressures and temperatures below 300 K, the AIS isotherm showed a contraction of Sorbonorit-4; its magnitude and corresponding pressure interval decreased with temperature. At T > 300 K, the temperature rise was accompanied by an adsorption-induced expansion of Sorbonorit-4 up to 0.08% at 393 K. At high pressures, the expansion decreased from 0.45 to 0.13% when the temperature increased from 213 to 393 K. The AIS of Sorbonorit-4 and differential isosteric heat of adsorption presented as functions of methane uptake changed within the same intervals of adsorption values, reflecting variations in the state of adsorbed molecules determined by contributions from the adsorbate–adsorbent and adsorbate–adsorbate interactions. The obtained results are essential for practical use of carbon adsorbents for natural gas storage.

    Copyright © 2022 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge (PDF). The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.jced.1c00904.

    • Experimental data on methane adsorption on Sorbonorit-4 microporous carbon adsorbent, thermal expansion, adsorption-induced deformation of Sorbonorit-4; the average distance between adsorbed methane molecules in a micropore as a function of methane adsorption (PDF)

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    This article is cited by 23 publications.

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    17. А. Е. Гринченко, И. Е. Меньщиков, А. В. Школин, А. А. Фомкин. Адсорбция паров метана на микро-мезопористом углеродном адсорбенте в процессах длительного хранения сжиженного природного газа. Физикохимия поверхности и защита материалов 2023, 59 (5) , 463-471. https://doi.org/10.31857/S0044185623700560
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2022, 67, 7, 1699–1714
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jced.1c00904
    Published April 6, 2022
    Copyright © 2022 American Chemical Society
    Request reuse permissions

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