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Densities and Viscosities of Sugar Alcohols in Vitamin B6 Aqueous Solutions at (293.15 to 323.15) K

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State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China
Tianjin Bohai Vocational Technical College, Tianjin, 300402, P. R. China
Cite this: J. Chem. Eng. Data 2015, 60, 6, 1535–1543
Publication Date (Web):April 29, 2015
https://doi.org/10.1021/acs.jced.5b00114
Copyright © 2015 American Chemical Society

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    Abstract

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    The densities and viscosities of ternary solutions (erythritol/xylitol/sorbitol/maltitol + vitamin B6 + water) were measured at 293.15 K, 303.15 K, 313.15 K, 323.15 K and atmospheric pressure. The experimental densities were correlated in terms of the Guimarães equation, and the apparent molar volumes (Vφ), the limiting partial molar volumes (Vφ0), and the limiting partial molar volumes of transfer (ΔtrVφ0) were calculated through the densities. The experimental viscosities were correlated according to the extended Jones–Dole equation to obtain the viscosity B coefficients, and the free energies of activation per mole of solute (Δμ20≠) and per mole of solvent (Δμ10≠) were calculated. These obtained thermodynamical properties and transport properties of multicomponents are useful to understand the structural change and strong solute–solvent interaction in the ternary solutions (sugar alcohols + vitamin B6 + water).

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    Comparison of experimental densities and viscosities for vitamin B6 + water solutions with the literature values. This material is available free of charge via the Internet at http://pubs.acs.org.

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