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Liquid Phase Equilibria of the Water + Propionic or Butyric Acid + Methyl tert-Butyl Ketone Ternary Systems at (298.15 and 323.15) K

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Key Laboratory of Heat Transfer Enhancement and Energy Conservation of Ministry of Education, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, P. R. China
*Tel.: +8613632384249. E-mail: [email protected]
Cite this: J. Chem. Eng. Data 2015, 60, 9, 2612–2617
Publication Date (Web):August 24, 2015
https://doi.org/10.1021/acs.jced.5b00214
Copyright © 2015 American Chemical Society

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    Abstract

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    In the present work, liquid–liquid equilibria (LLE) data for ternary systems, water + propionic acid or butyric acid + methyl tert-butyl ketone (MTBK), at (298.15 and 323.15) K under atmospheric pressure were measured. The reliability of the experimental LLE data was verified by the Othmer–Tobias and Hand equations. The distribution coefficient, together with the selectivity, was used to assess the extraction performance of MTBK. The universal quasichemical activity coefficient (UNIQUAC) and nonrandom two-liquid (NRTL) models were used to correlate the experimental tie-line data, and binary interaction parameters for relevant process simulation were thus obtained.

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    Cited By

    This article is cited by 7 publications.

    1. Jinbei Yang, Yichun Huang, Yang Wang, Jinyi Chen, Meiqiong Yu. Isobaric Vapor–Liquid Equilibrium for Binary Systems of n-Butyric Acid with Water, Isopropyl Acetate, n-Propyl Acetate, and n-Methylpyrrolidone. Journal of Chemical & Engineering Data 2023, 68 (8) , 2037-2044. https://doi.org/10.1021/acs.jced.3c00179
    2. Ali Ghanadzadeh Gilani, Atefeh Kashef, Behnaz Mohammadi Khanghah. Comparative Analysis of Liquid–Liquid Equilibria for Aqueous Systems of Propionic Acid with Structurally Similar Aryl Solvents. Industrial & Engineering Chemistry Research 2020, 59 (19) , 9254-9264. https://doi.org/10.1021/acs.iecr.0c00878
    3. Kangning Xiong, Xiuyu Zheng, Meiling Jiang, Dan Gao, Furong Wang, Yun Chen. Phase Equilibrium on Extraction Methylphenols from Aqueous Solution with 3,3-Dimethyl-2-butanone at 333.2 K and 353.2 K. Journal of Chemical & Engineering Data 2018, 63 (7) , 2376-2383. https://doi.org/10.1021/acs.jced.7b00932
    4. Shaoming Zhou, Mochen Liao, Dong Liu, Libo Li, and Yun Chen . Liquid–Liquid Equilibrium for the Ternary Systems Methyl tert-Butyl Ketone + o-, m-, p-Cresol + Water at (298.2, 313.2, and 323.2) K. Journal of Chemical & Engineering Data 2017, 62 (7) , 1929-1936. https://doi.org/10.1021/acs.jced.6b00825
    5. Sezin Bekri, Dilek Özmen, and Atilla Özmen . Correlation of Experimental Liquid–Liquid Equilibrium Data for Ternary Systems Using NRTL and GMDH-Type Neural Network. Journal of Chemical & Engineering Data 2017, 62 (6) , 1797-1805. https://doi.org/10.1021/acs.jced.6b00985
    6. Sina Shekarsaraee, Hossein Taherpour Nahzomi, Elham Nasiri-Touli. Phase diagrams for the system water/butyric acid/propylene carbonate at T = 293.2–313.2 K and p = 101.3 kPa. Russian Journal of Physical Chemistry A 2017, 91 (11) , 2078-2084. https://doi.org/10.1134/S0036024417110267
    7. Yun Chen, Youchang Wang, Shaoming Zhou, Huang Chen, Dong Liu, Libo Li. Liquid phase equilibrium of the ternary systems, water + propionic or butyric acid + mesityl oxide, at (298.2 and 323.2) K. The Journal of Chemical Thermodynamics 2017, 111 , 72-79. https://doi.org/10.1016/j.jct.2017.03.018

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