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Experimental Determination and Correlation of Liquid–Liquid Equilibria for Methyl Isopropyl Ketone + Phenol + Water Mixtures at 298.15, 313.15, and 323.15 K

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    Experimental Determination and Correlation of Liquid–Liquid Equilibria for Methyl Isopropyl Ketone + Phenol + Water Mixtures at 298.15, 313.15, and 323.15 K
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    Key Laboratory of Heat Transfer Enhancement and Energy Conservation of Ministry of Education, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, P. R. China
    *Tel.:+86 13632384249. E-mail: [email protected]
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2016, 61, 7, 2221–2225
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    https://doi.org/10.1021/acs.jced.5b00895
    Published June 8, 2016
    Copyright © 2016 American Chemical Society
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    Abstract

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    Liquid–liquid equilibria (LLE) data for the ternary system, methyl isopropyl ketone (MIPK) + phenol + water, were measured at 298.15 K, 313.15 and 323.15 K under atmospheric pressure by gas chromatography. Distribution coefficients and separation factors were calculated to evaluate the extracting performance of methyl isopropyl ketone, which was proven to be a very efficient solvent to extract phenol from aqueous solution, with distribution coefficients for phenol even higher than those of methyl isobutyl ketone (MIBK) or methyl butyl ketone (MBK). The nonrandom two-liquid (NRTL) and universal quasi-chemical activity coefficient (UNIQUAC) models were used to correlate the experimental data to yield binary interaction parameters for phenol extraction process design or optimization.

    Copyright © 2016 American Chemical Society

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jced.5b00895.

    • Comparison of experimental solubilities with that reported in the literature (PDF)

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    Cited By

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    This article is cited by 23 publications.

    1. Mansoureh Bahiraei, Javad Saien, Farnaz Jafari. Salting-out Effects in Extraction of Phenol from Aqueous Solutions Using a Hydrophobic Deep Eutectic Solvent Based on Dodecanoic and Octanoic Acids: Experimental Study and Comparison. Journal of Chemical & Engineering Data 2024, 69 (11) , 4019-4028. https://doi.org/10.1021/acs.jced.4c00570
    2. Weibin Cai, Tiankun Liu, Hong Ye, Meng Chen, Xue Cheng. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Cyclohexanone–Water–Phenol Ternary System. Journal of Chemical & Engineering Data 2021, 66 (2) , 861-866. https://doi.org/10.1021/acs.jced.0c00132
    3. Yangyang Wu, Bokun Chen, Siyu Yang. Liquid–Liquid Equilibria for the Quaternary System: Diisopropyl Ether + n-Pentanol + Phenol + Water at 298.15 K. Journal of Chemical & Engineering Data 2020, 65 (11) , 5210-5217. https://doi.org/10.1021/acs.jced.0c00354
    4. Shuai Shen, Yun Chen, Meiling Jiang. Experiments and COSMO-SAC Modeling of Methyl Isobutyl Ketone + Dimethylphenols + Water Mixtures. Journal of Chemical & Engineering Data 2019, 64 (8) , 3521-3534. https://doi.org/10.1021/acs.jced.9b00300
    5. Yinshuang Zhang, Bokun Chen, Siyu Yang. Liquid–Liquid Equilibrium for the Ternary Systems (Methyl Isobutyl Ketone + Quinoline or Isoquinoline + Water) at 298.15, 318.15, and 338.15 K. Journal of Chemical & Engineering Data 2018, 63 (8) , 2758-2765. https://doi.org/10.1021/acs.jced.8b00096
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    10. Georgy Sergeevich Dmitriev, Leonid Nikolaevich Zananeskin. Liquid–liquid equilibrium for ternary methyl tert-amyl ether + phenol + water system at 283.15, 298.15, and 313.15 K. Separation Science and Technology 2023, 58 (1) , 44-50. https://doi.org/10.1080/01496395.2022.2101006
    11. Georgy Sergeevich Dmitriev, Anton Vladimirovich Terekhov, Leonid Nikolaevich Zanaveskin. Influence of acetone and sodium sulfate impurities on the liquid-liquid equilibrium for the phenol extraction with n-butyl acetate. Separation Science and Technology 2022, 57 (17) , 2772-2778. https://doi.org/10.1080/01496395.2022.2038627
    12. G. S. Dmitriev, L. N. Zanaveskin, A. V. Terekhov, A. L. Maksimov. Extraction of Phenol from Wastewaters. Choice of Extractant in Coproduction of Phenol and Acetone (Review). Theoretical Foundations of Chemical Engineering 2022, 56 (5) , 859-871. https://doi.org/10.1134/S0040579522050037
    13. Meiling Jiang, Shuai Shen, Yun Chen. Separation of phenol from aqueous solution by 2-octanone: Phase equilibrium measurements and thermodynamic studies. Journal of Molecular Liquids 2020, 300 , 112323. https://doi.org/10.1016/j.molliq.2019.112323
    14. Shuai Shen, Yun Chen, Meiling Jiang. Experimental measurement, correlation and COSMO-SAC prediction of liquid-liquid equilibrium for MIPK + dimethylphenols + water mixtures. The Journal of Chemical Thermodynamics 2020, 140 , 105900. https://doi.org/10.1016/j.jct.2019.105900
    15. Kangning Xiong, Shuai Shen, Youchang Wang, Yun Chen. Measurements and correlation of liquid–liquid equilibrium data for the ternary (methyl tert-butyl ketone + o, m, p-benzenediol + water) system at (333.2, 343.2 and 353.2) K. Chinese Journal of Chemical Engineering 2019, 27 (4) , 905-911. https://doi.org/10.1016/j.cjche.2018.09.011
    16. Yun Chen, Shuai Shen, Meiling Jiang, Youchang Wang. Experimental result and data correlation of liquid-liquid equilibrium for methyl isopropyl ketone + o, m, p-dihydroxybenzene + water at 333.15 K, 343.15 K and 353.15 K. The Journal of Chemical Thermodynamics 2019, 129 , 44-54. https://doi.org/10.1016/j.jct.2018.08.041
    17. Mahdieh Razi Asrami, Javad Saien. Salting-out effect on extraction of phenol from aqueous solutions by [Hmim][NTf2] ionic liquid: Experimental investigations and modeling. Separation and Purification Technology 2018, 204 , 175-184. https://doi.org/10.1016/j.seppur.2018.04.075
    18. Yun Chen, Shaoming Zhou, Huang Chen, Youchang Wang, Libo Li. Extraction of o-, m- and p-cresol from aqueous solution with methyl isopropyl ketone: Equilibrium, correlations, and COSMO-RS predictions. The Journal of Chemical Thermodynamics 2017, 115 , 180-190. https://doi.org/10.1016/j.jct.2017.07.033
    19. Yun Chen, Shaoming Zhou, Youchang Wang, Libo Li. Screening solvents to extract phenol from aqueous solutions by the COSMO-SAC model and extraction process simulation. Fluid Phase Equilibria 2017, 451 , 12-24. https://doi.org/10.1016/j.fluid.2017.08.007
    20. Laëtitia Cesari, Laetitia Canabady-Rochelle, Fabrice Mutelet. Extraction of phenolic compounds from aqueous solution using choline bis(trifluoromethylsulfonyl)imide. Fluid Phase Equilibria 2017, 446 , 28-35. https://doi.org/10.1016/j.fluid.2017.04.022
    21. Shaoming Zhou, Libo Li, Youchang Wang, Yun Chen. Measurement, correlation and COSMO-SAC prediction of liquid-liquid equilibrium for the ternary systems, mesityl oxide + o-, m-, p-cresol + water, at 333.2K and 353.2 K. Fluid Phase Equilibria 2017, 440 , 45-53. https://doi.org/10.1016/j.fluid.2017.03.002
    22. Hengde Li, Li Wan, Guoqiang Chu, Wei Tan, Baoyu Liu, Yanlin Qin, Yuqing Feng, Dalei Sun, Yanxiong Fang. (Liquid+liquid) extraction of phenols from aqueous solutions with cineole. The Journal of Chemical Thermodynamics 2017, 107 , 95-103. https://doi.org/10.1016/j.jct.2016.12.018
    23. Yun Chen, Ran Lv, Furong Wang, Libo Li. Determination and modeling of liquid-liquid equilibrium for ternary mixtures of methyl isopropyl ketone, cresol isomers and water. Fluid Phase Equilibria 2016, 429 , 107-112. https://doi.org/10.1016/j.fluid.2016.08.034
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2016, 61, 7, 2221–2225
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jced.5b00895
    Published June 8, 2016
    Copyright © 2016 American Chemical Society
    Request reuse permissions

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