Experimental Determination and Correlation of Liquid–Liquid Equilibria for Methyl Isopropyl Ketone + Phenol + Water Mixtures at 298.15, 313.15, and 323.15 K
- Ran Lv
- ,
- Libo Li
- ,
- Huimin Wang
- , and
- Yun Chen
View Author Information
Key Laboratory of Heat Transfer Enhancement and Energy Conservation of Ministry of Education, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, P. R. China
*Tel.:+86 13632384249. E-mail: [email protected]
Abstract
Liquid–liquid equilibria (LLE) data for the ternary system, methyl isopropyl ketone (MIPK) + phenol + water, were measured at 298.15 K, 313.15 and 323.15 K under atmospheric pressure by gas chromatography. Distribution coefficients and separation factors were calculated to evaluate the extracting performance of methyl isopropyl ketone, which was proven to be a very efficient solvent to extract phenol from aqueous solution, with distribution coefficients for phenol even higher than those of methyl isobutyl ketone (MIBK) or methyl butyl ketone (MBK). The nonrandom two-liquid (NRTL) and universal quasi-chemical activity coefficient (UNIQUAC) models were used to correlate the experimental data to yield binary interaction parameters for phenol extraction process design or optimization.
Cited By
This article is cited by 21 publications.
- Weibin Cai, Tiankun Liu, Hong Ye, Meng Chen, Xue Cheng. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Cyclohexanone–Water–Phenol Ternary System. Journal of Chemical & Engineering Data 2021, 66 (2) , 861-866. https://doi.org/10.1021/acs.jced.0c00132
- Yangyang Wu, Bokun Chen, Siyu Yang. Liquid–Liquid Equilibria for the Quaternary System: Diisopropyl Ether + n-Pentanol + Phenol + Water at 298.15 K. Journal of Chemical & Engineering Data 2020, 65 (11) , 5210-5217. https://doi.org/10.1021/acs.jced.0c00354
- Shuai Shen, Yun Chen, Meiling Jiang. Experiments and COSMO-SAC Modeling of Methyl Isobutyl Ketone + Dimethylphenols + Water Mixtures. Journal of Chemical & Engineering Data 2019, 64 (8) , 3521-3534. https://doi.org/10.1021/acs.jced.9b00300
- Yinshuang Zhang, Bokun Chen, Siyu Yang. Liquid–Liquid Equilibrium for the Ternary Systems (Methyl Isobutyl Ketone + Quinoline or Isoquinoline + Water) at 298.15, 318.15, and 338.15 K. Journal of Chemical & Engineering Data 2018, 63 (8) , 2758-2765. https://doi.org/10.1021/acs.jced.8b00096
- Chao Guo, Yangtong Tan, Yu Qian, Siyu Yang. Liquid–Liquid Equilibria for Ternary (Methyl Propyl Ketone + Hydroquinone or Resorcinol + Water) Systems at 298.15, 318.15, and 333.15 K. Journal of Chemical & Engineering Data 2018, 63 (6) , 1994-2001. https://doi.org/10.1021/acs.jced.7b01127
- Nikolaos Montesantos, Matteo Chirullo, Marco Maschietti. Liquid–Liquid Equilibrium of Water + 2-Methoxyphenol + Methyl Isobutyl Ketone and Water + 1,2-Benzenediol + Methyl Isobutyl Ketone at 303.15 K and 328.15 K. Journal of Chemical & Engineering Data 2018, 63 (3) , 712-722. https://doi.org/10.1021/acs.jced.7b00887
- Javad Saien and Mahdieh Razi Asrami . Liquid–Liquid Equilibrium of the Ternary System of Water + Phenol + (Propan-2-yl) Benzene at Several Temperatures. Journal of Chemical & Engineering Data 2017, 62 (11) , 3663-3670. https://doi.org/10.1021/acs.jced.7b00393
- Georgy Sergeevich Dmitriev, Leonid Nikolaevich Zananeskin. Liquid–liquid equilibrium for ternary methyl tert-amyl ether + phenol + water system at 283.15, 298.15, and 313.15 K. Separation Science and Technology 2023, 58 (1) , 44-50. https://doi.org/10.1080/01496395.2022.2101006
- Georgy Sergeevich Dmitriev, Anton Vladimirovich Terekhov, Leonid Nikolaevich Zanaveskin. Influence of acetone and sodium sulfate impurities on the liquid-liquid equilibrium for the phenol extraction with n-butyl acetate. Separation Science and Technology 2022, 57 (17) , 2772-2778. https://doi.org/10.1080/01496395.2022.2038627
- G. S. Dmitriev, L. N. Zanaveskin, A. V. Terekhov, A. L. Maksimov. Extraction of Phenol from Wastewaters. Choice of Extractant in Coproduction of Phenol and Acetone (Review). Theoretical Foundations of Chemical Engineering 2022, 56 (5) , 859-871. https://doi.org/10.1134/S0040579522050037
- Meiling Jiang, Shuai Shen, Yun Chen. Separation of phenol from aqueous solution by 2-octanone: Phase equilibrium measurements and thermodynamic studies. Journal of Molecular Liquids 2020, 300 , 112323. https://doi.org/10.1016/j.molliq.2019.112323
- Shuai Shen, Yun Chen, Meiling Jiang. Experimental measurement, correlation and COSMO-SAC prediction of liquid-liquid equilibrium for MIPK + dimethylphenols + water mixtures. The Journal of Chemical Thermodynamics 2020, 140 , 105900. https://doi.org/10.1016/j.jct.2019.105900
- Kangning Xiong, Shuai Shen, Youchang Wang, Yun Chen. Measurements and correlation of liquid–liquid equilibrium data for the ternary (methyl tert-butyl ketone + o, m, p-benzenediol + water) system at (333.2, 343.2 and 353.2) K. Chinese Journal of Chemical Engineering 2019, 27 (4) , 905-911. https://doi.org/10.1016/j.cjche.2018.09.011
- Yun Chen, Shuai Shen, Meiling Jiang, Youchang Wang. Experimental result and data correlation of liquid-liquid equilibrium for methyl isopropyl ketone + o, m, p-dihydroxybenzene + water at 333.15 K, 343.15 K and 353.15 K. The Journal of Chemical Thermodynamics 2019, 129 , 44-54. https://doi.org/10.1016/j.jct.2018.08.041
- Mahdieh Razi Asrami, Javad Saien. Salting-out effect on extraction of phenol from aqueous solutions by [Hmim][NTf2] ionic liquid: Experimental investigations and modeling. Separation and Purification Technology 2018, 204 , 175-184. https://doi.org/10.1016/j.seppur.2018.04.075
- Yun Chen, Shaoming Zhou, Huang Chen, Youchang Wang, Libo Li. Extraction of o-, m- and p-cresol from aqueous solution with methyl isopropyl ketone: Equilibrium, correlations, and COSMO-RS predictions. The Journal of Chemical Thermodynamics 2017, 115 , 180-190. https://doi.org/10.1016/j.jct.2017.07.033
- Yun Chen, Shaoming Zhou, Youchang Wang, Libo Li. Screening solvents to extract phenol from aqueous solutions by the COSMO-SAC model and extraction process simulation. Fluid Phase Equilibria 2017, 451 , 12-24. https://doi.org/10.1016/j.fluid.2017.08.007
- Laëtitia Cesari, Laetitia Canabady-Rochelle, Fabrice Mutelet. Extraction of phenolic compounds from aqueous solution using choline bis(trifluoromethylsulfonyl)imide. Fluid Phase Equilibria 2017, 446 , 28-35. https://doi.org/10.1016/j.fluid.2017.04.022
- Shaoming Zhou, Libo Li, Youchang Wang, Yun Chen. Measurement, correlation and COSMO-SAC prediction of liquid-liquid equilibrium for the ternary systems, mesityl oxide + o-, m-, p-cresol + water, at 333.2K and 353.2 K. Fluid Phase Equilibria 2017, 440 , 45-53. https://doi.org/10.1016/j.fluid.2017.03.002
- Hengde Li, Li Wan, Guoqiang Chu, Wei Tan, Baoyu Liu, Yanlin Qin, Yuqing Feng, Dalei Sun, Yanxiong Fang. (Liquid+liquid) extraction of phenols from aqueous solutions with cineole. The Journal of Chemical Thermodynamics 2017, 107 , 95-103. https://doi.org/10.1016/j.jct.2016.12.018
- Yun Chen, Ran Lv, Furong Wang, Libo Li. Determination and modeling of liquid-liquid equilibrium for ternary mixtures of methyl isopropyl ketone, cresol isomers and water. Fluid Phase Equilibria 2016, 429 , 107-112. https://doi.org/10.1016/j.fluid.2016.08.034