ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Thermal and Mutual Diffusivity of Binary Mixtures of n-Dodecane and n-Tetracontane with Carbon Monoxide, Hydrogen, and Water from Dynamic Light Scattering (DLS)

View Author Information
Erlangen Graduate School in Advanced Optical Technologies (SAOT), University of Erlangen-Nuremberg, Paul-Gordan-Straße 6, D-91052 Erlangen, Germany
Shell Global Solutions International B.V., Grasweg 31, 1031 HW Amsterdam, The Netherlands
§ Department of Chemical and Biological Engineering, Institute of Engineering Thermodynamics, University of Erlangen-Nuremberg, Am Weichselgarten 8, D-91058 Erlangen, Germany
*E-mail: [email protected]. Tel.: +49-9131-85-29789.
Cite this: J. Chem. Eng. Data 2016, 61, 3, 1333–1340
Publication Date (Web):February 15, 2016
https://doi.org/10.1021/acs.jced.5b00986
Copyright © 2016 American Chemical Society

    Article Views

    503

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options

    Abstract

    Abstract Image

    The present work represents a continuation of a former study where the simultaneous determination of thermal and mutual diffusivity for binary mixtures of n-octacosane (n-C28H58) with dissolved carbon monoxide (CO), hydrogen (H2), or water (H2O) by using dynamic light scattering (DLS) was demonstrated. Here, the same properties are studied for binary mixtures of the n-alkanes n-dodecane (n-C12H26) or n-tetracontane (n-C40H82) with dissolved CO, H2, or H2O. In most cases, expanded relative uncertainties (k = 2) ranging from 2 to 12 % and 3 to 25 % for the thermal and mutual diffusivities could be obtained. The experimental mutual diffusivities for mixtures of n-C12H26 with CO, H2, or H2O measured at temperatures from 398 to 524 K and pressures from 0.2 to 4.2 MPa at saturation conditions agree well with molecular dynamics (MD) simulations using atomistic models and with experimental data from literature. Binary mixtures of n-C40H82 with dissolved CO, H2, or H2O were investigated in a temperature range from 447 to 498 K and pressures from 0.3 to 3.9 MPa. For mixtures with n-C40H82, the accessible temperature range was limited due to a change in the optical characteristics of the sample at elevated temperatures where DLS measurements suffered from absorption effects and particle scattering.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 33 publications.

    1. Frances D. Lenahan, Maximilian Piszko, Tobias Klein, Andreas P. Fröba. Prediction of Fick Diffusion Coefficients in Binary Mixtures of Liquids with Dissolved Gases at Infinite Dilution─A Review. Journal of Chemical & Engineering Data 2024, Article ASAP.
    2. Maximilian Piszko, Frances D. Lenahan, Claudio Dennstädt, Tobias Klein, Andreas P. Fröba. Mutual and Thermal Diffusivities in Binary Mixtures of n-Hexane or 1-Hexanol with Krypton, R143a, or Sulfur Hexafluoride by Using Dynamic Light Scattering and Molecular Dynamics Simulations. Journal of Chemical & Engineering Data 2023, 68 (6) , 1343-1357. https://doi.org/10.1021/acs.jced.3c00143
    3. Maximilian Piszko, Frances D. Lenahan, Tobias Klein, Andreas P. Fröba. Diffusivities in Binary Mixtures of Cyclohexane or Ethyl Butanoate with Dissolved CH4 or R143a Close to Infinite Dilution. Journal of Chemical & Engineering Data 2023, 68 (2) , 339-348. https://doi.org/10.1021/acs.jced.2c00696
    4. Frances D. Lenahan, Maximilian Piszko, Tobias Klein, Andreas P. Fröba. Diffusivities in Binary Mixtures of n-Decane, n-Hexadecane, n-Octacosane, 2-Methylpentane, 2,2-Dimethylbutane, Cyclohexane, Benzene, Ethanol, 1-Decanol, Ethyl Butanoate, or n-Hexanoic Acid with Dissolved He or Kr Close to Infinite Dilution. Journal of Chemical & Engineering Data 2022, 67 (3) , 622-635. https://doi.org/10.1021/acs.jced.1c00922
    5. Maximilian Piszko, Tobias Schaible, Christian Bonten, Andreas P. Fröba. Mutual and Thermal Diffusivities in Polystyrene Melts with Dissolved Nitrogen by Dynamic Light Scattering. Macromolecules 2021, 54 (12) , 5662-5672. https://doi.org/10.1021/acs.macromol.1c00819
    6. Tobias Klein, Maximilian Piszko, Chathura J. Kankanamge, Georgios Kasapis, Andreas P. Fröba. Fick Diffusion Coefficient in Binary Mixtures of [HMIM][NTf2] and Carbon Dioxide by Dynamic Light Scattering and Molecular Dynamics Simulations. The Journal of Physical Chemistry B 2021, 125 (19) , 5100-5113. https://doi.org/10.1021/acs.jpcb.1c01616
    7. Maximilian Piszko, Frances D. Lenahan, Simon Hahn, Michael H. Rausch, Thomas M. Koller, Tobias Klein, Andreas P. Fröba. Diffusivities in Binary Mixtures of n-Hexane or 1-Hexanol with Dissolved CH4, Ne, Kr, R143a, SF6, or R236fa Close to Infinite Dilution. Journal of Chemical & Engineering Data 2021, 66 (5) , 2218-2232. https://doi.org/10.1021/acs.jced.1c00084
    8. Qingyuan Zheng, Jack Williams, Mick D. Mantle, Andrew J. Sederman, Timothy A. Baart, Constant M. Guédon, Lynn F. Gladden. Experimental Determination of H2 and CO Diffusion Coefficients in a Wax Mixture Confined in a Porous Titania Catalyst Support. The Journal of Physical Chemistry B 2020, 124 (48) , 10971-10982. https://doi.org/10.1021/acs.jpcb.0c07440
    9. Xuyao Tang, Yang Wang, Junwei Cui, Xiaozhen Hu, Shengshan Bi, Jiangtao Wu. Thermal Diffusivity Measurement of Trans-1-chloro-3,3,3-trifluoropropene (R1233zd(E)) and Dodecafluoro-2-methylpentan-3-one (Novec1230) by the Dynamic Light Scattering Method. Journal of Chemical & Engineering Data 2020, 65 (9) , 4236-4241. https://doi.org/10.1021/acs.jced.0c00221
    10. Tobias Klein, Maximilian Piszko, Maren Lang, Julian Mehler, Peter S. Schulz, Michael H. Rausch, Cédric Giraudet, Thomas M. Koller, Andreas P. Fröba. Diffusivities in Binary Mixtures of [AMIM][NTf2] Ionic Liquids with the Dissolved Gases H2, He, N2, CO, CO2, or Kr Close to Infinite Dilution. Journal of Chemical & Engineering Data 2020, 65 (8) , 4116-4129. https://doi.org/10.1021/acs.jced.0c00430
    11. Maximilian Piszko, Korbinian Batz, Michael H. Rausch, Cédric Giraudet, Andreas P. Fröba. Diffusivities of Binary Mixtures Consisting of Carbon Dioxide, Methane, and Propane by Dynamic Light Scattering. Journal of Chemical & Engineering Data 2020, 65 (3) , 1068-1082. https://doi.org/10.1021/acs.jced.9b00495
    12. Francisco E. Berger Bioucas, Cornelia Damm, Wolfgang Peukert, Michael H. Rausch, Thomas M. Koller, Cédric Giraudet, Andreas P. Fröba. Translational and Rotational Diffusion Coefficients of Gold Nanorods Dispersed in Mixtures of Water and Glycerol by Polarized Dynamic Light Scattering. The Journal of Physical Chemistry B 2019, 123 (44) , 9491-9502. https://doi.org/10.1021/acs.jpcb.9b08274
    13. Wenchang Wu, Tobias Klein, Manuel Kerscher, Michael H. Rausch, Thomas M. Koller, Cédric Giraudet, Andreas P. Fröba. Diffusivities in 1-Alcohols Containing Dissolved H2, He, N2, CO, or CO2 Close to Infinite Dilution. The Journal of Physical Chemistry B 2019, 123 (41) , 8777-8790. https://doi.org/10.1021/acs.jpcb.9b06211
    14. Hossein Taghdisian, Saeideh Tasharrofi, Abdollah Golchoobi Firoozjaie, Akram Hosseinnia. Loading-Dependent Diffusion of SO2 in 13X and 5A Using Molecular Dynamics: Effects of Extraframework Ions and Topology. Journal of Chemical & Engineering Data 2019, 64 (7) , 3092-3104. https://doi.org/10.1021/acs.jced.9b00204
    15. Ying Zhang, Taotao Zhan, Junshuai Chen, Yutian Chen, Maogang He. Speed of Sound Measurement in 1-Methoxy-2-propanol from (306.81 to 648.29) K and up to 10 MPa. Journal of Chemical & Engineering Data 2019, 64 (1) , 337-344. https://doi.org/10.1021/acs.jced.8b00845
    16. Ying Zhang, Yutian Chen, Taotao Zhan, Maogang He. Measurement of the Speed of Sound in Near-Critical and Supercritical n-Heptane at Temperatures from (513.40 to 650.90) K and Pressures from (2.5 to 10.0) MPa. Journal of Chemical & Engineering Data 2018, 63 (9) , 3331-3337. https://doi.org/10.1021/acs.jced.8b00212
    17. Cédric Giraudet, Tobias Klein, Guanjia Zhao, Michael H. Rausch, Thomas M. Koller, Andreas P. Fröba. Thermal, Mutual, and Self-Diffusivities of Binary Liquid Mixtures Consisting of Gases Dissolved in n-Alkanes at Infinite Dilution. The Journal of Physical Chemistry B 2018, 122 (12) , 3163-3175. https://doi.org/10.1021/acs.jpcb.8b00733
    18. Thomas M. Koller, Tobias Klein, Jiaqi Chen, Ahmad Kalantar, Gerard P. van der Laan, Michael H. Rausch, and Andreas P. Fröba . Simultaneous Analysis of Equilibrium Fluctuations at the Surface and in the Bulk of a Binary Liquid Mixture by Dynamic Light Scattering. The Journal of Physical Chemistry B 2017, 121 (48) , 10950-10956. https://doi.org/10.1021/acs.jpcb.7b09770
    19. Thomas M. Koller, Tobias Klein, Cédric Giraudet, Jiaqi Chen, Ahmad Kalantar, Gerard P. van der Laan, Michael H. Rausch, and Andreas P. Fröba . Liquid Viscosity and Surface Tension of n-Dodecane, n-Octacosane, Their Mixtures, and a Wax between 323 and 573 K by Surface Light Scattering. Journal of Chemical & Engineering Data 2017, 62 (10) , 3319-3333. https://doi.org/10.1021/acs.jced.7b00363
    20. Ying Zhang, Xiong Zheng, Yutian Chen, and Maogang He . Thermal Diffusivity of 2-Ethoxy-2-methylpropane (ETBE) and 2-Methoxy-2-methylbutane (TAME) at Temperatures from (293 to 523) K and Pressure up to 10 MPa. Journal of Chemical & Engineering Data 2017, 62 (3) , 893-901. https://doi.org/10.1021/acs.jced.6b00365
    21. Andreas Heller, Cédric Giraudet, Zoi A. Makrodimitri, Matthieu S. H. Fleys, Jiaqi Chen, Gerard P. van der Laan, Ioannis G. Economou, Michael H. Rausch, and Andreas P. Fröba . Diffusivities of Ternary Mixtures of n-Alkanes with Dissolved Gases by Dynamic Light Scattering. The Journal of Physical Chemistry B 2016, 120 (41) , 10808-10823. https://doi.org/10.1021/acs.jpcb.6b08117
    22. Yuqi Su, Weijie Jia, Junshuai Chen, Songtao Cao, Maogang He, Ying Zhang. A novel measurement method for measuring the concentration-dependent mutual diffusion coefficients based on finite volume method. The Journal of Chemical Thermodynamics 2024, 189 , 107208. https://doi.org/10.1016/j.jct.2023.107208
    23. Zemin Yuan, Yirui Wang, Guanjia Zhao, Jianguo Yin, Suxia Ma. Experimental investigation of liquid thermal diffusivity for fatty acid methyl/ethyl esters by dynamic light scattering method. The Journal of Chemical Thermodynamics 2024, 188 , 107163. https://doi.org/10.1016/j.jct.2023.107163
    24. Chathura J. Kankanamge, Frances D. Lenahan, Tobias Klein, Andreas P. Fröba. Viscosity and Interfacial Tension of Binary Mixtures Consisting of an n-Alkane, Branched Alkane, Primary Alcohol, or Branched Alcohol and a Dissolved Gas Using Equilibrium Molecular Dynamics Simulations. International Journal of Thermophysics 2022, 43 (7) https://doi.org/10.1007/s10765-022-03038-5
    25. Junshuai Chen, Hongwei Xing, Taotao Zhan, Libin Chen, Maogang He, Ying Zhang. Measurement of thermal diffusivity of ethanol from (293 to 564) K and up to 10 MPa in vicinity of the critical point. Fluid Phase Equilibria 2022, 552 , 113276. https://doi.org/10.1016/j.fluid.2021.113276
    26. Junwei Cui, Shaomin Yan, Jiangtao Wu, Shengshan Bi. Determination of thermal and mutual diffusivity of n-heptane with dissolved carbon dioxide by dynamic light scattering. Fluid Phase Equilibria 2020, 526 , 112804. https://doi.org/10.1016/j.fluid.2020.112804
    27. Maximilian Piszko, Cédric Giraudet, Andreas P. Fröba. Diffusivities of an Equimolar Methane–Propane Mixture Across the Two-Phase Region by Dynamic Light Scattering. International Journal of Thermophysics 2020, 41 (7) https://doi.org/10.1007/s10765-020-02680-1
    28. Ubaya A. Higgoda, Chathura J. Kankanamge, Robert Hellmann, Thomas M. Koller, Andreas P. Fröba. Fick diffusion coefficients of binary fluid mixtures consisting of methane, carbon dioxide, and propane via molecular dynamics simulations based on simplified pair-specific ab initio-derived force fields. Fluid Phase Equilibria 2019, 502 , 112257. https://doi.org/10.1016/j.fluid.2019.112257
    29. Bayram ÇİMEN, Sonya ŞENGÜL, Memduha ERGÜT, Ayla ÖZER. CuO Nanopartiküllerinin Yeşil Sentezi ve Karakterizasyonu: Telon Blue AGLF ve Metilen Mavisi Adsorpsiyonu. Sinop Üniversitesi Fen Bilimleri Dergisi 2019, 4 (1) , 1-20. https://doi.org/10.33484/sinopfbd.315643
    30. Emel Simla Önal, Tolga Yatkın, Tural Aslanov, Memduha Ergüt, Ayla Özer. Biosynthesis and Characterization of Iron Nanoparticles for Effective Adsorption of Cr(VI). International Journal of Chemical Engineering 2019, 2019 , 1-13. https://doi.org/10.1155/2019/2716423
    31. Matthias Samuel Günter Knoll, Cédric Giraudet, Christian Joachim Hahn, Michael Heinrich Rausch, Andreas Paul Fröba. Simultaneous study of molecular and micelle diffusion in a technical microemulsion system by dynamic light scattering. Journal of Colloid and Interface Science 2019, 544 , 144-154. https://doi.org/10.1016/j.jcis.2019.02.070
    32. Maximilian Piszko, Wenchang Wu, Stefan Will, Michael H. Rausch, Cédric Giraudet, Andreas P. Fröba. Thermal and mutual diffusivities of fuel-related binary liquid mixtures under pre-combustion conditions. Fuel 2019, 242 , 562-572. https://doi.org/10.1016/j.fuel.2019.01.078
    33. Junwei Cui, Guanjia Zhao, Shengshan Bi, Jiangtao Wu. Thermal diffusivity measurements of R1234yf and R1234ze(E) under saturation conditions using dynamic light scattering method. International Journal of Refrigeration 2018, 86 , 133-138. https://doi.org/10.1016/j.ijrefrig.2017.10.039

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect