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Quaternary, Ternary, and Binary LLE Measurements for 2-Methoxy-2-methylpropane + Furfural + Acetic Acid + Water at Temperatures between 298 and 307 K

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Department of Biotechnology and Chemical Technology, Aalto University, P.O. Box 16100, FI-00076 Aalto, Finland
Cite this: J. Chem. Eng. Data 2016, 61, 7, 2458–2466
Publication Date (Web):June 20, 2016
https://doi.org/10.1021/acs.jced.6b00149
Copyright © 2016 American Chemical Society

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    Abstract

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    In this paper, measured quaternary and ternary liquid–liquid equilibrium (LLE) data for 2-methoxy-2-methylpropane (methyl tert-butyl ether, MTBE) + furfural + acetic acid (HAc) + water are presented. The measured data are presented together with the optimized binary interaction parameters for the utilized UNIQUAC-HOC (Hayden–O’Connell) activity coefficient model. Suitability of MTBE for liquid–liquid extraction of furfural in an industrial use is discussed.

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    Cited By

    This article is cited by 12 publications.

    1. Hongxun Zhang. Liquid–Liquid Phase Equilibria for Quinary, Quaternary, and Ternary Systems {Water + Furfural + Acetic Acid + Cyclopentyl Methyl Ether + CaCl2}: Measurement, Effect of Salt ,and Comparative Study. Journal of Chemical & Engineering Data 2018, 63 (9) , 3338-3344. https://doi.org/10.1021/acs.jced.8b00222
    2. Gaoyin He, Liping Wang, Midong Shi, Qingsong Li, and Yunfang Wang . Measurements and Thermodynamic Models for the Separation of 2-Methoxyethanol and Water Azeotropic Mixtures via Different Solvents. Journal of Chemical & Engineering Data 2017, 62 (7) , 2084-2089. https://doi.org/10.1021/acs.jced.7b00160
    3. Mikael Männistö, Juha-Pekka Pokki, Hele Haapaniemi, and Ville Alopaeus . Quaternary, Ternary and Binary LLE Measurements for 2-Methoxy-2-methylbutane + Furfural + Acetic Acid + Water at Temperatures between 298 and 341 K. Journal of Chemical & Engineering Data 2016, 61 (11) , 3730-3739. https://doi.org/10.1021/acs.jced.6b00150
    4. Ljudmila Fele Žilnik, Mladen Crnomarkovic, Uroš Novak, Miha Grilc, Blaž Likozar. Modelling, optimal solvent screening and separation of 5-hydroxymethylfurfural or furfural from catalytic conversion reactor stream in downstream purification process. Chemical Engineering Research and Design 2023, 194 , 376-387. https://doi.org/10.1016/j.cherd.2023.04.062
    5. Lucas de Oliveira Carneiro, Renata Pinto Da Silva Matos, Wagner Brandão Ramos, Romildo Pereira Brito, Karoline Dantas Brito. Sustainable design and optimization of the recovery process of acetic acid from vinasse: Operational, economic, and environmental analysis. Chemical Engineering and Processing - Process Intensification 2022, 181 , 109176. https://doi.org/10.1016/j.cep.2022.109176
    6. Marcos L. Corazza, Julia Trancoso. Phase equilibria modeling of biorefinery-related systems: a systematic review. Chemical Product and Process Modeling 2022, 17 (5) , 499-529. https://doi.org/10.1515/cppm-2020-0119
    7. Dominik Soukup-Carne, Xiaolei Fan, Jesús Esteban. An overview and analysis of the thermodynamic and kinetic models used in the production of 5-hydroxymethylfurfural and furfural. Chemical Engineering Journal 2022, 442 , 136313. https://doi.org/10.1016/j.cej.2022.136313
    8. Roshi Dahal, Petri Uusi-Kyyny, Juha-Pekka Pokki, Ville Alopaeus. Liquid – liquid equilibria in binary and ternary systems of phenol + hydrocarbons (n–dodecane or n–hexadecane) and water + phenol + hydrocarbons (n–dodecane or n–hexadecane) at temperatures between 298K and 353K. Fluid Phase Equilibria 2022, 556 , 113402. https://doi.org/10.1016/j.fluid.2022.113402
    9. Aynur Senol. Optimization of phase equilibria of quaternary liquid–liquid systems with a hybrid gradient method (HGM) using polynomial and quadratic differentiable models. Fluid Phase Equilibria 2020, 526 , 112800. https://doi.org/10.1016/j.fluid.2020.112800
    10. Aynur Senol. Modeling liquid-liquid equilibrium of quaternary systems with Integrated Quadratic Solvation Relationship (IQSR) in conjunction with the boundary constraints identified by ternary subsystems. Fluid Phase Equilibria 2018, 478 , 58-74. https://doi.org/10.1016/j.fluid.2018.09.003
    11. Mikael Männistö, Juha-Pekka Pokki, Ville Alopaeus. Quaternary and ternary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + acetic acid + water between 298 and 343 K. The Journal of Chemical Thermodynamics 2018, 119 , 61-75. https://doi.org/10.1016/j.jct.2017.12.015
    12. Mikael Männistö, Juha-Pekka Pokki, Ludivine Fournis, Ville Alopaeus. Ternary and binary LLE measurements for solvent (2-methyltetrahydrofuran and cyclopentyl methyl ether) + furfural + water between 298 and 343 K. The Journal of Chemical Thermodynamics 2017, 110 , 127-136. https://doi.org/10.1016/j.jct.2017.02.016

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