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Liquid–Liquid Equilibria for the Ternary System Mesityl Oxide + Phenol + Water at 298.15, 313.15, and 323.15 K

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    Liquid–Liquid Equilibria for the Ternary System Mesityl Oxide + Phenol + Water at 298.15, 313.15, and 323.15 K
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    Key Laboratory of Heat Transfer Enhancement and Energy Conservation of Ministry of Education, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, P. R. China
    *Tel.: +8613632384249. E-mail: [email protected]
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2016, 61, 7, 2493–2498
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    https://doi.org/10.1021/acs.jced.6b00186
    Published June 30, 2016
    Copyright © 2016 American Chemical Society
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    Abstract

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    In this work, liquid–liquid equilibria (LLE) data for the ternary system {mesityl oxide (1) + phenol (2) + water (3)} were measured at 298.15, 313.15, and 323.15 K under atmospheric pressure. The experimental LLE data were proven to be highly reliable by the Othmer–Tobias and Hand equations. The distribution coefficient and selectivity were calculated from the LLE data, which indicated mesityl oxide extracted phenol with a rather high efficiency. The NRTL and UNIQUAC models were employed to correlate the LLE data, yielding binary interaction parameters for simulating relevant extraction processes. The experimental LLE data were correlated successfully by both models.

    Copyright © 2016 American Chemical Society

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    • Distribution coefficients versus the mass fraction of phenol in the aqueous phase at 298.15 K (PDF)

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    Cited By

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    This article is cited by 37 publications.

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    Cite this: J. Chem. Eng. Data 2016, 61, 7, 2493–2498
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jced.6b00186
    Published June 30, 2016
    Copyright © 2016 American Chemical Society
    Request reuse permissions

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