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Density, Viscosity, and Refractive Index Data for a Ternary System of Wine Congeners (Ethyl Butyrate + Diethyl Succinate + Isobutanol) in the Temperature Range from 288.15 to 323.15 K and at Atmospheric Pressure

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Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11120 Belgrade, Serbia
*Phone: +381 11 3370429. Fax: +381 11 3370387. E-mail: [email protected]
Cite this: J. Chem. Eng. Data 2017, 62, 1, 275–291
Publication Date (Web):November 4, 2016
https://doi.org/10.1021/acs.jced.6b00640
Copyright © 2016 American Chemical Society
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    Abstract

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    Density, viscosity, and refractive index data for the ternary system ethyl butyrate + diethyl succinate + isobutanol and binary system ethyl butyrate + diethyl succinate have been measured in the temperature range 288.15–323.15 K, with temperature step of 5 K, and at atmospheric pressure. The measurements were performed on an Anton Paar DMA 5000 digital vibrating tube densimeter, Anton Paar SVM 3000 digital viscometer, and Anton Paar RXA 156 refractometer. Based on the corresponding binary data, as well as ternary data, presented in this work, excess molar volumes (VE), viscosity deviations (Δη), and refractive index deviations (ΔnD) were determined and fitted by the Redlich–Kister and Nagata–Tamura polynomial equations. The influence of mixture composition on values of excess molar volume, deviation functions, and the molecular interactions present in the mixtures was further discussed.

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