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Determination and Correlation of Ethyl Vanillin Solubility in Different Binary Solvents at Temperatures from 273.15 to 313.15 K

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State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
Collaborative Innovation Center of Chemical Science and Chemical Engineering (Tianjin), Tianjin 300072, People’s Republic of China
*E-mail: [email protected]. Tel: +86-22-27405754. Fax: +86-22-27374971.
Cite this: J. Chem. Eng. Data 2017, 62, 6, 1788–1796
Publication Date (Web):May 26, 2017
https://doi.org/10.1021/acs.jced.6b00972
Copyright © 2017 American Chemical Society

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    Abstract

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    The solubility data of ethyl vanillin in binary solvents, including (propan-2-one + water), (methanol + water), (ethanol + water), and (propan-2-ol + water), were measured in the temperature range from 273.15 to 313.15 K by using a UV spectroscopy method. The results show that the solubility of ethyl vanillin increases with increasing temperature. Besides, the modified Apelblat equation and the λh equation were used to correlate the experimental solubility data. Dissolution thermodynamic properties of ethyl vanillin in different binary solvent mixtures, including Gibbs energy, enthalpy, and entropy, were calculated based on the nonrandom two-liquid equation and the experimental solubility data.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jced.6b00972.

    • Comparison of solubility data for protocatechuic acid in methanol between experimental values obtained in this work and literature data; (8) parameters of different models for ethyl vanillin; dissolution thermodynamic properties of ethyl vanillin in different binary solvent mixtures; thermal analysis (TGA/DSC) of ethyl vanillin; X-ray powder diffraction pattern of ethyl vanillin; fitted curves by the modified Apelblat equation (PDF)

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