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Measurement and Correlation of Liquid–Liquid Equilibrium for Quaternary Systems of Water + Methanol or Ethanol + Ethyl Methyl Carbonate + Heptane at 25 °C

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    Measurement and Correlation of Liquid–Liquid Equilibrium for Quaternary Systems of Water + Methanol or Ethanol + Ethyl Methyl Carbonate + Heptane at 25 °C
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    Department of Chemistry, Jinan University, Guangzhou, 510632, China
    *Fax: +86-20-85221697. E-mail: [email protected]
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2017, 62, 9, 2516–2520
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    https://doi.org/10.1021/acs.jced.6b01031
    Published March 23, 2017
    Copyright © 2017 American Chemical Society
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    Abstract

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    In this work, liquid phase compositions for mixtures of water + methanol + ethyl methyl carbonate (EMC) + heptane, water + ethanol + EMC + heptane, and water + methanol + EMC, water + ethanol + EMC, and water + EMC + heptane at 25 °C were measured at atmospheric pressure. The modified UNIQUAC activity coefficient model was employed to correlate the experimental tie-line data, and the results were compared with ones obtained with the extended UNIQUAC model. The consistency of the measured tie-line data was ascertained by applying the Othmer–Tobias equation.

    Copyright © 2017 American Chemical Society

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    Cited By

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    This article is cited by 5 publications.

    1. Wenfeng Peng, Quanzhou Zhang, Wanxia Feng, Yao Chen. Liquid–Liquid Equilibria for Ternary Systems of (Ethyl Methyl Carbonate + Methanol or Ethanol + Water) at 293.15, 303.15, and 308.15 K. Journal of Chemical & Engineering Data 2018, 63 (12) , 4445-4452. https://doi.org/10.1021/acs.jced.8b00543
    2. Shunrui Zhang, Ligang Zheng, Xi Wang, Shuaiyong Tang, Yanfeng Li, Mengtao Xu, Qiankun Luo. Investigation on the intrinsic instabilities of ethyl methyl carbonate flames. Fuel 2024, 367 , 131526. https://doi.org/10.1016/j.fuel.2024.131526
    3. Lulu Yin, Wu Xu, Yong Hu, Yong Jiang. Experimental and theoretical investigation of ethyl methyl carbonate/air flames: Laminar burning velocity and cellular instability at elevated pressures. Fuel 2023, 346 , 128206. https://doi.org/10.1016/j.fuel.2023.128206
    4. Zhentao Zhao, Mingyu Liu, Yuxin Wang, Zizhen Yan, Guangwen Xu, Jianjun Guo, Lei Shi. One-step embedding method for immobilized bifunctional and alkaline ionic liquids as effective catalysts applied in transesterification. Reaction Chemistry & Engineering 2023, 8 (7) , 1654-1664. https://doi.org/10.1039/D3RE00070B
    5. Yue Yu, Lei Shi, Jianjun Guo, Xin Li, Wenbing Yang, Zhigang Zhang, Guangwen Xu. In-depth understanding of soluble base deactivation during the carbonate transesterification process. Fuel 2021, 285 , 119201. https://doi.org/10.1016/j.fuel.2020.119201
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2017, 62, 9, 2516–2520
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jced.6b01031
    Published March 23, 2017
    Copyright © 2017 American Chemical Society
    Request reuse permissions

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