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Vapor Pressures and Vapor–Liquid Critical Properties of Four Pentene Isomers

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Laboratory for Thermophysical Properties LTP GmbH, Associate Institute at the University of Oldenburg, Marie-Curie-Str. 10, 26129 Oldenburg, Germany
*E-mail: [email protected]. Tel.: +49 (0)441 361119-23.
Cite this: J. Chem. Eng. Data 2017, 62, 9, 2837–2841
Publication Date (Web):June 14, 2017
https://doi.org/10.1021/acs.jced.7b00148
Copyright © 2017 American Chemical Society

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    Abstract

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    For 1-pentene and the three branched C5H10 isomers (2-methylbut-1-ene, 3-methylbut-1-ene, and 2-methylbut-2-ene), vapor pressures and vapor–liquid critical properties were determined, thus filling several gaps in the thermodynamic database for these compounds. Using a static titanium autoclave with sapphire windows for high temperature and pressure determinations, vapor pressures and critical temperatures, pressures, and density data were measured. The experimental data were used to fit parameters for the Wagner vapor pressure equation and compared to available literature data. The consistency of the critical values was checked with the critical surface equation.

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    Cited By

    This article is cited by 2 publications.

    1. Xiaoyu Yao, Xueqiang Dong, Yanxing Zhao, Jun Shen, Maoqiong Gong. Measurement of Critical Parameters for the Binary Mixture of R744 (Carbon Dioxide) + R1243zf (3,3,3-Trifluoropropene). Journal of Chemical & Engineering Data 2022, 67 (9) , 2128-2135. https://doi.org/10.1021/acs.jced.2c00098
    2. K. Naresh, Harsha Nagar, Vineet Aniya. Thermodynamic Measurements and Correlation of Properties for Tribromomethane. Journal of Solution Chemistry 2021, 50 (5) , 723-751. https://doi.org/10.1007/s10953-021-01076-5

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