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Gaseous PVT Property Measurements of cis-1,3,3,3-Tetrafluoropropene

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† ‡ § Department of Mechanical Engineering, Research Center for Next Generation Refrigerant Properties (NEXT-RP), International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), and §Research Center for Hydrogen Industrial Use and Storage (HYDROGENIUS), Kyushu University, Fukuoka, 819-0395, Japan
Department of Energy and Material Sciences, Kyushu University, Fukuoka, 816-8580, Japan
Cite this: J. Chem. Eng. Data 2017, 62, 7, 2178–2182
Publication Date (Web):June 1, 2017
https://doi.org/10.1021/acs.jced.7b00263
Copyright © 2017 American Chemical Society

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    Abstract

    Abstract Image

    PVT properties in the vapor phase of cis-1,3,3,3-tetrafluoropropene (R1234ze(Z)) were measured by a multiple expansion method in the temperature range from 353 to 413 K and at pressures up to 2.7 MPa. Thirty data along four isotherms are obtained in the temperatures between 353 and 413 K. The vapor pressures at the temperatures were also measured by adding a sample of R1234ze(Z) to a sample cell at the vapor–liquid equilibrium conditions. The uncertainties in temperature and pressure measurements are estimated to be within 6 mK and 0.3 kPa, respectively. The expanded uncertainty in density measurement is estimated within no greater than 0.12% (k = 2). The obtained PVT properties and vapor pressures are compared with the existing equation of state.

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