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Density and Viscosity of N-Methylacetamide–Calcium Chloride Mixtures over the Temperature Range from 308.15 to 328.15 K at Atmospheric Pressure

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Laboratory of NMR-Spectroscopy and Computer Simulations, G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 1 Akademicheskaya Street, Ivanovo, 153045, Russia
*E-mail: [email protected]. Tel.: +7 4932 351869. Fax: +7 4932 336237.
Cite this: J. Chem. Eng. Data 2017, 62, 12, 4128–4132
Publication Date (Web):November 8, 2017
https://doi.org/10.1021/acs.jced.7b00494
Copyright © 2017 American Chemical Society

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    Abstract

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    The values of densities in N-methylacetamide solutions of calcium chloride have been measured at atmospheric pressure using an Anton Paar digital vibrating U-tube densimeter at temperatures ranging from 308.15 to 328.15 K, ΔT = 5 K and in the concentration range from 0 to 0.355 mol·kg–1. The kinematic viscosity for these mixtures has been measured at the same thermodynamic conditions using an Ubbelohde viscometer. Partial molar volumes of N-methylacetamide; partial molar volumes and apparent molar volumes of calcium chloride, and thermal expansion coefficients of solutions have been calculated using the experimental values. Dependences of these properties on the electrolyte concentrations have been discussed.

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    Cited By

    This article is cited by 10 publications.

    1. Alexey A. Dyshin, Michael G. Kiselev. Density and Viscosity of Magnesium Chloride Solution in N-Methylacetamide over the Temperature Range from 308.15 to 328.15 K at Ambient Pressure. Journal of Chemical & Engineering Data 2019, 64 (6) , 2536-2541. https://doi.org/10.1021/acs.jced.9b00046
    2. Alexey A. Dyshin, Olga V. Eliseeva, Michael G. Kiselev. Density and Viscosity of Zinc Chloride Solution in N-Methylacetamide over the Temperature Range from 308.15 to 328.15 K at Atmospheric Pressure. Journal of Chemical & Engineering Data 2018, 63 (8) , 3130-3135. https://doi.org/10.1021/acs.jced.8b00399
    3. Michael A. Krestyaninov, Dmitry V. Ivlev, Alexey A. Dyshin, Dmitriy M. Makarov, Michael G. Kiselev, Arkadiy M. Kolker. Complex investigation of H-bond in Water-N-methylacetamide system: Volumetric properties, DFT, IR, MD analysis. Journal of Molecular Liquids 2022, 360 , 119533. https://doi.org/10.1016/j.molliq.2022.119533
    4. A. A. Dyshin, M. S. Kuzmikov, A. A. Aleshonkova, G. V. Bondarenko, A. M. Kolker, M. G. Kiselev. Thermal Properties of Poly(Methyl Methacrylate) Samples of Different Molecular Weights Impregnated with Single-Walled Carbon Nanotubes in Supercritical Carbon Dioxide. Russian Journal of Physical Chemistry B 2021, 15 (8) , 1221-1227. https://doi.org/10.1134/S1990793121080030
    5. Bin Li, Long Zhao, Xiaoqing Yue, Yujie Pang, Shuai Zhang, Zhaojun Wu, Jianbin Zhang. Density, viscosity and intermolecular interaction of polyethylene glycol 300 + N, N-Dimethylformamide binary mixture. Physics and Chemistry of Liquids 2021, 59 (1) , 90-103. https://doi.org/10.1080/00319104.2019.1683830
    6. Giuseppe Graziano. N-methylacetamide is a solvent better than water for amino acid side chains: A rationalization grounded in the solvent-excluded volume effect. Chemical Physics Letters 2021, 762 , 138160. https://doi.org/10.1016/j.cplett.2020.138160
    7. Dmitriy M. Makarov, Gennadiy I. Egorov, Arkadiy M. Kolker. Density measurements of water – N-methylacetamide mixture at temperatures from 274.15 to 333.15 K and ambient pressure. A comparison of the volumetric characteristics of some amides. The Journal of Chemical Thermodynamics 2020, 151 , 106233. https://doi.org/10.1016/j.jct.2020.106233
    8. Emilia Kaczkowska, Jarosław Wawer, Magdalena Tyczyńska, Małgorzata Jóźwiak, Joanna Krakowiak. The interaction parameters for solutions of n-butylurea in aqueous solutions of N-methylacetamide – The volumetric and compressibility studies between 288.15 K and 308.15 K. The Journal of Chemical Thermodynamics 2020, 149 , 106143. https://doi.org/10.1016/j.jct.2020.106143
    9. Giuseppe Graziano. WITHDRAWN: Solvent-excluded volume effect explains why N-methylacetamide is a solvent better than water for amino acid side chains. Chemical Physics Letters 2020, 14 , 137918. https://doi.org/10.1016/j.cplett.2020.137918
    10. Karol A. Biernacki, Emilia Kaczkowska, Piotr Bruździak. Aqueous solutions of NMA, Na2HPO4, and NaH2PO4 as models for interaction studies in phosphate–protein systems. Journal of Molecular Liquids 2018, 265 , 361-371. https://doi.org/10.1016/j.molliq.2018.05.104

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