Determination and Correlation of Solubility and Thermodynamic Properties of trans-Cinnamyl Alcohol in Pure and Binary Solvents from 253.15 K to 293.15 K
- Si Li
- ,
- Lingyu Wang
- ,
- Minghe Zhu
- ,
- Dandan Han
- ,
- Ya Liu
- ,
- Mingyang Chen
- ,
- Jie Hou
- , and
- Junbo Gong
Abstract
The solubility of cinnamyl alcohol in 11 pure solvents (methanol, ethanol, n-propanol, isopropyl alcohol, n-butyl alcohol, isobutyl alcohol, sec-butyl alcohol, acetone, methyl acetate, ethyl acetate and n-hexane) and two binary solvents of n-hexane + (n-propanol, n-butyl alcohol) was measured by a gravimetric method over temperatures from 253.15 K to 293.15 K at atmosphere pressure. From the experimental results, it was found that the solubility increased with the increasing temperature in all these solvents. The Apelblat model, the λh model, and the nonrandom two-liquid (NRTL) model were used to correlate the solubility data of cinnamyl alcohol in pure and mixed solvents. The thermodynamic properties of the mixing process in binary solvents were calculated by the NRTL model. The result indicates that the mixing process of cinnamyl alcohol is endothermic and spontaneous. The experimental solubility provides good guidance for the subsequent study of crystallization design and crystal morphology of cinnamyl alcohol.
Cited By
This article is cited by 4 publications.
- Liangcheng Song, Danyang Zhao, Shuguang Zhang, Xiao Zhang, Guan Wang, Chongqiang Zhu, Yu Tian, Chunhui Yang. Solubility of Diflufenican in Pure and Binary Solvent Systems. Journal of Chemical & Engineering Data 2018, 63 (11) , 4176-4184. https://doi.org/10.1021/acs.jced.8b00632
- Min Su, Qing Lu, Hua Sun, Jingkang Wang. Solubility of p-Aminobenzoic Acid Potassium in Organic Solvents and Binary (Water + Isopropyl Alcohol) Mixture at Temperatures from (283.15 to 318.15) K. Journal of Chemical & Engineering Data 2018, 63 (8) , 2629-2636. https://doi.org/10.1021/acs.jced.7b00978
- Jiayin Zhang, Yumin Liu, Zeren Shang, Kuo Wang, Jianhua Han, Songgu Wu. Solubility measurement, correlation and computational analysis of p-Acetamidobenzoic acid in 12 pure solvents. The Journal of Chemical Thermodynamics 2021, 159 , 106478. https://doi.org/10.1016/j.jct.2021.106478
- Ellen Qian, Anisha Wadawadigi, Olivia Zha, Kelly Liu, Jingyi Dai, Shrika Eddula, Carina Jiang, Alex Zhang, Siqi Zhu, Estefania Garcia, William E. Acree, Michael H. Abraham. Determination of Abraham model correlations for describing solute transfer into the methyl butyrate mono-solvent at 298 K. Physics and Chemistry of Liquids 2020, 58 (6) , 792-802. https://doi.org/10.1080/00319104.2019.1660983