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Densities and Viscosities for Binary Liquid Mixtures of Biodiesel + 1-Pentanol, 2-Pentanol, or 2-Methyl-1-Butanol from (288.15 to 338.15) K at 0.1 MPa

  • Leidy T. Vargas-Ibáñez
    Leidy T. Vargas-Ibáñez
    Facultad de Ciencias Químicas Universidad Autónoma de Nuevo León, San Nicolás de los Garza, Nuevo León C.P. 66455, México
  • Gustavo A. Iglesias-Silva
    Gustavo A. Iglesias-Silva
    Departamento de Ingeniería Química Instituto Tecnológico de Celaya Celaya, Guanajuato, C.P. 38010, México
  • José J. Cano-Gómez*
    José J. Cano-Gómez
    Facultad de Ciencias Químicas Universidad Autónoma de Nuevo León, San Nicolás de los Garza, Nuevo León C.P. 66455, México
    *Tel: 011 52 81 8329 4000. Fax: (81) 8376 2929. E-mail: [email protected]
  • Carlos Escamilla-Alvarado
    Carlos Escamilla-Alvarado
    Facultad de Ciencias Químicas Universidad Autónoma de Nuevo León, San Nicolás de los Garza, Nuevo León C.P. 66455, México
  • , and 
  • Miguel A. Berrones-Eguiluz
    Miguel A. Berrones-Eguiluz
    Facultad de Ciencias Químicas Universidad Autónoma de Nuevo León, San Nicolás de los Garza, Nuevo León C.P. 66455, México
Cite this: J. Chem. Eng. Data 2018, 63, 7, 2438–2450
Publication Date (Web):March 29, 2018
https://doi.org/10.1021/acs.jced.7b00996
Copyright © 2018 American Chemical Society

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    Abstract

    Abstract Image

    This work presents experimentally determined densities and viscosities of biodiesel blended with 1-pentanol, 2-pentanol, and 2-methyl-1-butanol between 288.15 and 338.15 K at 0.1 MPa. The densities are measured using a vibrating tube densimeter, and the kinematic viscosities, using a glass capillary viscometer. The measured density and viscosity of the pure components agree with values reported in the literature within average absolute percentage deviations of 0.04 and 0.83%, respectively. The excess molar volumes and viscosity deviations show positive and negative deviations from ideality, respectively. The Redlich–Kister equation is used to represent the composition behavior of the excess molar volumes and viscosity deviations. The experimental kinematic viscosities have a minimum value over a composition range of 50–90% alcohol by weight. The McAllister equation correlates the kinematic viscosity within an average absolute percentage deviation of 1.77%, while the Nava-Ríos equation correlates the kinematic viscosity within 0.88%.

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    Cited By

    This article is cited by 21 publications.

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