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Density and Viscosity of Zinc Chloride Solution in N-Methylacetamide over the Temperature Range from 308.15 to 328.15 K at Atmospheric Pressure

  • Alexey A. Dyshin*
    Alexey A. Dyshin
    Laboratory of NMR-Spectroscopy and Computer Simulations, G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 1 Akademicheskaya Street, Ivanovo 153045, Russia
    *E-mail: [email protected]. Tel: +7 4932 351869. Fax: +7 4932 336237.
  • Olga V. Eliseeva
    Olga V. Eliseeva
    Laboratory of NMR-Spectroscopy and Computer Simulations, G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 1 Akademicheskaya Street, Ivanovo 153045, Russia
  • , and 
  • Michael G. Kiselev
    Michael G. Kiselev
    Laboratory of NMR-Spectroscopy and Computer Simulations, G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 1 Akademicheskaya Street, Ivanovo 153045, Russia
Cite this: J. Chem. Eng. Data 2018, 63, 8, 3130–3135
Publication Date (Web):July 31, 2018
https://doi.org/10.1021/acs.jced.8b00399
Copyright © 2018 American Chemical Society

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    Abstract

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    The densities of zinc chloride in N-methylacetamide solutions have been measured at atmospheric pressure (99.6 ± 0.8) kPa using an Anton Paar DMA 5000 M digital vibrating U-tube densimeter at temperatures ranging from 308.15 to 328.15 K, with ΔT = 5 K, and in the concentration range from 0 to 1.3 mol·kg–1. The kinematic viscosity for these compositions has been measured under the same thermodynamic conditions as for the measurements of densities, made with an Ubbelohde viscometer. Partial and apparent molar volumes of all components in solutions and the dynamic viscosity and thermal expansion coefficients of solutions have been calculated from the experimental data. The obtained dependencies were analyzed. Growth in the salt concentration increases the solution viscosity, and an increase in the temperature reduces the solution viscosity, at the same time. The increases in temperature and salt concentration lead to a decrease in the zinc chloride partial molar volume.

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    Cited By

    This article is cited by 7 publications.

    1. Upasana Mahanta, Sambita Choudhury, R. Prasanna Venkatesh, Sujatha SarojiniAmma, S. A. Ilangovan, Tamal Banerjee. Ionic-Liquid-Based Deep Eutectic Solvents as Novel Electrolytes for Supercapacitors: COSMO-SAC Predictions, Synthesis, and Characterization. ACS Sustainable Chemistry & Engineering 2020, 8 (1) , 372-381. https://doi.org/10.1021/acssuschemeng.9b05596
    2. Alexey A. Dyshin, Michael G. Kiselev. Density and Viscosity of Magnesium Chloride Solution in N-Methylacetamide over the Temperature Range from 308.15 to 328.15 K at Ambient Pressure. Journal of Chemical & Engineering Data 2019, 64 (6) , 2536-2541. https://doi.org/10.1021/acs.jced.9b00046
    3. Anjali Awasthi, Puneet Kumar Pandey, Aashees Awasthi. Densities and volumetric properties of binary mixtures of 2-ethoxyethanol with 2-pyrrolidinone and N-methylacetamide from 303.15 to 323.15 K. The Journal of Chemical Thermodynamics 2023, 178 , 106959. https://doi.org/10.1016/j.jct.2022.106959
    4. Zeyu Xu, Maochun Wu. Toward Dendrite-Free Deposition in Zinc-Based Flow Batteries: Status and Prospects. Batteries 2022, 8 (9) , 117. https://doi.org/10.3390/batteries8090117
    5. Michael A. Krestyaninov, Dmitry V. Ivlev, Alexey A. Dyshin, Dmitriy M. Makarov, Michael G. Kiselev, Arkadiy M. Kolker. Complex investigation of H-bond in Water-N-methylacetamide system: Volumetric properties, DFT, IR, MD analysis. Journal of Molecular Liquids 2022, 360 , 119533. https://doi.org/10.1016/j.molliq.2022.119533
    6. A. A. Dyshin, M. S. Kuzmikov, A. A. Aleshonkova, G. V. Bondarenko, A. M. Kolker, M. G. Kiselev. Thermal Properties of Poly(Methyl Methacrylate) Samples of Different Molecular Weights Impregnated with Single-Walled Carbon Nanotubes in Supercritical Carbon Dioxide. Russian Journal of Physical Chemistry B 2021, 15 (8) , 1221-1227. https://doi.org/10.1134/S1990793121080030
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