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Liquid–Liquid Equilibria for Ternary Systems of (Ethyl Methyl Carbonate + Methanol or Ethanol + Water) at 293.15, 303.15, and 308.15 K

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Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Chem. Eng. Data 2018, 63, 12, 4445-4452
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    Liquid–Liquid Equilibria for Ternary Systems of (Ethyl Methyl Carbonate + Methanol or Ethanol + Water) at 293.15, 303.15, and 308.15 K
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    • Wenfeng Peng
      Wenfeng Peng
      Department of Chemistry, Jinan University, Guangzhou 510632, China
      More by Wenfeng Peng
    • Quanzhou Zhang
      Quanzhou Zhang
      Department of Chemistry, Jinan University, Guangzhou 510632, China
      More by Quanzhou Zhang
    • Wanxia Feng
      Wanxia Feng
      Department of Chemistry, Jinan University, Guangzhou 510632, China
      More by Wanxia Feng
    • Yao Chen*
      Yao Chen
      Department of Chemistry, Jinan University, Guangzhou 510632, China
      *Fax: +86-20-85221697. E-mail: [email protected]
      More by Yao Chen
      Orcidhttp://orcid.org/0000-0002-3461-388X
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2018, 63, 12, 4445–4452
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    https://doi.org/10.1021/acs.jced.8b00543
    Published November 5, 2018
    Copyright © 2018 American Chemical Society
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    Abstract

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    Liquid-phase composition values for {water + methanol + ethyl methyl carbonate (EMC)} and (water + ethanol + EMC) were determined at temperatures of 293.15, 303.15, and 308.15 K at 101 kPa. Thermodynamic modified UNIQUAC and extended UNIQUAC models were used in regression of the experimental values, with average root-mean-square deviations of 0.96 and 1.45% in mole fraction, respectively. Moreover, optimum binary interaction parameters of (methanol or ethanol + EMC) were obtained by regression analysis of the phase composition values. The experimental data consistency was further ascertained by applying the Bachman equation. Distribution coefficients and separation factors were used to assess the extraction performance of EMC in the separation of methanol and ethanol from water.

    Copyright © 2018 American Chemical Society

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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2018, 63, 12, 4445–4452
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jced.8b00543
    Published November 5, 2018
    Copyright © 2018 American Chemical Society
    Request reuse permissions

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