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Physicochemical Properties of LiFSI Solutions II: LiFSI with Water, MTBE, and Anisole

  • Johannes Neuhaus
    Johannes Neuhaus
    Laboratory of Engineering Thermodynamics (LTD), University of Kaiserslautern, Erwin-Schrödinger Str. 44, D-67663 Kaiserslautern, Germany
  • Erik von Harbou*
    Erik von Harbou
    Laboratory of Engineering Thermodynamics (LTD), University of Kaiserslautern, Erwin-Schrödinger Str. 44, D-67663 Kaiserslautern, Germany
    *E-mail: [email protected]. Phone: +49-631/205-4685. Fax: +49-631/205-3835.
  • , and 
  • Hans Hasse
    Hans Hasse
    Laboratory of Engineering Thermodynamics (LTD), University of Kaiserslautern, Erwin-Schrödinger Str. 44, D-67663 Kaiserslautern, Germany
    More by Hans Hasse
Cite this: J. Chem. Eng. Data 2019, 64, 3, 878–883
Publication Date (Web):February 6, 2019
https://doi.org/10.1021/acs.jced.8b00595
Copyright © 2019 American Chemical Society

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    Abstract

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    This article is the second in a series in which the thermodynamic properties of solutions of lithium bis(fluorosulfonylimide (LiFSI) are investigated. The solvents that are considered here are methyl tert-butyl ether (MTBE) and water (H2O), which are good solvents for LiFSI, and anisole, which is an antisolvent for LiFSI. The solubility of LiFSI in MTBE, as well as in the binary solvent mixture MTBE-anisole, was measured at temperatures of between 283 and 303 K and concentrations of LiFSI of up to 0.47 mol mol–1. Furthermore, the liquid–liquid equilibrium of the system LiFSI-MTBE-H2O was studied at 293 K and ambient pressure. Moreover, the density and shear viscosity of solutions of LiFSI in MTBE were studied at temperatures between 273 and 308 K and concentrations of LiFSI up to 0.4 mol mol–1.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jced.8b00595.

    • Literature comparisons of the experimental density data of pure MTBE from this work to data from the literature and of the experimental shear viscosity data of pure MTBE from this work to data from the literature; 1H NMR spectra, 13C NMR spectra, and 19F NMR spectra of a solution of crystallized and redissolved LiFSI crystals in MTBE (PDF)

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    Cited By

    This article is cited by 1 publications.

    1. Xin Fang, Bolun Mei, Xingchuan Yang, Yi Yu, Chunmei Cao, Li Xu, Guoji Liu. Dissolution behavior, thermodynamic analysis and molecular simulation of lithium bis(fluorosulfonyl)imide in organic solvent at 273.15 K to 313.15 K. The Journal of Chemical Thermodynamics 2024, 191 , 107245. https://doi.org/10.1016/j.jct.2023.107245

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