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Solubility of Diflufenican in Pure and Binary Solvent Systems

  • Liangcheng Song
    Liangcheng Song
    School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
    School of Environment, Harbin Institute of Technology, Harbin 150090, People’s Republic of China
  • Danyang Zhao
    Danyang Zhao
    School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
    More by Danyang Zhao
  • Shuguang Zhang
    Shuguang Zhang
    Nantong Jiahe Chemicals Co., Ltd., Haimen 226100, People’s Republic of China
  • Xiao Zhang
    Xiao Zhang
    School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
    More by Xiao Zhang
  • Guan Wang
    Guan Wang
    School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
    More by Guan Wang
  • Chongqiang Zhu
    Chongqiang Zhu
    School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
  • Yu Tian
    Yu Tian
    School of Environment, Harbin Institute of Technology, Harbin 150090, People’s Republic of China
    State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology (SKLUWRE, HIT), Harbin 150090, People’s Republic of China
    More by Yu Tian
  • , and 
  • Chunhui Yang*
    Chunhui Yang
    School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
    State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology (SKLUWRE, HIT), Harbin 150090, People’s Republic of China
    *E-mail: [email protected]. Tel.: +86-451-86403829. Fax: +86-451-86418270.
    More by Chunhui Yang
Cite this: J. Chem. Eng. Data 2018, 63, 11, 4176–4184
Publication Date (Web):October 17, 2018
https://doi.org/10.1021/acs.jced.8b00632
Copyright © 2018 American Chemical Society

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    Abstract

    Abstract Image

    With the aid of a laser monitoring technique, the solution thermodynamics of diflufenican was sysmatically studied in the pure and binary solvent systems. The solubility screening results showed that diflufenican had excellent solubility in ethyl acetate, acetone, benzene, and toluene which could be used as good solvents. While methanol, ethanol, isopropyl alcohol and cyclohexane were the poor solvents for diflufenican as the solubility was quite small. Two binary solvent systems (acetone + water, acetone + ethanol) were composed, which exhibited a wide solubility range of diflufenican. The solubility data were well correlated by the modified Apelblat model, NRTL model, van’t Hoff model, λh model, and Jouyban–Acree model, which provided the basis for the design and optimization for the diflufenican crystallization process.

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    Cited By

    This article is cited by 13 publications.

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