Experimental Measurements and Modeling Study of Liquid–Liquid Equilibrium [(Water + Methyl Oleate + Model Molecules of Tar Issued from the Biomass Gasification Process (Benzene, Toluene, Phenol, Thiophene, and Pyridine)]
- Georgio Bassil*
- Joseph SaabJoseph SaabFaculty of Sciences, Department of Chemistry Biochemistry, Group ThEA-Thermodynamic Phase Equilibria and Analysis, Holy Spirit University of Kaslik, B.P. 446, Jounieh, LebanonMore by Joseph Saab
- Ilham MokbelIlham MokbelCNRS, Laboratoire des Multimatériaux et Interfaces, University of Lyon, Université Claude Bernard Lyon 1, UMR 5615, F-69622, Lyon, FranceUniversity of Lyon, Université Jean Monnet, Saint-Etienne, France 10 rue Tréfilerie, Maison de l’Université CS 82301 42023 Saint-Etienne Cedex 2, FranceMore by Ilham Mokbel
- Latifa NegadiLatifa NegadiLATA2M, Laboratoire de Thermodynamique Appliquée et Modélisation Moléculaire, University of Tlemcen, Post Office Box 119, Tlemcen 13000, AlgeriaMore by Latifa Negadi
- Jacques JoseJacques JoseCNRS, Laboratoire des Multimatériaux et Interfaces, University of Lyon, Université Claude Bernard Lyon 1, UMR 5615, F-69622, Lyon, FranceMore by Jacques Jose
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- Christelle GoutaudierChristelle GoutaudierCNRS, Laboratoire des Multimatériaux et Interfaces, University of Lyon, Université Claude Bernard Lyon 1, UMR 5615, F-69622, Lyon, FranceMore by Christelle Goutaudier
Biomass is known as a potential renewable energy source which can be used in the gasification process in order to produce biomethane gas. One of the major challenges encountered is the elimination of the high level of tar found in the syngas issued from the gasification process. The main purpose of this work is to conduct experimental measurements of liquid–liquid equilibria that will be used for tar removal from the biomass gasification process which is the important step before the distribution and the industrialization of the biomethane gas. In the present work, we propose an experimental and modeling study of liquid–liquid equilibrium of ternary systems of water + solvent (methyl oleate) + model molecules of tar (benzene, toluene, phenol, thiophene, and pyridine) at 303.2 K, 323.2 K, and 343.2 K. The experimental results were correlated using the nonrandom two-liquid (NRTL) and UNIQUAC models and are used to feed the industrial needs for thermodynamic modeling.
This article is cited by 2 publications.
- Georgio Bassil, Joseph Saab, Christelle Goutaudier, Latifa Negadi, Jacques Jose, Ilham Mokbel. Experimental measurements for the liquid-liquid equilibrium of ternary systems [(water + methyl oleate + model mixtures of tar (naphthalene, phenanthrene and anthracene)] issued from the biomass gasification process. The Journal of Chemical Thermodynamics 2022, 164 , 106613. https://doi.org/10.1016/j.jct.2021.106613
- Ilyas Yousuf Mir, Pranav Vivekrao Kherdekar, Divesh Bhatia. Experimental and Modeling Studies on the Removal of Tars from Coal‐Derived Syngas Using Methyl Oleate. Chemical Engineering & Technology 2021, 44 (11) , 2082-2091. https://doi.org/10.1002/ceat.202100317