ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Isobaric Vapor–Liquid Phase Equilibrium Measurements for Allyl Alcohol with Chloroform, Ethyl Acetate, and Methyl Propionate at 101.3 kPa

  • Baotao Diao
    Baotao Diao
    College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China
    More by Baotao Diao
  • Ke Wang
    Ke Wang
    College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China
    More by Ke Wang
  • Dongmei Xu
    Dongmei Xu
    College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China
    More by Dongmei Xu
  • Jun Gao*
    Jun Gao
    College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China
    *E-mail: [email protected]
    More by Jun Gao
  • Zhun Ma
    Zhun Ma
    College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China
    More by Zhun Ma
  • Lianzheng Zhang
    Lianzheng Zhang
    College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China
  • , and 
  • Yinglong Wang
    Yinglong Wang
    College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
Cite this: J. Chem. Eng. Data 2019, 64, 2, 682–687
Publication Date (Web):January 2, 2019
https://doi.org/10.1021/acs.jced.8b00908
Copyright © 2019 American Chemical Society

    Article Views

    407

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options

    Abstract

    Abstract Image

    For separation of the azeotrope allyl alcohol and water by azeotropic distillation, chloroform, ethyl acetate, and methyl propionate were selected as the azeotropic agents. In this work, the vapor–liquid phase equilibrium (VLE) data for the binary systems (allyl alcohol + chloroform/ethyl acetate/methyl propionate) were measured at 101.3 kPa using a modified Rose still. The VLE experimental data were checked by Herington and van Ness methods to verify the thermodynamic consistency. The excess Gibbs energy GE was calculated to evaluate the nonideality for three binary systems. Meanwhile, three thermodynamic models nonrandom two-liquid, universal quasichemical, and Wilson were adopted to correlate the experimental data, and the binary interaction parameters of the three models were regressed. The root-mean-square deviations of vapor composition (y1) and equilibrium temperature (T) are less than 0.0057 and 0.18 K, respectively, which indicates that the experimental data were well correlated by three models.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 5 publications.

    1. Shufen Wang, Xiaopeng Chen, Jiezhen Liang, Xiaojie Wei, Hairong Mo, Kaixi Deng, Linlin Wang. Vapor–Liquid Equilibrium of α-Pinene, Longifolene, and Abietic Acid of Pine Oleoresin: HS-GC Measurements and Model Correlation. Journal of Chemical & Engineering Data 2022, 67 (5) , 1125-1139. https://doi.org/10.1021/acs.jced.1c00799
    2. Karen Silva Vargas, Benjamin Katryniok, Marcia Araque. Isobaric Vapor–Liquid Equilibrium Data for Six Binary Systems: Prop-2-en-1-ol (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–Hexan-2-one (2), Hexan-2-one (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-one (2), and 4-Methyl-pentan-2-one (1)–4-Methyl-pentan-2-ol (2) at 101.32 kPa. Journal of Chemical & Engineering Data 2021, 66 (2) , 1055-1067. https://doi.org/10.1021/acs.jced.0c00861
    3. Xuemei Deng, Indira Inastiti Noor, Jun Zhang, Jun Gao, Dongmei Xu, Yixin Ma, Lianzheng Zhang, Yinglong Wang. Isobaric vapour-liquid equilibrium for binary and ternary systems of isopropyl acetate, isopropyl alcohol, acetic acid and water at 101.3 kPa. The Journal of Chemical Thermodynamics 2022, 165 , 106662. https://doi.org/10.1016/j.jct.2021.106662
    4. Rui Li, Xianglin Meng, Xiaowei Liu, Jun Gao, Dongmei Xu, Yinglong Wang. Separation of azeotropic mixture (2, 2, 3, 3-Tetrafluoro-1-propanol + water) by extractive distillation: Entrainers selection and vapour-liquid equilibrium measurements. The Journal of Chemical Thermodynamics 2019, 138 , 205-210. https://doi.org/10.1016/j.jct.2019.06.026
    5. Baotao Diao, Zenghui Wang, Hui Yang, Lianzheng Zhang, Dongmei Xu, Jun Gao, Yinglong Wang. Separation of azeotrope 2,2,3,3-tetrafluoro-1-propanol and water by extractive distillation using ionic liquids: Vapor-liquid equilibrium measurements and interaction analysis. Journal of Molecular Liquids 2019, 292 , 111424. https://doi.org/10.1016/j.molliq.2019.111424

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect