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Isobaric Vapor Liquid Equilibria for Binary Mixtures of Isoamyl Acetate + Ethyl Acetate at 50 and 100 kPa

  • Cesar A. Sánchez
    Cesar A. Sánchez
    Research Group of Chemical and Biochemical Process, Department of Chemical and Environmental Engineering, National University of Colombia, Bogotá Campus, Cra 30 No. 45-03, Ed. 453, Of. 318, Bogotá, Colombia
  • Andrés A. Herrera
    Andrés A. Herrera
    Research Group of Chemical and Biochemical Process, Department of Chemical and Environmental Engineering, National University of Colombia, Bogotá Campus, Cra 30 No. 45-03, Ed. 453, Of. 318, Bogotá, Colombia
  • Julio C. Vargas
    Julio C. Vargas
    Research Group of Chemical and Biochemical Process, Department of Chemical and Environmental Engineering, National University of Colombia, Bogotá Campus, Cra 30 No. 45-03, Ed. 453, Of. 318, Bogotá, Colombia
  • Iván D. Gil*
    Iván D. Gil
    Research Group of Chemical and Biochemical Process, Department of Chemical and Environmental Engineering, National University of Colombia, Bogotá Campus, Cra 30 No. 45-03, Ed. 453, Of. 318, Bogotá, Colombia
    *E-mail: [email protected]
    More by Iván D. Gil
  • , and 
  • Gerardo Rodríguez
    Gerardo Rodríguez
    Research Group of Chemical and Biochemical Process, Department of Chemical and Environmental Engineering, National University of Colombia, Bogotá Campus, Cra 30 No. 45-03, Ed. 453, Of. 318, Bogotá, Colombia
Cite this: J. Chem. Eng. Data 2019, 64, 5, 2110–2115
Publication Date (Web):April 29, 2019
https://doi.org/10.1021/acs.jced.8b01053
Copyright © 2019 American Chemical Society

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    Abstract

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    In this work new phase equilibria data for the system ethyl acetate + isoamyl acetate at pressures of 50 and 100 kPa are reported. The measures were carried out in the equilibrium apparatus FISCHER LABODEST VLE 602D, which is essentially a dynamic equilibrium cell equipped with a Cottrell recirculation pump. The quality of the experimental information was examined with the Wisniak point criteria because binary mixtures under study offer small deviations from the ideality. The nonrandom two-liquid and universal quasichemical activity models with symmetrical parameters were used to correlate experimental data, and both activity models show good correlation with experiments and can be used in distillation process calculations.

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    Cited By

    This article is cited by 1 publications.

    1. Karen Silva Vargas, Benjamin Katryniok, Marcia Araque. Isobaric Vapor–Liquid Equilibrium Data for Six Binary Systems: Prop-2-en-1-ol (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–Hexan-2-one (2), Hexan-2-one (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-one (2), and 4-Methyl-pentan-2-one (1)–4-Methyl-pentan-2-ol (2) at 101.32 kPa. Journal of Chemical & Engineering Data 2021, 66 (2) , 1055-1067. https://doi.org/10.1021/acs.jced.0c00861

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