ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Determination and Thermodynamic Modeling of Solid–Liquid Phase Equilibrium for Succinic Acid in the Glutaric Acid + Adipic Acid + Ethyl Acetate Mixture and Adipic Acid in the Succinic Acid + Glutaric Acid + Ethyl Acetate Mixture

  • Yulan Huang
    Yulan Huang
    School of Chemical Engineering and Energy, Zhengzhou University, Henan 450001, People’s Republic of China
    More by Yulan Huang
  • Chunhua Jiang
    Chunhua Jiang
    School of Chemical Engineering and Energy, Zhengzhou University, Henan 450001, People’s Republic of China
    Xinlianxin Energy Chemical Corporation Limited, Changji, Xinjiang 832200, People’s Republic of China
  • Jingjing Lu
    Jingjing Lu
    School of Chemical Engineering and Energy, Zhengzhou University, Henan 450001, People’s Republic of China
    More by Jingjing Lu
  • Honglin Chen
    Honglin Chen
    School of Chemical Engineering and Energy, Zhengzhou University, Henan 450001, People’s Republic of China
    More by Honglin Chen
  • Chunhao Guo
    Chunhao Guo
    School of Chemical Engineering and Energy, Zhengzhou University, Henan 450001, People’s Republic of China
    More by Chunhao Guo
  • , and 
  • Xunqiu Wang*
    Xunqiu Wang
    School of Chemical Engineering and Energy, Zhengzhou University, Henan 450001, People’s Republic of China
    *E-mail: [email protected]. Phone: +86 0371 67781292.
    More by Xunqiu Wang
Cite this: J. Chem. Eng. Data 2019, 64, 4, 1538–1549
Publication Date (Web):March 28, 2019
https://doi.org/10.1021/acs.jced.8b01127
Copyright © 2019 American Chemical Society

    Article Views

    263

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options

    Abstract

    Abstract Image

    The solid–liquid equilibrium of succinic acid in various mass fractions of the glutaric acid + adipic acid + ethyl acetate mixture and adipic acid in various mass fractions of the succinic acid + glutaric acid + ethyl acetate mixture was measured by the dynamic method within the temperature range of 299.12 to 343.56 K under atmospheric pressure. The results show that the solubility of succinic acid and adipic acid increases with the increasing temperature. The solubility of succinic acid in ethyl acetate increases with the increase of mass fraction of glutaric acid and adipic acid in the mixed solvent at the same temperature. Similarly, the solubility of adipic acid in ethyl acetate also increases with the increase of mass fraction of succinic acid and glutaric acid in the mixed solvent. The experimental data of solubility were correlated by the Apelblat equation, the Wilson equation, and nonrandom two-liquid equation. All equations can be well applied, and the Apelblat equation has the better fitting effect. In addition, the thermodynamic properties of the mixing processes in the ternary and quaternary mixed system were calculated based on the nonrandom two-liquid model, including the mixing enthalpy, the mixing entropy, and the mixing Gibbs free energy.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 4 publications.

    1. Ravleen Kaur Kohli, Stephanie Salas, Bilal Shokoor, Chelsea L. Price, James F Davies. Chemically Resolved Evaporation Dynamics of Dicarboxylic Acid Mixtures in Solid Particles. Analytical Chemistry 2023, 95 (31) , 11831-11838. https://doi.org/10.1021/acs.analchem.3c02475
    2. Yang Shi, Guangya Yu, Xunqiu Wang. Experimental determination and thermodynamic modeling of solid-liquid equilibrium of 2,6-dimethylphenol, 3,5-dimethylphenol and 2,5-dimethylphenol binary and ternary systems. Thermochimica Acta 2022, 710 , 179174. https://doi.org/10.1016/j.tca.2022.179174
    3. Yong Wang, Wenfeng Ge, Mingming Wang, Xunqiu Wang. Studies on dissolution equilibrium of chlorfenapyr in five mono-solvents and two mixed solvents ranging from 288.15 to 328.15K. Fluid Phase Equilibria 2020, 514 , 112560. https://doi.org/10.1016/j.fluid.2020.112560
    4. Lei Zhang, Yue Zuo, Huixin Liu, Xunqiu Wang. Study on the solid–liquid equilibrium of bifenthrin in solvents. Journal of Molecular Liquids 2020, 308 , 113033. https://doi.org/10.1016/j.molliq.2020.113033

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect