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Thermophysical and Molar Volume Aberration of Amphiphilic Eutectic Mix of Bivalent Diols and Ammonium-Ionic Liquid

Cite this: J. Chem. Eng. Data 2019, 64, 8, 3307–3315
Publication Date (Web):July 25, 2019
https://doi.org/10.1021/acs.jced.9b00134
Copyright © 2019 American Chemical Society

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    Abstract

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    The thermophysical delineation of four diol (glycerol, 1,2 butanediol, 1,6 hexanediol, and ethanediol)-based deep eutectic solvents (DESs) were investigated in the temperature range of 273–323 K at atmospheric pressure. The homogenous mixture was prepared with quaternary ammonium salt and diols, respectively, at an identical molar ratio of 1:1 (HBA/HBD). Density and viscosity have a negative response with increasing temperature. Conductivity and excess molar volume ratio increase at elevated temperatures. The results obtained were correlated with linear model equations. The liquid–liquid equilibrium of the ternary mixture formed with PEG (6000) + Na2CO3 + DES was measured and correlated with the Merchuk equation. It is inferred from the data that the molecular weight and complex molecular nature of the HBD have a positive influence on the physicochemical properties of DES and its biphasic separation.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jced.9b00134.

    • Values of individual physical parameter dependence on temperature respectively and table for the Merchuk equation parameters evaluated for various binodal curves (PDF)

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