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Efficient and Reversible Nitric Oxide Absorption by Low-Viscosity, Azole-Derived Deep Eutectic Solvents

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    Efficient and Reversible Nitric Oxide Absorption by Low-Viscosity, Azole-Derived Deep Eutectic Solvents
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    • Luhong Zhang
      Luhong Zhang
      School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
      More by Luhong Zhang
      Orcidhttp://orcid.org/0000-0002-7073-4793
    • Haopeng Ma
      Haopeng Ma
      School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
      More by Haopeng Ma
    • Guangsen Wei
      Guangsen Wei
      School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
      More by Guangsen Wei
    • Bin Jiang
      Bin Jiang
      School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
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    • Yongli Sun
      Yongli Sun
      School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
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    • Xiaowei Tantai*
      Xiaowei Tantai
      School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
      *E-mail: [email protected]. Tel/Fax: +86 22 27400199.
      More by Xiaowei Tantai
      Orcidhttp://orcid.org/0000-0003-2925-0444
    • Zhaohe Huang
      Zhaohe Huang
      School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
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    • Yang Chen
      Yang Chen
      School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2019, 64, 7, 3068–3077
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    https://doi.org/10.1021/acs.jced.9b00173
    Published June 5, 2019
    Copyright © 2019 American Chemical Society
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    Abstract

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    Deep eutectic solvents (DESs) have been extensively studied and applied to the absorption of acid gases. However, the absorption of nitric oxide (NO) by DES has rarely been reported. In this work, we found that NO can be absorbed by azole-derived DESs effectively and reversibly. A series of DESs with low viscosity based on tetrazolium (Tetz), triazole, and imidazole as hydrogen bond donors (HBDs) and common ionic liquids as hydrogen bond acceptors (HBAs) were prepared. The absorption results showed that DESs based on tetrabutylphosphine chloride (P4444Cl) as HBA or Tetz as HBD exhibited higher NO absorption. Notably, Tetz/P4444Cl DES exhibited the NO absorption values of 2.10 and 1.01 mol/mol at 101.3 and 12 kPa partial pressures, respectively, and 303.15 K. In addition, the NO absorption capacity decreased continuously with the increasing temperature. The evaporation of Tetz/P4444Cl DES can be ignored during the absorption progress. The results of thermogravimetric analysis measurement and regeneration experiments demonstrated that Tetz/P4444Cl possessed desirable thermostability and reusability. The absorption mechanism of NO by Tetz/P4444Cl was studied by Fourier transform infrared, 1H NMR, and Gaussian simulations. It was found that there was chemical interaction between NO and the hydrogen-containing nitrogen atom of Tetz.

    Copyright © 2019 American Chemical Society

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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2019, 64, 7, 3068–3077
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jced.9b00173
    Published June 5, 2019
    Copyright © 2019 American Chemical Society
    Request reuse permissions

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