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Efficient and Reversible Nitric Oxide Absorption by Low-Viscosity, Azole-Derived Deep Eutectic Solvents

  • Luhong Zhang
    Luhong Zhang
    School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
    More by Luhong Zhang
  • Haopeng Ma
    Haopeng Ma
    School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
    More by Haopeng Ma
  • Guangsen Wei
    Guangsen Wei
    School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
    More by Guangsen Wei
  • Bin Jiang
    Bin Jiang
    School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
    More by Bin Jiang
  • Yongli Sun
    Yongli Sun
    School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
    More by Yongli Sun
  • Xiaowei Tantai*
    Xiaowei Tantai
    School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
    *E-mail: [email protected]. Tel/Fax: +86 22 27400199.
  • Zhaohe Huang
    Zhaohe Huang
    School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
    More by Zhaohe Huang
  • , and 
  • Yang Chen
    Yang Chen
    School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, People’s Republic of China
    More by Yang Chen
Cite this: J. Chem. Eng. Data 2019, 64, 7, 3068–3077
Publication Date (Web):June 5, 2019
https://doi.org/10.1021/acs.jced.9b00173
Copyright © 2019 American Chemical Society

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    Abstract

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    Deep eutectic solvents (DESs) have been extensively studied and applied to the absorption of acid gases. However, the absorption of nitric oxide (NO) by DES has rarely been reported. In this work, we found that NO can be absorbed by azole-derived DESs effectively and reversibly. A series of DESs with low viscosity based on tetrazolium (Tetz), triazole, and imidazole as hydrogen bond donors (HBDs) and common ionic liquids as hydrogen bond acceptors (HBAs) were prepared. The absorption results showed that DESs based on tetrabutylphosphine chloride (P4444Cl) as HBA or Tetz as HBD exhibited higher NO absorption. Notably, Tetz/P4444Cl DES exhibited the NO absorption values of 2.10 and 1.01 mol/mol at 101.3 and 12 kPa partial pressures, respectively, and 303.15 K. In addition, the NO absorption capacity decreased continuously with the increasing temperature. The evaporation of Tetz/P4444Cl DES can be ignored during the absorption progress. The results of thermogravimetric analysis measurement and regeneration experiments demonstrated that Tetz/P4444Cl possessed desirable thermostability and reusability. The absorption mechanism of NO by Tetz/P4444Cl was studied by Fourier transform infrared, 1H NMR, and Gaussian simulations. It was found that there was chemical interaction between NO and the hydrogen-containing nitrogen atom of Tetz.

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    Cited By

    This article is cited by 14 publications.

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