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Electrolytic Effect on the Solubility and Solvation Thermodynamics of l-Serine and l-Isoleucine in Aqueous Media

  • Saroj Chowdhury
    Saroj Chowdhury
    Department of Chemistry, University of Kalyani, Kalyani, 741235, Nadia, India
  • Prasenjit Mandal
    Prasenjit Mandal
    Department of Chemistry, University of Kalyani, Kalyani, 741235, Nadia, India
  • Aslam Hossain
    Aslam Hossain
    Department of Physical and Inorganic Chemistry, Institute of Natural Sciences and Mathematics, Ural Federal University, Yekaterinburg, Russia
  • Partha Sarathi Guin
    Partha Sarathi Guin
    Shibpur Dinobundhoo Institution (College), 412/1, G.T. Road (South), Howrah, Pin-711102, India
  • Sanjay Roy*
    Sanjay Roy
    Shibpur Dinobundhoo Institution (College), 412/1, G.T. Road (South), Howrah, Pin-711102, India
    *E-mail: [email protected] (S.R.).
    More by Sanjay Roy
  • , and 
  • Kalachand Mahali*
    Kalachand Mahali
    Department of Chemistry, University of Kalyani, Kalyani, 741235, Nadia, India
    *E-mail: [email protected] (K.M.).
Cite this: J. Chem. Eng. Data 2019, 64, 10, 4286–4297
Publication Date (Web):September 4, 2019
https://doi.org/10.1021/acs.jced.9b00363
Copyright © 2019 American Chemical Society

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    Abstract

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    By the analytical gravimetric technique, the equilibrium saturated solubilities of l-serine and l-isoleucine in aqueous solutions of sodium nitrate (NaNO3) and potassium nitrate (KNO3) were measured at six different temperatures in the range of 288.15 to 313.15 K. The theoretical studies on the standard transfer Gibbs free energies were performed with the help of experimental solubility data. The molar volume, transfer enthalpy of cavity, transfer Gibbs free energy, and dipole–dipole interactions were also measured to explore complete thermodynamical aspects of these molecules in aqueous electrolytes. In addition, the solute–solute, solute–solvent, and solvent–solvent interactions in terms of transfer Gibbs energies due to chemical interactions and transfer entropy for the present amino acids (AA’S) were calculated by deducting the cavity interaction and dipole–dipole interaction from the total transfer Gibbs free energy (ΔGt0(i)) and transfer entropies (TΔSt0(i)). Finally, the stability owing to the chemical nature of the amino acids in aqueous electrolytic solutions is explained by introducing the abovementioned thermodynamical parameters.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acs.jced.9b00363.

    • Standard Gibbs energies of solutions of the amino acids in aqueous electrolytes at different temperatures and cosolvent parameters (PDF)

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    2. Yingchen Wang, Kai Lin, Wanying Jia, Qiushuo Yu. Measurement and Correlation of Solubility of l-Valine, l-Isoleucine, l-Methionine, and l-Threonine in Water + tert-Butanol from 283.15 to 328.15 K. Journal of Chemical & Engineering Data 2021, 66 (1) , 677-683. https://doi.org/10.1021/acs.jced.0c00821
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    8. Avishek Saha, Kalachand Mahali, Puspal Mukherjee, Sintu Ganai, Aslam Hossain, A.M.A. Henaish, Simanta Kundu, Jahangeer Ahmed, Sanjay Roy. Solubility and dissolution thermodynamics of L-histidine and L-tryptophan in aqueous ethanol solution at five equidistant temperatures. Journal of Molecular Liquids 2023, 389 , 122852. https://doi.org/10.1016/j.molliq.2023.122852
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    10. Yankui Xing, Zhengda Zhou, Fangfang Li, Shuangping Tian, Yuxi Liang, Sixian Li, Yanan Zhou, Yun Gao. Solid-liquid equilibrium and dissolution thermodynamic properties of L-isoleucine in binary solvent mixtures. The Journal of Chemical Thermodynamics 2023, 182 , 107035. https://doi.org/10.1016/j.jct.2023.107035
    11. Saroj Chowdhury, Biplab Ghosh, Sibdas Baskey, Aslam Hossain, A.M.A. Henaish, Sanjay Roy, Kalachand Mahali. Solubility and thermodynamical phenomenafor l-serine and l-isoleucine in chloride Salts of Na+ and K+ electrolytic media. Journal of Molecular Liquids 2023, 378 , 121619. https://doi.org/10.1016/j.molliq.2023.121619
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