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Determining Iron(III) Concentration in a Green Chemistry Experiment Using Phyllanthus emblica (Indian Gooseberry) Extract and Spectrophotometry
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    Laboratory Experiment

    Determining Iron(III) Concentration in a Green Chemistry Experiment Using Phyllanthus emblica (Indian Gooseberry) Extract and Spectrophotometry
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    Journal of Chemical Education

    Cite this: J. Chem. Educ. 2019, 96, 4, 756–760
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    https://doi.org/10.1021/acs.jchemed.8b00817
    Published March 26, 2019
    Copyright © 2019 American Chemical Society and Division of Chemical Education, Inc.

    Abstract

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    A laboratory experiment utilizing locally available Indian Gooseberry (Phyllanthus emblica Linn.) extract as a bioreagent to determine iron(III) is described with the goal of providing students with hands-on experience in spectrophotometry and green chemistry. Spectrophotometry was used to measure the concentration of the complex formed between iron(III) and gallic acid, an active compound found in Indian Gooseberry extract. Excellent results from the quantitative analysis of iron(III) in water were achieved. In this case, the bioreagent was used to replace the conventional hazardous chemicals that are usually employed as chromogenic reagents. The use of Indian Gooseberry extract is simple, inexpensive, and environmentally friendly. This experiment is appropriate for use as a simple spectrophotometric protocol for undergraduate teaching in an analytical- or general-chemistry laboratory.

    Copyright © 2019 American Chemical Society and Division of Chemical Education, Inc.

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    Cited By

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    This article is cited by 10 publications.

    1. Parawee Rattanakit, Adcharawadee Chooyimpanit, Rasimate Maungchang. Green Analytical Chemistry Laboratory Boxset: From the Lab-at-Home during COVID-19 to a Science Teacher Training. Journal of Chemical Education 2023, 100 (11) , 4472-4481. https://doi.org/10.1021/acs.jchemed.3c00614
    2. Kimberley A. Frederick, Amanda S. Harper-Leatherman. An Inquiry-Based In-Person or Remote Laboratory Using Iron Analysis and Paper Microfluidics to Teach Analytical Method Development. Journal of Chemical Education 2022, 99 (12) , 4024-4031. https://doi.org/10.1021/acs.jchemed.2c00370
    3. Matheus Fernandes Filgueiras, Endler Marcel Borges. Iron Quantification in Dietary Supplements using Four Colorimetric Assays. Journal of Chemical Education 2022, 99 (5) , 2067-2078. https://doi.org/10.1021/acs.jchemed.1c00869
    4. Jixin Wang, Wenshui Zhou, Mei Yu, Zheng Zhu, Ying Li. Adsorption of Additives in Cola Beverages: A Safe and Improved Experiment Exploring Beer’s Law and Adsorption Process. Journal of Chemical Education 2022, 99 (2) , 924-931. https://doi.org/10.1021/acs.jchemed.1c00471
    5. Somchai Lapanantnoppakhun, Urai Tengjaroensakul, Pitchaya Mungkornasawakul, Chanida Puangpila, Sila Kittiwachana, Jeeraphithak Saengtempiam, Supaporn Kradtap Hartwell. Green Analytical Chemistry Experiment: Quantitative Analysis of Iron in Supplement Tablets with Vis spectrophotometry Using Tea Extract as a Chromogenic Agent. Journal of Chemical Education 2020, 97 (1) , 207-214. https://doi.org/10.1021/acs.jchemed.9b00530
    6. Siripat Suteerapataranon, Kanokwan Kiwfo, Pei Meng Woi, Chalermpong Saenjum, Kate Grudpan. The past is the future: from natural acid-base indicators to natural reagents in sustainable analytical chemistry. Pure and Applied Chemistry 2024, https://doi.org/10.1515/pac-2024-0204
    7. Sanele M. Mnkandla, Mafereka Francis Tyson Mosoabisane, Norah Basopo, Patricks Voua Otomo. Mycofiltration of Aqueous Iron (III) and Imidacloprid Solutions, and the Effects of the Filtrates on Selected Biomarkers of the Freshwater Snail Helisoma duryi. Archives of Environmental Contamination and Toxicology 2024, 86 (2) , 187-197. https://doi.org/10.1007/s00244-023-01049-3
    8. Andrew P. Dicks. Teaching greener & more sustainable analytical chemistry to undergraduates: Some strategies & tips. Green Analytical Chemistry 2023, 7 , 100082. https://doi.org/10.1016/j.greeac.2023.100082
    9. Vesna Ferk Savec, Katarina Mlinarec. Experimental Work in Science Education from Green Chemistry Perspectives: A Systematic Literature Review Using PRISMA. Sustainability 2021, 13 (23) , 12977. https://doi.org/10.3390/su132312977
    10. Luana Curbani, Jane Mary Lafayette Neves Gelinski, Endler Marcel Borges. Determination of Ethanol in Beers Using a Flatbed Scanner and Automated Digital Image Analysis. Food Analytical Methods 2020, 13 (1) , 249-259. https://doi.org/10.1007/s12161-019-01611-7

    Journal of Chemical Education

    Cite this: J. Chem. Educ. 2019, 96, 4, 756–760
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jchemed.8b00817
    Published March 26, 2019
    Copyright © 2019 American Chemical Society and Division of Chemical Education, Inc.

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