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Earth-Abundant Bimetallic Nanoparticle Catalysts for Aerobic Ammoxidation of Alcohols to Nitriles

  • Tomohiro Yasukawa
    Tomohiro Yasukawa
    Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
  • Xi Yang
    Xi Yang
    Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
    More by Xi Yang
  • , and 
  • Shu Kobayashi*
    Shu Kobayashi
    Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
    *Email: [email protected]
Cite this: J. Org. Chem. 2020, 85, 11, 7543–7548
Publication Date (Web):April 28, 2020
https://doi.org/10.1021/acs.joc.0c00670
Copyright © 2020 American Chemical Society

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    Abstract

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    Heterogeneous nitrogen-doped carbon-incarcerated iron/copper bimetallic nanoparticle (NP) catalysts prepared from nitrogen-containing polymers were developed. These catalysts showed activity higher than that of the corresponding monometallic NPs for aerobic ammoxidation of alcohols to nitriles. The important procedure for high activity in the catalyst preparation was found to be a simultaneous reduction of two metal salts.

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