ACS Publications. Most Trusted. Most Cited. Most Read

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Phys. Chem. A 2019, 123, 43, 9257-9267
RETURN TO ISSUEPREVFeature ArticleNEXT

Catalytic CO Oxidation by Gas-Phase Metal Oxide Clusters

  • Xiao-Na Li
    Xiao-Na Li
    State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
    Beijing National Laboratory for Molecular Sciences and CAS Research/Education Center of Excellence in Molecular Sciences, Beijing 100190, China
    More by Xiao-Na Li
    View Biography
    Orcidhttp://orcid.org/0000-0002-0316-5762
  • , 
  • Li-Na Wang
    Li-Na Wang
    State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
    University of Chinese Academy of Sciences, Beijing 100049, China
    Beijing National Laboratory for Molecular Sciences and CAS Research/Education Center of Excellence in Molecular Sciences, Beijing 100190, China
    More by Li-Na Wang
    View Biography
  • , 
  • Li-Hui Mou
    Li-Hui Mou
    State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
    University of Chinese Academy of Sciences, Beijing 100049, China
    Beijing National Laboratory for Molecular Sciences and CAS Research/Education Center of Excellence in Molecular Sciences, Beijing 100190, China
    More by Li-Hui Mou
    View Biography
  • , and 
  • Sheng-Gui He*
    Sheng-Gui He
    State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
    University of Chinese Academy of Sciences, Beijing 100049, China
    Beijing National Laboratory for Molecular Sciences and CAS Research/Education Center of Excellence in Molecular Sciences, Beijing 100190, China
    *Sheng-Gui He. E-mail: [email protected]
    More by Sheng-Gui He
    View Biography
    Orcidhttp://orcid.org/0000-0002-9919-6909
Cite this: J. Phys. Chem. A 2019, 123, 43, 9257–9267
Publication Date (Web):July 17, 2019
https://doi.org/10.1021/acs.jpca.9b05185
Copyright © 2019 American Chemical Society
Request reuse permissions

    Article Views

    1943

    Altmetric

    -

    Citations

    45
    LEARN ABOUT THESE METRICS
    Other access options
    Get e-Alerts
    SUBJECTS:

    Abstract

    Abstract Image

    Oxidation of CO into CO2 is a prototypical reaction in heterogeneous catalysis and is one of the extensively studied reactions in the gas phase to explore the underlying mechanisms of related catalysis. In this Feature Article, we present and discuss our recent advances in the fundamental understanding of catalytic CO oxidation by O2 mediated with heteronuclear metal oxide clusters (HMOCs) using state-of-the-art mass spectrometry and quantum chemistry calculations. The HMOCs can be considered as ideal models for active sites on mixed or oxide supported catalysts at a strictly molecular level. A concept of electronegativity-ladder effect was proposed to account for the enhanced reactivity of noble metal (NM) doped HMOCs, and then this effect was successfully extended in the design of NM-free HMOCs in catalytic CO oxidation by O2. The future directions and the challenges were also discussed.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 45 publications.

    1. Si-Dun Wang, Tong-Mei Ma, Xiao-Na Li, Sheng-Gui He. CO Oxidation Promoted by NO Adsorption on RhMn2O3– Cluster Anions. The Journal of Physical Chemistry A 2024, 128 (4) , 738-746. https://doi.org/10.1021/acs.jpca.3c06445
    2. Qi Yang, Gui-Duo Jiang, Sheng-Gui He. Enhancing the Performance of Global Optimization of Platinum Cluster Structures by Transfer Learning in a Deep Neural Network. Journal of Chemical Theory and Computation 2023, 19 (6) , 1922-1930. https://doi.org/10.1021/acs.jctc.2c00923
    3. Ya-Ke Li, Chu-Man Sun, Gong-Ping Wei, Sheng-Gui He, Knut R. Asmis, Shuang-Quan Zang. Thermal Methane Conversion to Formaldehyde Mediated by NiAlO3+ in the Gas Phase. The Journal of Physical Chemistry A 2023, 127 (7) , 1636-1641. https://doi.org/10.1021/acs.jpca.3c00132
    4. Le-Shi Chen, Yun-Zhu Liu, Jiao-Jiao Chen, Si-Dun Wang, Tong-Mei Ma, Xiao-Na Li, Sheng-Gui He. Water–Gas Shift Catalyzed by Iridium–Vanadium Oxide Clusters IrVO2– with Iridium in a Rare Oxidation State of −II. The Journal of Physical Chemistry A 2022, 126 (32) , 5294-5301. https://doi.org/10.1021/acs.jpca.2c03974
    5. Jiao-Jiao Chen, Yun-Zhu Liu, Qing-Yu Liu, Xiao-Na Li, Sheng-Gui He. Single Ti3+ Ion Catalyzes NO Reduction on Stoichiometric Titanium Oxide Cluster Anions (TiO2)n– (n = 1–11). ACS Catalysis 2022, 12 (15) , 8768-8775. https://doi.org/10.1021/acscatal.2c02006
    6. Jiao-Jiao Chen, Xiao-Na Li, Qing-Yu Liu, Gong-Ping Wei, Yuan Yang, Zi-Yu Li, Sheng-Gui He. Water Gas Shift Reaction Catalyzed by Rhodium–Manganese Oxide Cluster Anions. The Journal of Physical Chemistry Letters 2021, 12 (35) , 8513-8520. https://doi.org/10.1021/acs.jpclett.1c02267
    7. Le-Shi Chen, Yun-Zhu Liu, Xiao-Na Li, Jiao-Jiao Chen, Gui-Duo Jiang, Tong-Mei Ma, Sheng-Gui He. An IrVO4+ Cluster Catalytically Oxidizes Four CO Molecules: Importance of Ir–V Multiple Bonding. The Journal of Physical Chemistry Letters 2021, 12 (28) , 6519-6525. https://doi.org/10.1021/acs.jpclett.1c01584
    8. Yun-Zhu Liu, Jiao-Jiao Chen, Xiao-Na Li, Sheng-Gui He. Activation of Carbon Dioxide by CoCDn– (n = 0–4) Anions. The Journal of Physical Chemistry A 2021, 125 (17) , 3710-3717. https://doi.org/10.1021/acs.jpca.1c02229
    9. Li-Hui Mou, Yao Li, Zi-Yu Li, Qing-Yu Liu, Yi Ren, Hui Chen, Sheng-Gui He. Dinitrogen Activation and Functionalization by Heteronuclear Metal Cluster Anions FeV2C2– at Room Temperature. The Journal of Physical Chemistry Letters 2020, 11 (23) , 9990-9994. https://doi.org/10.1021/acs.jpclett.0c02921
    10. Yun-Zhu Liu, Xiao-Na Li, Sheng-Gui He. Reactivity of Iron Hydride Anions Fe2Hn– (n = 0–3) with Carbon Dioxide. The Journal of Physical Chemistry A 2020, 124 (41) , 8414-8420. https://doi.org/10.1021/acs.jpca.0c06986
    11. David C. McDonald II, Brendan C. Sweeny, Albert A. Viggiano, Nicholas S. Shuman, Shaun G. Ard. Role of Spin in the Catalytic Oxidation of CO by N2O Enabled by Co+: New Insights from Temperature-Dependent Kinetics and Statistical Modeling. The Journal of Physical Chemistry A 2020, 124 (39) , 7966-7972. https://doi.org/10.1021/acs.jpca.0c06960
    12. Shu-Hua Ou, Jiao-Jiao Chen, Xiao-Na Li, Tong-Mei Ma, Sheng-Gui He. CO Oxidation Catalyzed by the Neutral Cluster IrAl2O8 with Iridium in a High Oxidation State of VI. The Journal of Physical Chemistry C 2020, 124 (16) , 8869-8875. https://doi.org/10.1021/acs.jpcc.0c01562
    13. Li-Xue Jiang, Xiao-Na Li, Sheng-Gui He. Metal-Dependent Selectivity on the Reactions of Carbon Dioxide with Diatomic Hydride Anions MH– (M = Co, Ni, and Cu). The Journal of Physical Chemistry C 2020, 124 (11) , 5928-5933. https://doi.org/10.1021/acs.jpcc.9b11619
    14. Brendan C. Sweeny, David C. McDonald II, Jennifer L. Poutsma, John C. Poutsma, Nicholas S. Shuman, Shaun G. Ard, Albert A. Viggiano. Catalytic Oxidation of CO by N2O Enabled by Al2O2/3+: Temperature Dependent Kinetics and Statistical Modeling. The Journal of Physical Chemistry A 2020, 124 (9) , 1705-1711. https://doi.org/10.1021/acs.jpca.9b10732
    15. Xiao-Na Li, Li-Xue Jiang, Li−Na Wang, Shu-Hua Ou, Mei-Qi Zhang, Yuan Yang, Tong-Mei Ma, Sheng-Gui He. An Eight-Atom Iridium–Aluminum Oxide Cluster IrAlO6+ Catalytically Oxidizes Six CO Molecules. The Journal of Physical Chemistry Letters 2019, 10 (24) , 7850-7855. https://doi.org/10.1021/acs.jpclett.9b03056
    16. Boying Song, Zongcheng Wang, Wei Ma, Wenshuo Zhou, Qiong Tang, Xiaolei Bao, Kuo Liu, Yongchun Liu. Photocatalytic oxidation mechanism of isoprene over titanium oxide by UV–Vis lights. Journal of Catalysis 2024, 430 , 115362. https://doi.org/10.1016/j.jcat.2024.115362
    17. Bangmin Ju, Ziheng Zhang, Xiangtao Kong, Jinghan Zou, Gang Li, Hua Xie, Ling Jiang. Photoelectron velocity map imaging spectroscopy of group 14 elements and iron tetracarbonyl anionic clusters MFe(CO)4− (M = Si, Ge, Sn). The Journal of Chemical Physics 2024, 160 (4) https://doi.org/10.1063/5.0187204
    18. Julia Ciarlini, Brian S. Haynes, Alejandro Montoya. Carbon and nitrogen product distribution in the electrochemical degradation of nitrogen-heterocyclic compounds. Chemical Engineering Journal 2024, 480 , 148110. https://doi.org/10.1016/j.cej.2023.148110
    19. Sima ZULFUGAROVA, Gunel R AZİMOVA, S Z ALESKEROVA, Dilgam TAGİYEV. Cobalt-Containing Oxide Catalysts Obtained by The Sol-Gel Method with Auto-Combustion in The Reaction of Low-Temperature Oxidation of Carbon Monoxide. Journal of the Turkish Chemical Society Section A: Chemistry 2023, 10 (3) , 577-588. https://doi.org/10.18596/jotcsa.1261839
    20. Yun-Zhu Liu, Xing-Yue He, Jiao-Jiao Chen, Zhong-Pu Zhao, Xiao-Na Li, Sheng-Gui He. Filtration of the preferred catalyst for reverse water-gas shift among Rh n − ( n = 3–11) clusters by mass spectrometry under variable temperatures. Dalton Transactions 2023, 52 (20) , 6668-6676. https://doi.org/10.1039/D3DT00802A
    21. Xiao-Na Li, Sheng-Gui He. Gas-phase reactions driven by polarized metal–metal bonding in atomic clusters. Physical Chemistry Chemical Physics 2023, 25 (6) , 4444-4459. https://doi.org/10.1039/D2CP05148F
    22. Wolfgang E. Ernst, Maximilian Lasserus, Daniel Knez, Ferdinand Hofer, Andreas W. Hauser. Mixed-metal nanoparticles: phase transitions and diffusion in Au–VO clusters. Faraday Discussions 2023, 242 , 160-173. https://doi.org/10.1039/D2FD00089J
    23. Si-Dun Wang, Jiao-Jiao Chen, Yun-Zhu Liu, Tong-Mei Ma, Xiao-Na Li, Sheng-Gui He. Facile CO bond cleavage on polynuclear vanadium nitride clusters V 4 N 5 −. Physical Chemistry Chemical Physics 2022, 24 (48) , 29765-29771. https://doi.org/10.1039/D2CP04304A
    24. Nan Wang, Shan Wang, Jie Yang, Ping Xiao, Junjiang Zhu. Promotion Effect of Ce Doping on Catalytic Performance of LaMnO3 for CO Oxidation. Catalysts 2022, 12 (11) , 1409. https://doi.org/10.3390/catal12111409
    25. Abdul Majid, Sidra Arif, Tariq M. Younes, Mohammad Alkhedher, Sayed M. ElDin. DFT Study of Heteronuclear (TMFeO3)x Molecular Clusters (Where TM = Sc, Ti, Fe and x = 2, 4, 8) for Photocatalytic and Photovoltaic Applications. Energies 2022, 15 (19) , 7253. https://doi.org/10.3390/en15197253
    26. Xing-Yue He, Yun-Zhu Liu, Si-Dun Wang, Xingwang Lan, Xiao-Na Li, Sheng-Gui He. Multiple CO 2 reduction mediated by heteronuclear metal carbide cluster anions RhTaC 2 −. Dalton Transactions 2022, 51 (30) , 11491-11498. https://doi.org/10.1039/D2DT01612E
    27. Yulu Liu, Chenghua Xu, Wanglai Cen, Hao Li. Design strategy of bifunctional catalysts for CO oxidation. Fuel 2022, 320 , 123909. https://doi.org/10.1016/j.fuel.2022.123909
    28. Yun-Zhu Liu, Jiao-Jiao Chen, Li-Hui Mou, Qing-Yu Liu, Zi-Yu Li, Xiao-Na Li, Sheng-Gui He. Reverse water–gas shift reaction catalyzed by diatomic rhodium anions. Physical Chemistry Chemical Physics 2022, 24 (23) , 14616-14622. https://doi.org/10.1039/D2CP00472K
    29. Jiao-Jiao Chen, Xiao-Na Li, Li-Hui Mou, Qing-Yu Liu, Sheng-Gui He. Catalytic conversion of NO and CO into N 2 and CO 2 by rhodium–aluminum oxides in the gas phase. Journal of Materials Chemistry A 2022, 10 (11) , 6031-6037. https://doi.org/10.1039/D1TA04911A
    30. Riddhi Sengupta, Raghavendra, R. G. Pooja, Satyam Kumar Gupta, Bharat Kumar, Rajeev Shesha Joshi. Magnetic Surfaces for Photo-Isomerization of Azobenzene Based Polymer Probed Using Magneto Optical Method. Topics in Catalysis 2022, 123 https://doi.org/10.1007/s11244-022-01594-6
    31. Le-Shi Chen, Jiao-Jiao Chen, Tong-Mei Ma, Xiao-Na Li, Sheng-Gui He. CO self-promoted oxidation by gas-phase cluster anions IrVO4−. Chemical Physics Letters 2022, 787 , 139276. https://doi.org/10.1016/j.cplett.2021.139276
    32. Ruo-lin SUN, Si-ran ZHANG, Kang AN, Peng-fei SONG, Yuan LIU. Cu1.5Mn1.5O4 spinel type composite oxide modified with CuO for synergistic catalysis of CO oxidation. Journal of Fuel Chemistry and Technology 2021, 49 (6) , 799-808. https://doi.org/10.1016/S1872-5813(21)60032-4
    33. Max Schütz, Christian Gemel, Maximilian Muhr, Christian Jandl, Samia Kahlal, Jean-Yves Saillard, Roland A. Fischer. Exploring Cu/Al cluster growth and reactivity: from embryonic building blocks to intermetalloid, open-shell superatoms. Chemical Science 2021, 12 (19) , 6588-6599. https://doi.org/10.1039/D1SC00268F
    34. Yan-Xia Zhao, Xi-Guan Zhao, Yuan Yang, Man Ruan, Sheng-Gui He. Rhodium chemistry: A gas phase cluster study. The Journal of Chemical Physics 2021, 154 (18) https://doi.org/10.1063/5.0046529
    35. Suresh Sampathkumar, Selvarengan Paranthaman. Neutral noble-metal-free VCoO 2 and CrCoO 2 cluster catalysts for CO oxidation by O 2. New Journal of Chemistry 2021, 45 (8) , 4090-4100. https://doi.org/10.1039/D0NJ05199C
    36. Baoqi Yin, Zhixun Luo. Coinage metal clusters: From superatom chemistry to genetic materials. Coordination Chemistry Reviews 2021, 429 , 213643. https://doi.org/10.1016/j.ccr.2020.213643
    37. Yan Chen, Jia-Jun Deng, Wen-Wen Yao, Joseph Israel Gurti, Wei Li, Wen-Jie Wang, Jian-Xi Yao, Xun-Lei Ding. Non-stoichiometric molybdenum sulfide clusters and their reactions with the hydrogen molecule. Physical Chemistry Chemical Physics 2021, 23 (1) , 347-355. https://doi.org/10.1039/D0CP04457A
    38. Yubing Lu, Zihao Zhang, Fan Lin, Huamin Wang, Yong Wang. Single‐atom Automobile Exhaust Catalysts. ChemNanoMat 2020, 6 (12) , 1659-1682. https://doi.org/10.1002/cnma.202000407
    39. Si‐Dun Wang, Jiao‐Jiao Chen, Xiao‐Na Li, Tong‐Mei Ma, Sheng‐Gui He. Catalytic CO Oxidation by O 2 Mediated with Single Gold Atom Doped Titanium Oxide Cluster Anions AuTi 2 O 4–6 −. ChemPhysChem 2020, 21 (22) , 2550-2556. https://doi.org/10.1002/cphc.202000755
    40. Chaoqun Ma, Bingping Liu, Shihai Yan. Enhanced catalytic activity for CO oxidation by Fe-Adsorbing on BN under mild condition: A promising single-atom catalyst. Molecular Catalysis 2020, 495 , 111165. https://doi.org/10.1016/j.mcat.2020.111165
    41. Xiao-na Li, Li-xue Jiang, Qing-yu Liu, Yi Ren, Gong-ping Wei. Hydrogen-assisted C-C coupling on reaction of CuC3H−Cluster anion with CO. Chinese Journal of Chemical Physics 2020, 33 (5) , 628-634. https://doi.org/10.1063/1674-0068/cjcp2006094
    42. Li-hui Mou, Gui-duo Jiang, Zi-yu Li, Sheng-gui He. Activation of dinitrogen by gas-phase species. Chinese Journal of Chemical Physics 2020, 33 (5) , 507-520. https://doi.org/10.1063/1674-0068/cjcp2008141
    43. Hui Li, Shoutian Sun, Haodong Ji, Wen Liu, Zhurui Shen. Enhanced activation of molecular oxygen and degradation of tetracycline over Cu-S4 atomic clusters. Applied Catalysis B: Environmental 2020, 272 , 118966. https://doi.org/10.1016/j.apcatb.2020.118966
    44. L. Qian, G. Zheng. Recent advances of metal nanoclusters for aerobic oxidation. Materials Today Nano 2020, 11 , 100080. https://doi.org/10.1016/j.mtnano.2020.100080
    45. Zebin Yu, Lun Qian, Tao Zhong, Qi Ran, Jun Huang, Yanping Hou, Fengyuan Li, Mingjie Li, Qianqian Sun, Heqing Zhang. Enhanced visible light photocatalytic activity of CdS through controllable self-assembly compositing with ZIF-67. Molecular Catalysis 2020, 485 , 110797. https://doi.org/10.1016/j.mcat.2020.110797
    Download PDF

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect