Translational and Rotational Diffusion Coefficients of Gold Nanorods Dispersed in Mixtures of Water and Glycerol by Polarized Dynamic Light Scattering
- Francisco E. Berger BioucasFrancisco E. Berger BioucasInstitute of Advanced Optical Technologies − Thermophysical Properties (AOT-TP), Department of Chemical and Biological Engineering (CBI) and Erlangen Graduate School in Advanced Optical Technologies (SAOT), Friedrich-Alexander-University Erlangen-Nürnberg (FAU), Paul-Gordan-Straße 8, 91052 Erlangen, GermanyMore by Francisco E. Berger Bioucas
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- Cornelia DammCornelia DammInstitute of Particle Technology (LFG), Department of Chemical and Biological Engineering (CBI), Friedrich-Alexander-University Erlangen-Nürnberg (FAU), Cauerstraße 4, 91058 Erlangen, GermanyMore by Cornelia Damm
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- Wolfgang PeukertWolfgang PeukertInstitute of Particle Technology (LFG), Department of Chemical and Biological Engineering (CBI), Friedrich-Alexander-University Erlangen-Nürnberg (FAU), Cauerstraße 4, 91058 Erlangen, GermanyMore by Wolfgang Peukert
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- Michael H. RauschMichael H. RauschInstitute of Advanced Optical Technologies − Thermophysical Properties (AOT-TP), Department of Chemical and Biological Engineering (CBI) and Erlangen Graduate School in Advanced Optical Technologies (SAOT), Friedrich-Alexander-University Erlangen-Nürnberg (FAU), Paul-Gordan-Straße 8, 91052 Erlangen, GermanyMore by Michael H. Rausch
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- Thomas M. KollerThomas M. KollerInstitute of Advanced Optical Technologies − Thermophysical Properties (AOT-TP), Department of Chemical and Biological Engineering (CBI) and Erlangen Graduate School in Advanced Optical Technologies (SAOT), Friedrich-Alexander-University Erlangen-Nürnberg (FAU), Paul-Gordan-Straße 8, 91052 Erlangen, GermanyMore by Thomas M. Koller
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- Cédric GiraudetCédric GiraudetInstitute of Advanced Optical Technologies − Thermophysical Properties (AOT-TP), Department of Chemical and Biological Engineering (CBI) and Erlangen Graduate School in Advanced Optical Technologies (SAOT), Friedrich-Alexander-University Erlangen-Nürnberg (FAU), Paul-Gordan-Straße 8, 91052 Erlangen, GermanyMore by Cédric Giraudet
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- Andreas P. Fröba*Andreas P. Fröba*E-mail [email protected]. Tel: +49-9131-85-29789. Fax: +49-9131-85-25878.Institute of Advanced Optical Technologies − Thermophysical Properties (AOT-TP), Department of Chemical and Biological Engineering (CBI) and Erlangen Graduate School in Advanced Optical Technologies (SAOT), Friedrich-Alexander-University Erlangen-Nürnberg (FAU), Paul-Gordan-Straße 8, 91052 Erlangen, GermanyMore by Andreas P. Fröba
Abstract
Polarized dynamic light scattering (DLS) gives access to orientation-averaged translational and rotational diffusion coefficients of anisotropic particles dispersed in fluids in a single experiment. As the combination of both diffusivities contains information on the morphology of the particles, their simultaneous and accurate measurement for the same sample and thermodynamic state is beneficial for particle characterization. For nontransparent model suspensions of gold nanorods in water and water–glycerol mixtures, a scattering geometry in reflection direction was realized, which minimizes multiple scattering and allows using low laser powers to avoid laser heating. Furthermore, a heterodyne detection scheme was guaranteed by superimposing much stronger reference light to the scattered light. This ensures an unambiguous data evaluation and reduces the uncertainties for the rotational and the translational diffusivity, where the latter is accessible with smaller uncertainty. For the water-based suspensions, both diffusivities agree well with the stick hydrodynamic theory for rods and show an Andrade-type behavior in the studied temperature range from 271 to 323 K. The measured results for both diffusivities, particularly for the rotational diffusivity, indicate a breakdown of the stick boundary conditions for dynamic viscosities larger than 4 mPa·s.
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