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Signatures of Vibrational Strong Coupling in Raman Scattering

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    Signatures of Vibrational Strong Coupling in Raman Scattering
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    † Departamento de Física Teórica de la Materia Condensada and Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, Madrid E-28049, Spain
    ‡ Donostia International Physics Center (DIPC), E-20018 Donostia/San Sebastian, Spain
    *E-mail: [email protected] (J.d.P.).
    *E-mail: [email protected] (J.F.).
    *E-mail: [email protected] (F.J.G.-V.).
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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2015, 119, 52, 29132–29137
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    https://doi.org/10.1021/acs.jpcc.5b11654
    Published December 8, 2015
    Copyright © 2015 American Chemical Society
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    Abstract

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    We have analyzed theoretically how the emergence of collective strong coupling between vibrational excitations and confined cavity modes affects Raman scattering processes. This work was motivated by recent experiments (Shalabney et al. Angew. Chem., Int. Ed. 2015, 54, 7971) that reported enhancements of up to 3 orders of magnitude in the Raman signal. By using different models within linear response theory, we show that the total Raman cross section is maintained constant when the system evolves from the weak-coupling limit to the strong-coupling regime. A redistribution of the Raman signal among the two polaritons is the main fingerprint of vibrational strong coupling in the Raman spectrum.

    Copyright © 2015 American Chemical Society

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    This article is cited by 64 publications.

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    Cite this: J. Phys. Chem. C 2015, 119, 52, 29132–29137
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acs.jpcc.5b11654
    Published December 8, 2015
    Copyright © 2015 American Chemical Society
    Request reuse permissions

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